Hexabutyldistannane六正丁基二锡

规格:
CAS: 813-19-4
产品编号: Bellen10003267
MDL: MFCD00009417
品牌: Bellen
Chemical NameHexabutylditin
Synonym 1,1,1,2,2,2-Hexabutyl-distannane BIS[TRIBUTYLTIN(IV)] Bis(tri-n-butyltin) Bis(tributyltin) Bis-(tributylzinn) Distannane, hexabutyl- Distannane,hexabutyl- HEXABUTYLDISTANNANE HEXABUTYLDITIN 97+% Hexa-n-butyldistannane Hexa-n-butylditin, min. 95% Hexa-n-butylditin,min.95% Hexabutyldistannane, Hexabutylditin Hexabutyldistannane; Hexabutylditin Hexabutylditin {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
CAS Number813-19-4
PubChem Substance ID6327815
EC Number212-383-3
Beilstein Registry Number3605476
MDL Number-
Chemical Name Translation六正丁基二锡
InChIKeyREDSKZBUUUQMSK-UHFFFAOYSA-N
LabNetwork Molecule IDLN00009522
InChIInChI=1S/6C4H9.2Sn/c6*1-3-4-2;;/h6*1,3-4H2,2H3;;
Canonical SMILES-
GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H301 Toxic if swallowed 吞食有毒
  • H312 Harmful in contact with skin 皮肤接触有害
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
    Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
    Hazard Codes 6.1 T,N
    Precautionary statements
    • P273 Avoid release to the environment. 避免释放到环境中。
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P301+P310
    • P305+P351+P338
    • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
    • P501 Dispose of contents/container to..… 处理内容物/容器.....
      Signal word Danger
      UN Number 2788 UN 2788 6.1/PG 1 UN2788
      Risk Statements
      • R21 Harmful in contact with skin 与皮肤接触有害
      • R25 Toxic if swallowed 吞咽有毒
      • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
      • R48/23/25
      • R50/53
        Safety Statements
        • S35 This material and its container must be disposed of in a safe way 该物料及其容器必须以安全方式处置；
        • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
        • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
        • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
        • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
          Storage condition +4°C, Hygroscopic 4 4°C, Hygroscopic Air & Moisture Sensitive Freezer (-20°C) 对空气和湿度敏感，密封保存。
          Packing GroupIII
          Hazard Class6.1
        • 用于甲锡烷化芳基卤的试剂．
        • {ALF} Brings about the deoxygenation of amine oxides: Synthesis, 55 (1987), and the photo-desulfurisation of 1,3-dithiole-2-thiones to tetrathiafulvalenes: J. Am. Chem. Soc., 98, 7440 (1976).
        • {ALF} Source of on thermolysis or photolysis of tributylstannyl radicals, avoiding the problems sometimes attributable to the hydrogen donor capability of Tri-n-butyl­tin hydride, A13298.ɑ-Iodo-ketones or esters with a suitably-placed double bond undergo radical cyclizations on UV irradiation in the presence of a catalytic amount of the distannane: Tetrahedron Lett., 28, 2477 (1987); J. Org. Chem., 54, 1826, 3140 (1989). Compare analogous reductive cyclizations using the tin hydride. Improved conditions have been developed for generation of the tributylstannyl radical by mild UV irradiation in the presence of a triplet sensitizer (e.g. 4'-Methoxyacetophenone, A11162), allowing selective C-C bond forming reactions to be performed under free-radical conditions: Synlett, 287 (1993).
        • {uni_hamburg} Short: III/35C4
        • {SA} Tetrahedron Lett. 29 , 6893, (1988)
        • {ALF} Source of on thermolysis or photolysis of tributylstannyl radicals, avoiding the problems sometimes attributable to the hydrogen donor capability of Tri-n-butyl­tin hydride, A13298.ɑ-Iodo ketones or esters with a suitably-placed double bond undergo radical cyclizations on UV irradiation in the presence of a catalytic amount of the distannane: Tetrahedron Lett., 28, 2477 (1987); J. Org. Chem., 54, 1826, 3140 (1989). Compare analogous reductive cyclizations using the tin hydride. Improved conditions have been developed for generation of the tributylstannyl radical by mild UV irradiation in the presence of a triplet sensitizer (e.g. 4'-Methoxyacetophenone, A11162), allowing selective C-C bond forming reactions to be performed under free-radical conditions: Synlett, 287 (1993).
        • {ALF} Brings about the deoxygenation of amine oxides: Synthesis, 55 (1987), and the photo-desulfurization of 1,3-dithiole-2-thiones to
          • 813-19-4 Bellen10003267 Hexabutyldistannane六正丁基二锡

          化学属性

          Mol. FormulaC₂₄H₅₄Sn₂
          Mol. Weight580.11
          Refractive indexn20/D 1.512(lit.)
          Density1.148
          Flash Point-
          TSCANo
          Boiling Point-
          Stability对空气敏感，对湿度敏感
          pH:A

          *以上化合物性质及应用等信息仅供参考