Phosphine, tris(2-methylphenyl)-

规格: 96% min
CAS: 6163-58-2
产品编号: Bellen00015335
MDL: MFCD00008514
品牌: Bellen
Chemical NameTri(o-tolyl)phosphine
Alfabeta NameTRITOLYLPHOSPHINE M()-
Synonym Tri(2-methylphenyl)phosphine {LY} Tri(2-methylphenyl)phosphine {} {LY} Tri(2-methylphenyl)phosphine {} {} {LY} Tri(2-methylphenyl)phosphine {} {} {} {LY} Tri(2-methylphenyl)phosphine {} {} {} {} {LY} Tri(2-methylphenyl)phosphine {} {} {} {} {} {LY} Tri(2-methylphenyl)phosphine {} {} {} {} {} {} {LY} Tri(2-methylphenyl)phosphine {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {LY} Tri(2-methylphenyl)phosphine {} {} {} {} {} {} {} {} {LY} Tri(2-methylphenyl)phosphine {} {} {} {} {} {} {} {} {} {LY} Tri(2-methylphenyl)phosphine {} {} {} {} {} {} {} {} {} {} {LY} Tri(2-methylphenyl)phosphine {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} Tri(2-methylphenyl)phosphine {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tri(2-methylphenyl)phosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tri(2-methylphenyl)phosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tri(2-methylphenyl)phosphine {} {} {} {} {} {} {}
EC Number228-193-9
Beilstein Registry Number661212
PubChem Substance ID80271
Reaxys-RN661212
Chemical Name Translation三(邻甲苯基)膦
InChIKeyCOIOYMYWGDAQPM-UHFFFAOYSA-N
LabNetwork Molecule IDLN00173237
InChIInChI=1S/C21H21P/c1-16-10-4-7-13-19(16)22(20-14-8-5-11-17(20)2)21-15-9-6-12-18(21)3/h4-15H,1-3H3
MDL NumberMFCD00008514
CAS Number6163-58-2
Canonical SMILESCC1=C(C=CC=C1)P(C(C=CC=C2)=C2C)C(C=CC=C3)=C3C
GHS Symbol
Warnings IRRITANT
Signal word Warning
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S37 Wear suitable gloves 戴适当手套；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
    Risk Statements
    • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
      Precautionary statements
      • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
      • P305+P351+P338
      • P305+P351+P338+P337+P313
      • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
        Hazard statements
        • H315 Causes skin irritation 会刺激皮肤
        • H319 Causes serious eye irritation 严重刺激眼睛
        • H335 May cause respiratory irritation 可能导致呼吸道刺激
          Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
          Hazard Codes Xi
          Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitr
        • 配体，用于钌催化的醇的氨基化反应。
        • {uni_hamburg} Short: III/10b
        • {uni_hamburg} Short: EINECS
        • {ALF} Preferred phosphine ligand for use in combination with Pd salts in the Heck-type coupling reactions of vinylic halides. For examples, see Palladium(II)­ acetate, 10516. For a review of the Heck reaction, see: Org. React., 27, 345 (1982).
        • {ALF} The Pd-catalyzed amination of bromoarenes with 1-Boc-piperazine, L13363, in the presence of this ligand, provides a route to arylpiperazines of potential pharmacological interest: Tetrahedron Lett., 39, 2219 (1998).
        • {ALD} Beilstein: 16,III,835
          • 6163-58-2 Bellen00015335 Phosphine, tris(2-methylphenyl)-

          化学属性

          Density1.589
          TSCAYes
          Boiling Point412.4±44.0 °C at 760 mmHg
          Mol. FormulaC21H21P
          Mol. Weight304.37
          Appearance white xtl.
          Stabilityair sensitive
          Melting Point123-125°C

          *以上化合物性质及应用等信息仅供参考