N-Methyl-N-(trimethylsilyl)trifluoroacetamideN-甲基-N-(三甲基硅烷基)三氟乙酰胺

规格:
CAS: 24589-78-4
产品编号: Bellen10002372
MDL: MFCD00000411
品牌: Bellen
Chemical NameN-Methyl-N-(trimethylsilyl)trifluoroacetamide
CAS Number24589-78-4
Alfabeta NameMETHYLTRIMETHYLSILYLTRIFLUOROACETAMIDE NN---
MDL NumberMFCD00000411
Synonym Acetamide, 2,2,2-trifluoro-N-methyl-N-(trimethylsilyl)- N-Methyl-N-trimethylsilyltrifluoroacetamide trifluoroacetyl(trimethylsilyl)methyl-amine N-Methyl-N-(trimethylsilyl)trifluoracetamid N- N-三甲基硅基-N-甲基三氟乙酰胺 MSTFA N-methyl-N-trimethylsilyltrifluoroacetamide MSTFA N-Trimethylsilyl-N-methyltrifluoroacetamide 2,2,2-Trifluoro-N-methyl-N-(trimethylsilyl)acetamide N-methyl-n-trimethylsilyl-trifluoroacetamide 含 1% 三甲基氯硅烷的 N-甲基-N-(三甲基硅烷基)三氟乙酰胺 Mstfa N-三甲基硅基-N-甲基三氟乙酰胺 MSTFA 2,2,2-Trifluor-N-methyl-N-(trimethylsilyl)-acetam N-Methyl-N-trimethylsilyl-trifluoracetamid N-Methyl-N-(trimethylsilyl)trifluoroacetamide trifluoroacetyl(trimethylsilyl)methylamine
PubChem Substance ID87572684
EC Number246-331-6
Beilstein Registry Number1941550
Reaxys-RN1941550
Chemical Name TranslationN-甲基-N-三甲基硅基三氟乙酰胺
Wiswesser Line NotationFXFFVN1&-SI-1&1&1
InChIKeyMSPCIZMDDUQPGJ-UHFFFAOYSA-N
LabNetwork Molecule IDLN00118272
GHS Symbol
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1 gm/kg
TOXIC EFFECTS :
   Immunological Including Allergic - decreased immune response
REFERENCE :
   StoGD# Personal Communication from G.D. Stoner, Dept. of Community Medicine,
   School of Medicine, Univ. of California, La Jolla, CA 92037, May 25, 1975 
   Volume(issue)/page/year: 27MAY1975

Warnings MOISTURE SENSITIVE, FLAMMABLE
WGK Germany3
Hazard Codes
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
    Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
    RTECSAC9800000
    Precautionary statements
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
    • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
    • P501 Dispose of contents/container to..… 处理内容物/容器.....
    • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P305+P351+P338
    • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
    • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
    • P370+P378
    • P305+P351+P338+P337+P313
      Signal word
      UN Number
      Risk Statements
      • R10 Flammable 易燃
      • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
        Safety Statements
        • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
        • S33 Take precautionary measures against static discharges 对静电采取预防措施；
        • S37 Wear suitable gloves 戴适当手套；
        • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
        • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
        • S7 Keep container tightly closed 保存在严格密闭容器中；
        • S36 Wear suitable protective clothing 穿戴适当的防护服；
        • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
          Storage condition Moisture Sensitive
          Packing GroupIII
          Hazard Class3
        • A new metabolite of Famprofazone in humans.
        • {TRC} Oh, E., et al.: Xenobiotica, 22, 377 (1992),
        • {TRC} Caldwell, J., et al.: Biochem. J., 129, 11 (1972),
        • {uni_hamburg} Short: III/35F
        • {SA} 4. J. Heberle, G. Simchen Silylating Agents, 2nd ed. Buchs , (1995)
        • {ALFA} Powerful silylating agent for a wide range of functional groups: J. Chromat., 115, 591 (1975); 134, 387 (1977); Chromatographia, 9, 440 (1976). See Appendix 4.
          • 24589-78-4 Bellen10002372 N-Methyl-N-(trimethylsilyl)trifluoroacetamideN-甲基-N-(三甲基硅烷基)三氟乙酰胺

          化学属性

          Mol. FormulaCF3CON(CH3)Si(CH3)3
          Mol. Weight199
          Boiling Point130-132
          TSCAT
          Refractive index1.3780 to 1.3820
          Density1.075
          Flash Point26°C(lit.)
          Vapor Density>;1 (vs air)
          Vapor Pressure8.8 mmHg ( 27 °C)
          pH:A

          *以上化合物性质及应用等信息仅供参考