Chemical Name | 1,3-Dibromo-5-fluorobenzene |
CAS Number | 1435-51-4 |
Alfabeta Name | DIBROMOFLUOROBENZENE 135---, |
MDL Number | MFCD00061119 |
EC Number | 250-023-7 |
Beilstein Registry Number | 2353462 |
PubChem Substance ID | 137003 |
Synonym |
1,3-Dibromo-5-fluorobenzene
{LY} 1,3-Dibromo-5-fluorobenzene
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Reaxys-RN | 2353462 |
Chemical Name Translation | 1,3-二溴-5-氟苯 |
InChIKey | ASWYHZXKFSLNLN-UHFFFAOYSA-N |
LabNetwork Molecule ID | LN00008409 |
Canonical SMILES | FC1=CC(Br)=CC(Br)=C1 |
InChI | InChI=1S/C6H3Br2F/c7-4-1-5(8)3-6(9)2-4/h1-3H |
Warnings |
IRRITANT |
Signal word |
Warning |
GHS Symbol
WGK Germany | 3 |
Safety Statements | |
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S37 Wear suitable gloves 戴适当手套;
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Risk Statements | |
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
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Precautionary statements | |
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P350
- P302+P352
- P302+P352+P332+P313+P362+P364
- P304+P340
- P305+P351+P338
- P305+P351+P338+P337+P313
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
- P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
- P332+P313
- P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
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Personal Protective Equipment |
Eyeshields, Gloves |
Hazard Codes |
Xi |
Hazard statements | |
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
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Storage condition |
Store at room temperature
{LY} Store at room temperature
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{ALF} Lithiation with lithium 2,2,6,6-tetramethylpiperidide at -75o occurs at the 4-position, affording 2,4-dibromo-6-fluorobenzoic acid in 81% yield after carboxylation: Tetrahedron Lett., 37, 6551 (1996).