Chemical Name | [(methoxymethyl)(phenyl)phosphoroso]benzene |
MDL Number | MFCD00015451 |
CAS Number | 4455-77-0 |
Synonym |
(Methoxymethyl)diphenylphosphine oxide
{LY} (Methoxymethyl)diphenylphosphine oxide
{} {LY} (Methoxymethyl)diphenylphosphine oxide
{} {} {LY} (Methoxymethyl)diphenylphosphine oxide
{} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide
{} {} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide
{} {} {} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide
{} {} {} {} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide
{} {} {} {} {} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide
{} {} {} {} {} {} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide
{} {} {} {} {} {} {} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide
{} {} {} {} {} {} {} {} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide
{} {} {} {} {} {} {} {} {} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide
{} {} {} {} {} {} {} {} {} {} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide
{} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide
{} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (Me |
PubChem Substance ID | 78203 |
Beilstein Registry Number | 649558 |
EC Number | 224-704-4 |
Chemical Name Translation | (甲氧基甲基)二苯基磷氧 |
Reaxys-RN | 649558 |
InChIKey | OEPKDBQOTLDTNC-UHFFFAOYSA-N |
LabNetwork Molecule ID | LN00222937 |
InChI | InChI=1S/C14H15O2P/c1-16-12-17(15,13-8-4-2-5-9-13)14-10-6-3-7-11-14/h2-11H,12H2,1H3 |
Canonical SMILES | COCP(C1=CC=CC=C1)(C2=CC=CC=C2)=O |
GHS Symbol
Hazard statements | |
- H302 Harmful if swallowed 吞食有害
|
WGK Germany | 3 |
RTECS | SZ0199360 |
Personal Protective Equipment |
dust mask type N95 (US), Eyeshields, Gloves |
Signal word |
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Safety Statements | |
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Risk Statements | |
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R22 Harmful if swallowed 吞咽有害
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Hazard Codes |
Xn |
Precautionary statements | |
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
- P301+P312
- P301+P312+P330
- P301+P317
- P330 Rinse mouth. 漱口
- P501 Dispose of contents/container to..… 处理内容物/容器.....
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TYPE OF TEST : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE : Oral
SPECIES OBSERVED : Rodent - mouse
DOSE/DURATION : 1500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
KHFZAN Khimiko-Farmatsevticheskii Zhurnal. Chemical Pharmaceutical Journal.
For English translation, see PCJOAU. (V/O Mezhdunarodnaya Kniga, 113095
Moscow, USSR) V.1- 1967- Volume(issue)/page/year: 24(4),22,1990
Storage condition |
2-8°C, protect from light, stored under nitrogen
{LY} 2-8°C, protect from light, stored under nitrogen
{} {LY} 2-8°C, protect from light, stored under nitrogen
{} {} {LY} 2-8°C, protect from light, stored under nitrogen
{} {} {} {LY} 2-8°C, protect from light, stored under nitrogen
{} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen
{} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen
{} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen
{} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen
{} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen
{} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen
{} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen
{} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen
{} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitr |
{ALF} Horner olefination with aldehydes and ketones gives vinyl ethers (and hence higher aldehydes). The method is reported to be superior to the Wittig alternative. The two diastereoisomeric adducts can also be isolated and each converted to a single stereoisomer of the enol ether: J. Chem. Soc., Perkin 1, 3099 (1979):