(R)-2-amino-2-phenylethanol

规格: 96% min
CAS: 56613-80-0
产品编号: Bellen00013890
MDL: MFCD00008062
品牌: Bellen
Chemical Name(R)-(-)-2-Phenylglycinol
CAS Number56613-80-0
Alfabeta NamePHENYLGLYCINOL R2(())----
MDL NumberMFCD00008062
Synonym (R)-(-)-2-Amino-2-phenylethanol (R)-(-)-2-氨基-2-苯基乙醇;(R)-(-)-2-苯基-2-氨基乙醇 (R)-2-Amino-2-phenylethanol, D-(−)-α-Phenylglycinol (R)-2-氨基-2-苯乙醇 D-(-)-α-苯甘氨醇 (R)-2-氨基-2-苯乙醇 D-(-)-α-苯甘氨醇 D-(-)-α-苯甘氨醇 R-苯甘氨醇,右旋苯甘氨醇,2-苯甘氨酸
Beilstein Registry Number2935848
PubChem Substance ID87575300
EC Number260-287-5
Reaxys-RN2935848
Chemical Name TranslationD-苯甘氨醇
LabNetwork Molecule IDLN00009350
InChIKeyIJXJGQCXFSSHNL-UHFFFAOYSA-N
GHS Symbol
Warnings IRRITANT
WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
    Precautionary statements
    • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P302+P350
    • P302+P352+P332+P313+P362+P364
    • P305+P351+P338
    • P305+P351+P338+P337+P313
    • P332+P313
    • P337+P313
    • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
      Safety Statements
      • S22 Do not breathe dust 不要吸入粉尘；
      • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
      • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
      • S37 Wear suitable gloves 戴适当手套；
        Risk Statements
        • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
          Storage condition 0-10°C Air Sensitive
        • 作为合成的结构单元使用的手性 β-氨基醇。
        • 本氨基醇可用于由三氟丙酮酸乙酯制备手性亚胺或噁唑烷。然后，可将这些中间体用于合成 α-三氟甲基脯氨酸的两种对映体。
        • {SA} Tetrahedron Lett. 45 , 5287, (2004)
        • {ALFA} Condensation with glutaraldehyde gives a useful intermediate in asymmetric synthesis of alkaloids: Org. Synth. Coll., 9, 176 (1998):
        • {ALD} Beilstein:13(4)1835
        • {ALF} Condensation with glutaraldehyde gives a useful intermediate in asymmetric synthesis of alkaloids: Org. Synth. Coll., 9, 176 (1998):
        • {TRC} Kristensen, T. E. et al.: Eur. J. Org. Chem., 30, 5185 (2009); Liu, W. et al.: You. Xua., 26, 518 (2006);
        • {ALF} Starting material for the enantioselective synthesis of 2,6-disubstituted piperazines: Synthesis, 833 (1996), and for chiral ɑ-amino phosphonates: Org. Synth., 75, 19 (1997).
        • {ALFA} Starting material for the enantioselective synthesis of 2,6-disubstituted piperazines: Synthesis, 833 (1996), and for chiral ɑ-amino phosphonates: Org. Synth., 75, 19 (1997).
          • 56613-80-0 Bellen00013890 (R)-2-amino-2-phenylethanol

          化学属性

          Mol. FormulaC8
          Mol. Weight137
          Melting Point75-77
          TSCANo
          Density1.104
          Stability对空气敏感

          *以上化合物性质及应用等信息仅供参考