Bis(acetonitrile)dichloropalladium(II)双(乙腈)二氯化钯(II)

规格:
CAS: 14592-56-4
产品编号: Bellen10003531
MDL: MFCD00013122
品牌: Bellen
Chemical NameBis(acetonitrile)dichloropalladium(II)
Synonym bis(acetonitrile)dichloropalladium TRANS-DICHLOROBIS(ACETONITRILE)PALLADIUM BIS(ACETONITRILE)PALLADIUM(II) DICHLORIDE 反式双(乙腈)氯化钯(II) 氯化钯(II)二乙腈络合物 双乙腈氯化钯 DICHLOROBIS(ACETONITRILE)PALLADIUM(III) Palladium, bis(acetonitrile)dichloro- BIS(ACETONITRILE)PALLADIUM(II) CHLORIDE TRANS-BIS(ACETONITRILE)PALLADIUM(II) CHLORIDE 双(乙腈)二氯钯(II), PD 40.5% PALLADIUM DICHLOROBIS(ACETONITRILE) bis (acetontrile) dichloropalladium (II) DICHLOROBIS(ACETONITRILE)PALLADIUM(II) Dichlorobis(acetoni Bis(acetonitrile)dichloropalladium(II) 二乙腈基二氯化钯 双(乙腈)二氯钯(II) {Chemica Dichlorobis(acetonitrile)palladium(II) BIS(ACETONITRILE)DICHLOROPALLADIUM(II)
PubChem Substance ID84541
EC Number238-637-3
Beilstein Registry Number14640205
Reaxys-RN14640205
Chemical Name Translation双(乙腈)氯化钯(II)
InChIKeyRBYGDVHOECIAFC-UHFFFAOYSA-L
InChIInChI=1S/2C2H3N.2ClH.Pd/c2*1-2-3;;;/h2*1H3;2*1H;/q;;;;+2/p-2
LabNetwork Molecule IDLN00188715
MDL NumberMFCD00013122
CAS Number14592-56-4
GHS Symbol
WGK Germany3
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310+P330
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P304+P340+P311
  • P302+P352+P312+P361+P364
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P405 Store locked up. 上锁保管。
    Signal word Danger
    Hazard statements
    • H301+H311+H331
    • H331 Toxic if inhaled 吸入中毒
    • H311 Toxic in contact with skin 皮肤接触中毒
    • H301 Toxic if swallowed 吞食有毒
      Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
      Safety Statements
      • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
      • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
      • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
      • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
      • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
        Packing GroupIII
        UN Number 3439 UN 3077 9/PG 3 UN3439 3077
        Risk Statements
        • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
        • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
          Hazard Codes T 9
          Hazard Class6.1
        • {ALF} A 6:1 molar ratio of the high-temperature phase-transfer catalyst Tetraphenyl­phosphonium chloride, A10575, and the Pd complex, provides an effective catalyst for the Heck reaction of normally unreactive aryl halides, e.g. chlorobenzene with styrene to give stilbene. The reaction is performed at 140-150o in DMF or NMP in the presence of sodium acetate: Angew. Chem. Int. Ed., 37, 481 (1997).
        • {ALF} Catalyses the cleavage of phenolic TBDMS ethers under mild conditions: Tetrahedron Lett., 37, 153 (1996), and, in the presence of 2-Bromomesityl­ene, A12277, promotes one-pot desilylation-oxidation of aliphatic silyl ethers to aldehydes or ketones: J. Org. Chem., 61, 2918 (1996); cf J. Org. Chem., 48, 1286 (1983).
        • {ALF} Effective alternative catalyst to trans-Dichlorobis(triphenyl­phosphine)­palladium(II)­, 10491, for the carbonylative cross-coupling of arylboronic acids with aryl iodides to give unsymmetrical benzophenones: Tetrahedron Lett., 34, 7595 (1993); see also Appendix 5.
        • {ALF} Organic-soluble complex for catalysis of a variety of reactions, with the advantage over trans-Bis(benzonitrile)­dichloropalladium(II)­, 10006, that the nitrile by-product, being volatile and water-miscible, is readily removed in the workup. In the presence of triethylamine, ortho-allylanilines undergo cyclization to indoles: J. Am. Chem. Soc., 98, 2674 (1976):
          • 14592-56-4 Bellen10003531 Bis(acetonitrile)dichloropalladium(II)双(乙腈)二氯化钯(II)

          化学属性

          SolubilitySoluble in acetonitrile, acetone, chloroform
          TSCANo
          Density1.422
          Melting Point300 ºC
          Mol. FormulaPdCl2
          Appearance orange pwdr.
          Mol. Weight259

          *以上化合物性质及应用等信息仅供参考