4-Nitrobenzaldehyde4-硝基苯甲醛

规格:
CAS: 555-16-8
产品编号: Bellen10002787
MDL: MFCD00007346
品牌: Bellen
Chemical Name4-Nitrobenzaldehyde
Synonym 4-Nitrobenzaldehyde {LY} 4-Nitrobenzaldehyde {} {LY} 4-Nitrobenzaldehyde {} {} {LY} 4-Nitrobenzaldehyde {} {} {} {LY} 4-Nitrobenzaldehyde {} {} {} {} {LY} 4-Nitrobenzaldehyde {} {} {} {} {} {LY} 4-Nitrobenzaldehyde {} {} {} {} {} {} {LY} 4-Nitrobenzaldehyde {} {} {} {} {} {} {} {LY} 4-Nitrobenzaldehyde {} {} {} {} {} {} {} {} {LY} 4-Nitrobenzaldehyde {} {} {} {} {} {} {} {} {} {LY} 4-Nitrobenzaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Nitrobenzaldehyde {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Nitrobenzaldehyde {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Nitrobenzaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Nitrobenzaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Nitrobenzaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Nitrobenzaldehyde {} {} {} {} {} {} {} {} {} {} {} {}
CAS Number555-16-8
EC Number209-084-5
Beilstein Registry Number386796
MDL NumberMFCD00007346
Merck Number6587
PubChem Substance ID541
Reaxys-RN386796
Chemical Name Translation对硝基苯甲醛
Wiswesser Line NotationWNR DVH
InChIKeyBXRFQSNOROATLV-UHFFFAOYSA-N
LabNetwork Molecule IDLN00008497
InChIInChI=1S/C7H5NO3/c9-5-6-1-3-7(4-2-6)8(10)11/h1-5H
Canonical SMILESO=CC1=CC=C([N+]([O-])=O)C=C1
GHS Symbol
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 545 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   HINEL* Hine Laboratories Reports.  (San Francisco, CA)
   Volume(issue)/page/year: AF33(657)-11756,1964

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 4700 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Lungs, Thorax, or Respiration - cyanosis
   Blood - normocytic anemia
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 24(9),15,1959

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 16 gm/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Lungs, Thorax, or Respiration - cyanosis
   Blood - normocytic anemia
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 24(9),15,1959

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 500 ug/plate
REFERENCE :
   SAIGBL Sangyo Igaku.  Japanese Journal of Industrial Health.  (Nippon Sangyo
   Eisei Igakkai, Kosu Eisei Bldg., 1-29-8, Shinjuku, Shinjuku-ku, Tokyo 160,
   Japan)  V.1-    1959-  Volume(issue)/page/year: 29,34,1987

TYPE OF TEST            : DNA repair
TEST SYSTEM             : Bacteria - Bacillus subtilis
DOSE/DURATION           : 500 ug/disc
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 170,11,1986

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 100 ug/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 170,11,1986

Signal word
WGK Germany2
Safety Statements
  • S24 Avoid contact with skin 避免皮肤接触；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
    Risk Statements
    • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
      Precautionary statements
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
      • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
      • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
      • P501 Dispose of contents/container to..… 处理内容物/容器.....
      • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P305+P351+P338
      • P332+P313
      • P273 Avoid release to the environment. 避免释放到环境中。
      • P305+P351+P338+P337+P313
      • P337+P313
      • P302+P350
      • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
        Hazard statements
        • H317 May cause an allergic skin reaction 可能导致皮肤过敏
        • H319 Causes serious eye irritation 严重刺激眼睛
        • H303 May be harmfully swallowed 吞食可能有害
          RTECSCU7350000
          Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
          Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen Air Sensitive {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitro
          Hazard Codes Xi
        • 检验芳香族伯胺(根据伯胺与本品所形成的缩合物的熔点检别)，有机合成。该品为染料、医药等有机合成的中间体，在医药工业中用来生产对 硝基苯丁烯酮（氯霉素）。
        • {uni_hamburg} Short: II/27B
        • {ALD} Merck:14,6587
        • {ALD} Merck:14,6587
        • Beilstein:7(4)598
        • {uni_hamburg} Short: III/20a
        • {ALF} 1,3-Oxathiolanes (see 2-Mercaptoethanol, A15890) can be selectively cleaved in the presence of dithioacetals using 4-nitrobenzaldehyde catalyzed by TMS-OTf: J. Chem. Soc., Chem. Commun., 1937 (1994). This combination has been used for conversion of thioketones to ketones: Tetrahedron Lett., 36, 2277 (1995).
          • 555-16-8 Bellen10002787 4-Nitrobenzaldehyde4-硝基苯甲醛

          化学属性

          Mol. FormulaC7H5NO3
          Mol. Weight151.12
          Density1.338
          Melting Point103-106°C
          TSCAYes
          Solubility不溶于水，微溶于乙醚，易溶于乙醇、苯。
          Stability对空气敏感
          Boiling Point299.6°C at 760 mmHg
          RedoxOxidation

          *以上化合物性质及应用等信息仅供参考