triisopropylsilane

规格: 96% min
CAS: 6485-79-6
产品编号: Bellen00011945
MDL: MFCD00009657
品牌: Bellen
Chemical NameTriisopropylsilane
MDL NumberMFCD00009657
Synonym Triisopropylsilane {LY} Triisopropylsilane {} {LY} Triisopropylsilane {} {} {LY} Triisopropylsilane {} {} {} {LY} Triisopropylsilane {} {} {} {} {LY} Triisopropylsilane {} {} {} {} {} {LY} Triisopropylsilane {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triisopropylsilane {} {} {} {} {} {} {} {LY} Triisopropylsilane {} {} {} {} {} {} {} {} {LY} Triisopropylsilane {} {} {} {} {} {} {} {} {} {LY} Triisopropylsilane {} {} {} {} {} {} {} {} {} {} {LY} Triisopropylsilane {} {} {} {} {} {} {} {} {} {} {} {LY} Triisopropylsilane {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triisopropylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triisopropylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triisopropylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triisopropylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triisopropylsilane
CAS Number6485-79-6
Beilstein Registry Number1733718
EC Number250-023-7
PubChem Substance ID87577292
Chemical Name Translation三异丙基硅烷
Reaxys-RN1733718
InChIKeyYDJXDYKQMRNUSA-UHFFFAOYSA-N
LabNetwork Molecule IDLN00009319
InChIInChI=1S/C9H21Si/c1-7(2)10(8(3)4)9(5)6/h7-9H,1-6H3
Canonical SMILESCC([SiH](C(C)C)C(C)C)C
GHS Symbol
UN Number 1993
Risk Statements
  • R10 Flammable 易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
    Safety Statements
    • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
    • S36 Wear suitable protective clothing 穿戴适当的防护服；
      Signal word Warning
      WGK Germany3
      Precautionary statements
      • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
      • P233 Keep container tightly closed. ?保持容器密闭。
      • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
      • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
      • P241+P242+P243
      • P242 Use only non-sparking tools. 只能使用无火花工具。
      • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
      • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
      • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
      • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
      • P302+P352
      • P302+P352+P332+P313+P362+P364
      • P303+P361+P353
      • P304+P340
      • P305+P351+P338
      • P305+P351+P338+P337+P313
      • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
      • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
      • P332+P313
      • P333+P313
      • P337+P313
      • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
      • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
      • P370+P378
      • P403+
      • P403+P233
      • P403+P235
      • P405 Store locked up. 上锁保管。
      • P501 Dispose of contents/container to..… 处理内容物/容器.....
        Hazard statements
        • H226 Flammable liquid and vapour 易燃液体和蒸气
        • H315 Causes skin irritation 会刺激皮肤
        • H317 May cause an allergic skin reaction 可能导致皮肤过敏
        • H319 Causes serious eye irritation 严重刺激眼睛
        • H335 May cause respiratory irritation 可能导致呼吸道刺激
          Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
          Packing GroupIII
          Hazard Codes 3
          Storage condition 2-8°C {LY} 2-8°C Store at RT. {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C
          Hazard Class3
        • 大体积异丙基（与乙基相比）能实现选择性更高的还原反?应（例如，异头 C-苯基缩酮的 β-选择性还原），但是不会降低它们的活性（例如，三甲基硅醚的三氟甲烷?磺酸酮催化型还原醚化）。
        • 用于 Ni(O) N-杂环卡宾络合物催化的反式-1,2-二醇的高度非?对映选择性制备。
        • {ALD} Beilstein:4(3)1851
        • {ALFA} Selective silylation of primary OH groups in the presence of secondary has been carried out with this reagent in combination with CsF and imidazole: J. Organomet. Chem., 282, 155 (1985). See Appendix 4.
        • {ALF} Triethylsilane and triisopropylsilane have been studied as cation scavengers in the deprotection of peptides with TFA, and were found to give good results, with triisopropylsilane being particularly effective in trapping trityl cations in the TFA deprotection of cysteine containing peptides. The use of triisopropylsilane minimizes the risk of reduction of the indole nucleus in tryptophan-containing peptides: Tetrahedron Lett., 30, 2739 (1989). See Appendix 6.
        • {ALFA} Triethylsilane and triisopropylsilane have been studied as cation scavengers in the deprotection of peptides with TFA, and were found to give good results, with triisopropylsilane being particularly effective in trapping trityl cations in the TFA deprotection of cysteine containing peptides. The use of triisopropylsilane minimizes the risk of reduction of the indole nucleus in tryptophan-containing peptides: Tetrahedron Lett., 30, 2739 (1989). See Appendix 6.
        • {ALF} Selective silylation of primary OH groups in the presence of secondary has been carried out with this reagent in combination with CsF and imidazole: J. Organomet. Chem., 282, 155 (1985). See Appendix 4.
          • 6485-79-6 Bellen00011945 triisopropylsilane

          化学属性

          Mol. FormulaC9H22Si
          Mol. Weight158.36
          Density0.773
          Refractive index1.4340 to 1.4370
          Flash Point37°C(lit.)
          TSCANo
          Boiling Point84-86 °C at 35 mmHg
          Stability对湿度敏感
          Melting Point99°F
          Appearance 无色液体, B.P.84-85℃(35mmHg), F.P.35℃,d 0.773.nD201.4340 .本品易燃,有刺激性
          Danger-Level甲类

          *以上化合物性质及应用等信息仅供参考