Phenyltrimethylammonium tribromide苯基三甲基三溴化铵

规格:
CAS: 4207-56-1
产品编号: Bellen10002493
MDL: MFCD00011789
品牌: Bellen
Chemical NameTrimethylphenylammonium Tribromide
Synonym Mono(N,N,N-trimethylbenzenaminium) tribromide {LY} Mono(N,N,N-trimethylbenzenaminium) tribromide X-TractElute hydroxide of phenyltrimethylammonium iodide of phenyltrimethylammonium phenyltrimethylammonium phenyltrimethylammonium acetate phenyltrimethylammonium benzenesulfonate phenyltrimethylammonium bromide phenyltrimethylammonium chloride phenyltrimethylammonium tosylate phenyltrimethylammonium tribromide phenyltrimethylammonium, tri(methyl-3(2)H)-labeled cpd trimethyl-d9-anilinium hydroxide trimethylanilinium trimethylanilinium iodide trimethylphenylammonium hydroxide trimethylphenylammonium iodide {} {LY} Mono(N,N,N-trimethylbenzenaminium) tribromide {} {} {LY} Mono(N,N,N-trimethylbenzenaminium) tribromide {} {} {} {LY} Mono(N,N,N-trimethylbenzenaminium) tribromide {} {} {} {} {LY} Mono(N,N,N-trim
CAS Number4207-56-1
EC Number224-127-8
Beilstein Registry Number3919459
MDL NumberMFCD00011789
PubChem Substance ID77880
Reaxys-RN3919459
Chemical Name Translation苯基三甲基三溴化铵
InChIKeyPRXNKYBFWAWBNZ-UHFFFAOYSA-N
LabNetwork Molecule IDLN00191249
InChIInChI=1S/C9H14N.Br3/c1-10(2,3)9-7-5-4-6-8-9;1-3-2/h4-8H,1-3H3;/q+1;-1
Canonical SMILESC[N+](C)(C1=CC=CC=C1)C.Br[Br-]Br
GHS Symbol
Signal word Danger
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
    Risk Statements
    • R34 Causes burns 会导致灼伤
    • R37 Irritating to respiratory system 刺激呼吸道
      Precautionary statements
      • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
      • P301+P330+P331
      • P301+P330+P331+P310
      • P302+P361+P354
      • P303+P361+P353
      • P303+P361+P353+P310+P363
      • P304+P340
      • P304+P340+P310
      • P305+P351+P338
      • P305+P351+P338+P310
      • P305+P354+P338
      • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
      • P316
      • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
      • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
      • P405 Store locked up. 上锁保管。
      • P501 Dispose of contents/container to..… 处理内容物/容器.....
        Hazard statements
        • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
          Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
          Packing GroupII
          UN Number 1759 3261 UN 3261 8/PG 2
          Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
          Hazard Codes 8 C
          Hazard Class8
        • 溴化试剂，用于在1,2-位把溴增加到α,β-不饱和化合物的双键上。
        • {ALF} Reagent for the selective ɑ-bromination of acetals with good stability and solubility in organic solvents such as THF: Tetrahedron Lett., 24 (1959); Bull. Soc. Chim. Fr., 1822 (1961); 90 (1962). For example of use in a one-pot ɑ-bromoacetalization of carbonyl com
        • {ALF} For example of selective ɑ-monobromination of ketones, see: Org. Synth. Coll., 6, 175 (1988). Silyl enol ethers are also ɑ-brominated with this reagent to give ɑ-bromo enones: Synlett, 651 (1994).
        • {uni_hamburg} Short: EINECS
        • {ALF} Tosylhydrazones have been oxidized to N-alkenyl-N'-tosyldiazenes: J. Org. Chem., 39, 826 (1974).
        • {ALF} Reagent for the selective ɑ-bromination of acetals with good stability and solubility in organic solvents such as THF: Tetrahedron Lett., 24 (1959); Bull. Soc. Chim. Fr., 1822 (1961); 90 (1962). For example of use in a one-pot ɑ-bromoacetalization of carbonyl compounds in high yields, see: Synthesis, 309 (1982).
        • {uni_hamburg} Short: II/27B
        • {ALD} Beilstein:12,159
        • {ALF} Catalyses the aziridination of alkenes by Chloramine-T trihydrate, A12044: J. Am. Chem. Soc., 120, 6844 (1998).
          • 4207-56-1 Bellen10002493 Phenyltrimethylammonium tribromide苯基三甲基三溴化铵

          化学属性

          Mol. FormulaC9H14Br3N
          Mol. Weight375.93
          Density1.443
          Melting Point110-115°C
          TSCAYes
          Solubility不溶
          Stability对光敏感

          *以上化合物性质及应用等信息仅供参考