(Methoxycarbonylsulfamoyl)triethylammonium hydroxide, inner salt(甲氧基羰酰磺胺酰)三乙基氢氧化铵

规格:
CAS: 29684-56-8
产品编号: Bellen10004427
MDL: MFCD00077815
品牌: Bellen
Chemical NameBurgess Reagent
Synonym Burgess reagent {LY} Burgess reagent {} {LY} Burgess reagent {} {} {LY} Burgess reagent {} {} {} {LY} Burgess reagent {} {} {} {} {LY} Burgess reagent {} {} {} {} {} {LY} Burgess reagent {} {} {} {} {} {} {LY} Burgess reagent {} {} {} {} {} {} {} {LY} Burgess reagent {} {} {} {} {} {} {} {} {LY} Burgess reagent {} {} {} {} {} {} {} {} {} {LY} Burgess reagent {} {} {} {} {} {} {} {} {} {} {LY} Burgess reagent {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Burgess reagent {} {} {} {} {} {} {} {} {} {} {} {} {LY} Burgess reagent {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Burgess reagent {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Burgess reagent {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Burgess reagent {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Burgess reagent {} {} {} {} {} {} {}
PubChem Substance ID87573236
Beilstein Registry Number1432131
MDL NumberMFCD00077815
CAS Number29684-56-8
EC Number250-023-7
Reaxys-RN1432131
Merck Number1502
Chemical Name Translation伯吉斯试剂
LabNetwork Molecule IDLN00192406
Canonical SMILESCC[N+](CC)(CC)S(=O)([N-]C(OC)=O)=O
GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
    Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
    Precautionary statements
    • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P305+P351+P338
    • P305+P351+P338+P337+P313
    • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
      Signal word Warning
      Safety Statements
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
      • S36 Wear suitable protective clothing 穿戴适当的防护服；
      • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
      • S37 Wear suitable gloves 戴适当手套；
        Risk Statements
        • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
          Storage condition -20°C, stored under nitrogen {LY} -20°C, stored under nitrogen 0-10 0-10°C Moisture Sensitive {} {LY} -20°C, stored under nitrogen {} {} {LY} -20°C, stored under nitrogen {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under n
          Hazard Codes Xi
        • {ALF} Mild, efficient dehydrating agent. Primary alcohols are converted to carbamates, which can be hydrolyzed to primary amines, thus providing a valuable alcohol to amine transformation. Secondary and tertiary alcohols afford olefins in synthetically useful yields: J. Org. Chem., 38, 26 (1973); Org. Synth. Coll., 6, 788 (1988). For further discussion, see: Encyclopedia of Reagents for Organic Synthesis, L. A. Paquette, Ed., Wiley, Chichester (1995), vol. 5, p. 3345.
        • {ALF} Primary amides undergo facile dehydration to nitriles, even in the presence of other functional groups including alcohols: Tetrahedron Lett., 29, 2155 (1988). Aldoximes are also dehydrated to nitriles: Synth. Commun., 30, 1509 (2000); Synlett, 1169 (2000). Formamides afford isonitriles: J. Chem. Soc., Perkin 1, 1015 (1998). 2-Acylamino carbonyl compounds undergo the Robinson-Gabriel cyclodehydration to give oxazoles, avoiding conventional harsh dehydrating agents (e.g. P2 O5, POCl3 or SOCl2 ): Synlett, 1642 (1999): <fo:block line-stacking-strategy="max-height" text-align="center"></fo:block>
        • {ALF} The cyclization of 1,2-diacylhydrazines to 1,3,4-oxadiazoles has also been reported: Tetrahedron Lett., 40, 3275 (1999).
          • 29684-56-8 Bellen10004427 (Methoxycarbonylsulfamoyl)triethylammonium hydroxide, inner salt(甲氧基羰酰磺胺酰)三乙基氢氧化铵

          化学属性

          Mol. FormulaC8H18N2O4S
          Mol. Weight238.30
          Melting Point76-79°C
          TSCANo
          Density1.422

          *以上化合物性质及应用等信息仅供参考