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Ammonium thiocyanate, solution 0,1 mol/l (0,1 N) 硫氰酸铵溶液，0,1 mol/l (0,1 N)

规格: solution 0,1 mol/l (0,1 N)

CAS: 1762-95-4

产品编号: AM04201000

MDL: MFCD00011428

品牌: Scharlab

Chemical Name	Ammonium thiocyanate
Synonym	Ammonium thiocyanate {LY} Ammonium thiocyanate {} {LY} Ammonium thiocyanate {} {} {LY} Ammonium thiocyanate {} {} {} {LY} Ammonium thiocyanate {} {} {} {} {LY} Ammonium thiocyanate {} {} {} {} {} {LY} Ammonium thiocyanate {} {} {} {} {} {} {LY} Ammonium thiocyanate {} {} {} {} {} {} {} {LY} Ammonium thiocyanate {} {} {} {} {} {} {} {} {LY} Ammonium thiocyanate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ammonium thiocyanate {} {} {} {} {} {} {} {} {} {} {LY} Ammonium thiocyanate {} {} {} {} {} {} {} {} {} {} {} {LY} Ammonium thiocyanate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ammonium thiocyanate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ammonium thiocyanate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ammonium thiocyanate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ammonium thiocyanate {} {} {} {} {} {}
CAS Number	1762-95-4
PubChem Substance ID	15666
EC Number	217-175-6
Beilstein Registry Number	3595135
MDL Number	MFCD00011428
Merck Number	561
Chemical Name Translation	硫氰酸铵
Wiswesser Line Notation	SHCN &ZH
LabNetwork Molecule ID	LN00193601
InChI	InChI=1S/CHNS.H3N/c2-1-3;/h3H;1H3
Canonical SMILES	N#CS.N

GHS Symbol

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Human
DOSE/DURATION           : 430 mg/kg
TOXIC EFFECTS :
   Behavioral - hallucinations, distorted perceptions
   Gastrointestinal - nausea or vomiting
   Gastrointestinal - other changes
REFERENCE :
   DAKMAJ Deutsches Archiv fuer Klinische Medizin.  (Leipzig, Ger. Dem. Rep.)
   V.1-211, 1865-1965.  For publisher information, see EJCIB8.
   Volume(issue)/page/year: 102,606,1911

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 750 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 30(10),51,1986

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Former

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 30(10),51,1986

WGK Germany	1
Hazard Codes
Hazard statements
H302 Harmful if swallowed 吞食有害 H302+H312+H332 H312 Harmful in contact with skin 皮肤接触有害 H318 Causes serious eye damage 严重伤害眼睛 H332 Harmful if inhaled 吸入有害 H400 Verytoxictoaquaticlife 对水生生物毒性非常大。 H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。 H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
Personal Protective Equipment	Eyeshields, Faceshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US) dust mask type N95 (US), Eyeshields, Gloves Eyeshields, Faceshields, Gloves, half-mask respirator (EU), half-mask respirator (US), multi-purpose combination respirator cartridge (US)
RTECS	XK7875000
Precautionary statements
P233 Keep container tightly closed. ?保持容器密闭。 P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。 P264+P265 P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。 P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。 P273 Avoid release to the environment. 避免释放到环境中。 P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。 P301+P312 P301+P312+P330 P301+P317 P301+P330+P331 P302+P352 P302+P352+P312+P362+P364 P304+P312 P304+P340 P304+P340+P312 P305+P351+P338 P305+P354+P338 P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。 P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服 P317 P319 P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。 P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。 P330 Rinse mouth. 漱口 P337+P313 P337+P317 P362+P364 P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。 P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。 P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Safety Statements

Risk Statements
R32 Contact with acids liberates very toxic gas 与酸接触释放出毒性很高的气体 R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害 R52/53
Storage condition	Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
UN Number	9092
Packing Group	III

用于形成新型二维 Cd-SCN 配位固体，该配位固体具有独特和可自行调节的方格状或人字形图案结构，这些结构对于获得科技实用性材料至关重要。

{ALD} Merck: 14,561

Beilstein: 3,IV,299

{ALF} In combination with CAN in t-butanol, epoxides are converted to thiiranes in high yield: Synthesis, 821 (1996). The same conversion can also be effected in the presence of SbCl3 in acetonitrile: Indian J. Chem., 38B, 605 (1999). CAN also promotes the direct conversion of activated aryl systems, e.g. indoles, pyrroles and N,N-dialkylanilines to aryl thiocyanates: Tetrahedron Lett., 40, 1195 (1999).

{uni_hamburg} Short: III/20a

{uni_hamburg} Short: III/20c

{ALF} Thiocyanogen bromide can be generated in situ by reaction with bromine in acetic acid, e.g. in the thiocyanation of N,N-dimethylaniline to 4-N,N-dimethylaminophenylisothiocyanate: Org. Synth. Coll., 2, 574 (1943).

{ALF} Also useful for the conversion of arylamines to thioureas either indirectly via benzoyl isothiocyanate: Org. Synth. Coll., 3, 735 (1955), or directly, but in lower yield, by reaction of ammonium thiocyanate with the amine in the presence of HCl: Org. Synth. Coll., 4, 180 (1963).

{ALD} Merck: 14,561

1762-95-4 AM04201000 Ammonium thiocyanate, solution 0,1 mol/l (0,1 N) 硫氰酸铵溶液，0,1 mol/l (0,1 N)

化学属性

Mol. Formula	CH4N2S
Mol. Weight	76.12
Melting Point	152-154 °C
Density	1.3
TSCA	Yes
Solubility	Soluble in water, ethanol, methanol, ammonia, and acetone. Practically insoluble in CHCl3 and ethyl acetate.
Flash Point	190 ºC
Stability	对湿度、光和空气敏感
Boiling Point	262.85 °C at 760 mmHg

*以上化合物性质及应用等信息仅供参考