Chemical Name | N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine |
CAS Number | 93102-05-7 |
Alfabeta Name | METHOXYMETHYLTRIMETHYLSILYLMETHYLBENZYLAMINE NN(())---- |
MDL Number | MFCD00674005 |
EC Number | 000-000-0 |
Beilstein Registry Number | 4311216 |
PubChem Substance ID | 87564822 |
Synonym |
N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine
{LY} N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine
{} {LY} N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine
{} {} {LY} N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine
{} {} {} {LY} N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine
{} {} {} {} {LY} N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine
{} {} {} {} {} {LY} N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine
{} {} {} {} {} {} {LY} N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine
{} {} {} {} {} {} {} {LY} N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine
{} {} {} {} {} {} {} {} {LY} N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine
{} {} {} {} {} {} {} {} {} {LY} N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine
{} {} {} {} {} {} {} {} {} {}
{} {} {} {} {} {} {} {} {} {} {LY} N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine
{} {} {} {} {} {} {} {} {} {} {} {LY} N-(Methoxymethyl)-N-(trimethylsilylmethyl)be |
Reaxys-RN | 4311216 |
Chemical Name Translation | N-(甲氧甲基)-N-(三甲基硅甲基)苄胺 |
LabNetwork Molecule ID | LN00009631 |
InChI | InChI=1S/C13H23NOSi/c1-15-11-14(12-16(2,3)4)10-13-8-6-5-7-9-13/h5-9H,10-12H2,1-4H3 |
Canonical SMILES | COCN(C[Si](C)(C)C)CC1=CC=CC=C1 |
Warnings |
IRRITANT |
Risk Statements | |
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
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Safety Statements | |
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
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Storage condition |
-20°C, sealed storage, away from moisture and light
{LY} -20°C, sealed storage, away from moisture and light
Moisture & Light Sensitive
Store at room temperature
{} {LY} -20°C, sealed storage, away from moisture and light
{} {} {LY} -20°C, sealed storage, away from moisture and light
{} {} {} {LY} -20°C, sealed storage, away from moisture and light
{} {} {} {} {LY} -20°C, sealed storage, away from moisture and light
{} {} {} {} {} {LY} -20°C, sealed storage, away from moisture and light
{} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture and light
{} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture and light
{} {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture and light
{} {} {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture and light
{} {} {} {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture and light
{} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from |
WGK Germany | 3 |
Precautionary statements | |
- P201 Obtain special instructions before use. 使用前获取专门指示。
- P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352+P332+P313+P362+P364
- P305+P351+P338
- P305+P351+P338+P337+P313
- P308+P313
- P332+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
- P370+P378
- P403+P235
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
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Signal word |
Warning |
Hazard statements | |
- H227 Combustible liquid 可燃液体
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
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GHS Symbol
Personal Protective Equipment |
Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
Hazard Codes |
Xi |
{ALF} Ultrasound treatment with LiF in acetonitrile generates an azomethine ylide which undergoes 1,3-dipolar cycloaddition to olefins to give pyrrolidine derivatives in good yield: J. Org. Chem., 52, 235 (1987). Also found use in the the synthesis of 3-carboxy-1-azabicyclo[2.2.1]heptane derivatives, an important class of physiologically active compounds: J. Org. Chem., 66, 2526 (2001).