Methylmagnesium chloride 甲基氯化镁

规格:
CAS: 676-58-4
产品编号: Bellen10017749
MDL: MFCD00000468
品牌: Bellen
Chemical NameMethylmagnesium Chloride
EC Number211-629-7
Beilstein Registry Number3587199
PubChem Substance ID12670
Synonym METHYLMAGNESIUM CHLORIDE 甲基氯化镁, 3M IN THF, PACKAGED UNDER ARGON IN RESEALABLE 甲基氯化镁; 氯代甲基镁 Methylmagnesium chloride, 3M in THF, packaged under Argon in resealable ChemSealTM bottles 甲基氯化镁 溶液 methylmagnesium chloride solution Methylmagnesium Chloride 1.5 M in n-Butyl Ether Methylmagnesium chloride, 22 wt% solution in tetrahydrofuran Methylmagnesiumchloride,3MinTHF 氯化甲基鎂 Methylmagnesium Chloride 2.0 M In Diethyl Ether 氯代甲基镁 甲基氯化镁, 3M IN THF chloromethyl-magnesiu Methylmagnesium Chloride 1.5 M In Butyl Diglyme Methylmagnesium Chloride 2.2 M In Butyl Diglyme METHYLMAGNESIUM CHLORIDE IN TFE METHYLMAGNESIUM CHLORIDE SOLUTION, ~3 M IN THF METHYLMAGNESIUM CHLORIDE, 3 M in TETRAHYDROFURAN METHYLMAGNESIUM CHLORIDE, 2.5M SOLUTIONIN BUTYL DIGLYME METHYLMAGNESIUM CHLORIDE, 3.0M SOLUTION Methylmagnesium Chloride 3.0 M In Tetrahydrofuran METHYLMAGNESIUM CHLORIDE, 3.0M SOLUTION IN TETRAHYDROFURAN 甲基氯化镁 methylmagnesium chloride, 3m in thf, packaged under argon in resealable chemseal Methylmagnesium Chloride 2.0 M In Tetrahydrofuran Magnesium, chloromethyl-
Chemical Name Translation甲基氯化镁
LabNetwork Molecule IDLN00222985
InChIInChI=1S/CH3.ClH.Mg/h1H3;1H;/q-1;;+2/p-1
MDL NumberMFCD00000468
CAS Number676-58-4
GHS Symbol
Signal word Danger
WGK Germany3
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S29 Do not empty into drains 不要排入下水道；
  • S30 Never add water to this product 切勿将水加入该产品中；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S7/8 Keep container tightly closed and dry 保存在严格密闭容器中，保持干燥；
    Risk Statements
    • R11 Highly flammable 非常易燃
    • R14 Reacts violently with water 遇水会猛烈反应
    • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应，释放出高度可燃气体
    • R15 Contact with water liberates extremely flammable gases 遇水会释放出极端易燃的气体
    • R19 May form explosive peroxides 可能生成易爆的过氧化物质
    • R34 Causes burns 会导致灼伤
    • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
    • R37 Irritating to respiratory system 刺激呼吸道
      Precautionary statements
      • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
      • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能，因为会剧烈反应可能产生闪火。
      • P231+
      • P231+P232
      • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
      • P305+P351+P338
      • P370+P378
      • P402+P404
      • P403+P235
      • P422 Store contents under… 存储目录在…之下。
        Hazard statements
        • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
        • H351 Suspected of causing cancer 怀疑致癌
        • H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体，可自燃。
        • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
        • H335 May cause respiratory irritation 可能导致呼吸道刺激
        • H302 Harmful if swallowed 吞食有害
          Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
          Packing GroupII
          UN Number 3399
          Storage condition Flammables + water-Freezer (-20°C)e area 充氩储存 Air & Moisture Sensitive
          Hazard Codes 4.3 F,C
          Hazard Class4.3
          Restrict 危险品
        • 在有机合成中作为格氏试剂和烷基化试剂
          • 676-58-4 Bellen10017749 Methylmagnesium chloride 甲基氯化镁

          化学属性

          Density1.01
          Autoignition Point609 °F
          Solubility不溶于碳氢化合物
          TSCAYes
          Boiling Point66 ºC
          Mol. FormulaCH3ClMg
          Mol. Weight74.79
          Flash Point1°F (THF)
          Appearance liq.
          Stabilityair sensitive, moisture sensitive
          RedoxReduction

          *以上化合物性质及应用等信息仅供参考