Phenylmagnesium chloride 苯基氯化镁

规格:
CAS: 100-59-4
产品编号: Bellen10014756
MDL: MFCD00000464
品牌: Bellen
Chemical NamePhenylmagnesium Chloride
EC Number250-023-7
Beilstein Registry Number3587900
PubChem Substance ID7513
Synonym Chlorphenylmagnesium Phenylmagnesium Chloride 2.0 M In Tetrahdyrofuran PHENYLMAGNESIUMCHLORIDE,25%INTETRAHYDROFURAN chlorophenylmagnesium PHENYLMAGNESIUM CHLORIDE, 1 M in DIBUTYL ETHER Phenylmagnesiumchloride,2-3MinTHF PHENYLMAGNESIUM CHLORIDE 25 WT% IN THF Phenylmagnesium chloride, 25 wt% solution in tetrahydrofuran 氯化苯基鎂 PHENYLMAGNESIUM CHLORIDE, 2.0M SOLUTION IN TETRAHYDROFURAN 氯化苯鎂 PHENYLMAGNESIUM CHLORIDE SOLUTION, ~2.0 M IN THF Phenylmagnesium Chloride (27% in Tetrahydrofuran, ca. 2mol/L) 氯化苯基镁 chlorophenyl-magnesiu PHENYLMAGNESIUM CHLORIDE SOLUTION & Magnesium, chlorophenyl- PHENYLMAGNESIUM CHLORIDE, 2 M in TETRAHYDROFURAN Phenylmagnesium chloride25 wt% solution in tetrahydrofuranAcroSeal§3 苯基氯化镁 Phenylchloromagnesium 苯基氯化镁 溶液 PHENYLMAGNESIUM CHLORIDE
Merck Number7298
Chemical Name Translation苯基氯化镁
Reaxys-RN4576984
InChIInChI=1S/C6H5.ClH.Mg/c1-2-4-6-5-3-1;;/h1-5H;1H;/q-1;;+2/p-1
MDL NumberMFCD00000464
CAS Number100-59-4
GHS Symbol
Signal word
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S30 Never add water to this product 切勿将水加入该产品中；
  • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签；
    Risk Statements
    • R11 Highly flammable 非常易燃
    • R19 May form explosive peroxides 可能生成易爆的过氧化物质
    • R37 Irritating to respiratory system 刺激呼吸道
    • R14 Reacts violently with water 遇水会猛烈反应
    • R34 Causes burns 会导致灼伤
    • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
      Precautionary statements
      • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
      • P233 Keep container tightly closed. ?保持容器密闭。
      • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
      • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
      • P241+
      • P242 Use only non-sparking tools. 只能使用无火花工具。
      • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
      • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
      • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
      • P301+P330+P331
      • P303+P361+P353
      • P304+P340
      • P305+P351+P338
      • P305+P351+P338+P310
      • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
      • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
      • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
      • P370+P378
      • P403+P233
      • P403+P235
      • P405 Store locked up. 上锁保管。
      • P501 Dispose of contents/container to..… 处理内容物/容器.....
        Hazard statements
        • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
        • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
        • H335 May cause respiratory irritation 可能导致呼吸道刺激
        • H351 Suspected of causing cancer 怀疑致癌
          Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
          Packing GroupII
          UN Number
          Storage condition 充氩保存; 在25°C 以下可能引起镁盐结晶，移到温度稍高地方轻微摇动可分解固体。 water-free area Air & Moisture Sensitive 在25°C 以下可能引起镁盐结晶，移到温度稍高地方轻微摇动可分解固体。
          Hazard Codes F,C
          Hazard Class3/8
          Restrict 危险品
        • {ALD} Merck:7298
        • {ALD} Merck:7298
        • Beilstein:16,929
          • 100-59-4 Bellen10014756 Phenylmagnesium chloride 苯基氯化镁

          化学属性

          TSCAYes
          Flash Point1°F (THF)
          Appearance liq.
          Stabilityair sensitive, moisture sensitive
          Density1.05
          Mol. FormulaC6H5MgCl
          Mol. Weight136.86
          RedoxReduction

          *以上化合物性质及应用等信息仅供参考