2,4-Dinitrophenylhydrazine hydrochloric acid solution2,4-二硝基苯肼

规格:
CAS: 119-26-6
产品编号: Bellen10000458
MDL: MFCD00007578
品牌: Bellen
Chemical Name2,4-DINITROPHENYLHYDRAZINE
MDL NumberMFCD00007578
CAS Number119-26-6
PubChem Substance ID87567460
Beilstein Registry Number615586
Synonym 2,4-二硝基苯肼,溶液 1-(2,4-DINITROPHENYL)HYDRAZINE 2,4-Dnph 2,4-DinitrophenylHydrazineForSynthesis 2,4-Dinitrophenylhydrazine, moist with water 2,4-dinitrophenyl-hydrazin 2,4-DNPH 1-Hydrazino-2,4-dinitrobenzene 2,4-DinitrophenylHydrazineGr 2,4-二硝基苯胼 DNPH 二硝基苯肼 2,4-DINITROPHENYLHYDRAZINE, MOIST. WITH WATER (H2O ~50%) Dnp-hydrazine 2,4-二硝苯肼 2.4一二硝基苯肼 二硝基苯肼、2,4-二硝基酚联胺 2 2,4-Dinitrofenylhydrazin 2,4-二硝苯基 DNP 2,4-DINITROPHENYLHYDRAZINE HYDROCHLORIC ACID SOLTUION Hydrazine,(2,4-dinitrophenyl)- 2,4-二硝基苯肼(0407禁空运) 2,4-二硝基酚聯胺 2,4-二硝基苯肼 2 4-DINITROPHENYLHYDRAZINE MOIST. WITH 2,4-Dinitrophenylhydrazine99% 4-二硝基苯肼 1,4-二硝苯肼 (2,4-dinitrophenyl)-hydrazin 2,4-DINITROPHENYLHYDRAZINE 2,4-DINITROPHENYLHYDRAZINE 99+% GR 2,4-二硝基苯肼, 97%(DRY WT.), WATER CA 30-40% 1-(2,4-Dinitrophenyl)hydrazine; DNP DINITROPHENYL HYDRAZINE 2,4-Dinitrophenylhydrazine 2,4-二硝基苯肼盐酸盐 溶液 2，4-二硝基苯肼 二硝基苯肼; 2,4-二硝基酚联胺
EC Number204-309-3
Merck Number3283
Reaxys-RN615586
Chemical Name Translation2,4-二硝基苯肼
Wiswesser Line NotationZMR BNW DNW
LabNetwork Molecule IDLN00194746
InChIInChI=1S/C6H6N4O4/c7-8-5-2-1-4(9(11)12)3-6(5)10(13)14/h1-3,8H,7H2
GHS Symbol
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 450 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   41,1469,1981

TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NCNSA6 National Academy of Sciences, National Research Council,
   Chemical-Biological Coordination Center, Review.  (Washington, DC)
   Volume(issue)/page/year: 5,25,1953

TYPE OF TEST            : DNA repair
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 4 ug/well
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 133,161,1984

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Microorganism - not otherwise specified
DOSE/DURATION           : 6 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 173,233,1986

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 50 ug/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 44,9,1977

TYPE OF TEST            : Unscheduled DNA synthesis
TEST SYSTEM             : Rodent - rat Liver
DOSE/DURATION           : 50 mg/L
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   26,147,1995

TYPE OF TEST            : DNA damage
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 1900 umol/kg
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   41,1469,1981

WGK Germany2
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H228 Flammable solid 易燃固体
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H302 Harmful if swallowed 吞食有害
    Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
    Precautionary statements
    • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
    • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
    • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
    • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
    • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
    • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P301+P312+P330
    • P301+P330+P331+P310
    • P305+P351+P338+P310
    • P305+P351+P338+P337+P313
    • P308+P313
    • P337+P313
    • P403+P233
    • P501 Dispose of contents/container to..… 处理内容物/容器.....
      Signal word Danger
      RTECSMV3325000
      Safety Statements
      • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
      • S35 This material and its container must be disposed of in a safe way 该物料及其容器必须以安全方式处置；
      • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
      • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
      • S48 Keep wet with ... (appropriate material to be specified by the manufacturer) 用……（生产厂家指定的适当物料）保持湿润；
        Packing GroupII
        UN Number 2924 3380 UN1325
        Risk Statements
        • R1 Explosive when dry 干燥时易爆
        • R11 Highly flammable 非常易燃
        • R22 Harmful if swallowed 吞咽有害
        • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
          Hazard Codes 4.1 F F,Xn
          Hazard Class4.1
          Storage condition 2-8°C 储存温度2-8°C
          Warnings 危化品目录(2015)
          Restrict 危险品
        • 用作光度法测定醛，酮类的显色剂，薄层色谱法测定醛，酮类的显色试剂。还用作醛和酮的紫外衍生试剂，用于有机合成及炸药制造.
        • {ALF} 2,4-Dinitrophenylhydrazones of aryl-alkyl- or diaryl-ketones are readily hydrogenolyzed to methylene compounds in an alternative to the Wolff-Kishner or Clemmensen methods: J. Org. Chem., 36, 737 (1971).
        • {ALF} Reagent for the identification and determination of ketones: Anal. Biochem., 49, 436 (1972); Anal. Chim. Acta, 69, 481 (1974).
        • {ALD} Merck: 14,3283
        • Beilstein: 15,IV,380
        • {ALF} For cleavage of 2,4-dinitrophenylhydrazones by TiCl3, see: J. Org. Chem., 40, 1502 (1975), and by Fe(NO3)3 on a clay support, see: Synthesis, 439 (1985). A particularly convenient method is by exchange with aqueous acetone in the presence of Amberlyst. 15: J. Chem. Soc., Perkin 1, 2563 (1988).
        • {ALD} Merck: 14,3283
          • 119-26-6 Bellen10000458 2,4-Dinitrophenylhydrazine hydrochloric acid solution2,4-二硝基苯肼

          化学属性

          Mol. FormulaC6H6N4O4
          Mol. Weight198
          Refractive indexn20/D 1.374
          Density0.843
          Melting Point197-200
          TSCAYes
          Solubility略溶于水
          Flash Point14 °C
          Stability对空气和光敏感

          *以上化合物性质及应用等信息仅供参考