Tetrabutylphosphonium bromide四丁基溴化膦

规格:
CAS: 3115-68-2
产品编号: Bellen10017775
MDL: MFCD00011853
品牌: Bellen
Chemical NameTetrabutylphosphonium bromide
MDL NumberMFCD00011853
CAS Number3115-68-2
PubChem Substance ID76564
Beilstein Registry Number4160474
EC Number221-487-8
Synonym Tetrabutylphosphonium bromide {LY} Tetrabutylphosphonium bromide {} {LY} Tetrabutylphosphonium bromide {} {} {LY} Tetrabutylphosphonium bromide {} {} {} {LY} Tetrabutylphosphonium bromide {} {} {} {} {LY} Tetrabutylphosphonium bromide {} {} {} {} {} {LY} Tetrabutylphosphonium bromide {} {} {} {} {} {} {LY} Tetrabutylphosphonium bromide {} {} {} {} {} {} {} {LY} Tetrabutylphosphonium bromide {} {} {} {} {} {} {} {} {LY} Tetrabutylphosphonium bromide {} {} {} {} {} {} {} {} {} {LY} Tetrabutylphosphonium bromide {} {} {} {} {} {} {} {} {} {} {LY} Tetrabutylphosphonium bromide {} {} {} {} {} {} {} {} {} {} {} {LY} Tetrabutylphosphonium bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetrabutylphosphonium bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetrabutylphosphonium bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetrabutylphosphonium bromide {} {} {} {} {} {} {} {} {}
Reaxys-RN4160474
Chemical Name Translation四丁基溴化鏻
Wiswesser Line Notation4P4&4&4 &E
LabNetwork Molecule IDLN00198966
InChIInChI=1S/C16H36P.BrH/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;/h5-16H2,1-4H3;1H/q+1;/p-1
Canonical SMILESCCCC[P+](CCCC)(CCCC)CCCC.[Br-]
GHS Symbol
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >3 mg/m3/1H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXCYAC Toxicology.  (Elsevier Scientific Pub. Ireland, Ltd., POB 85,
   Limerick, Ireland) V.1-    1973-  Volume(issue)/page/year: 24,245,1982

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 56 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#03131

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 700 mg/kg
TOXIC EFFECTS :
   Behavioral - ataxia
   Lungs, Thorax, or Respiration - dyspnea
   Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
   TXCYAC Toxicology.  (Elsevier Scientific Pub. Ireland, Ltd., POB 85,
   Limerick, Ireland) V.1-    1973-  Volume(issue)/page/year: 24,245,1982

RTECSTA2417000
WGK Germany1
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
    Packing GroupIII
    UN Number UN3464 3462 UN 3464 6.1/PG 3 2811
    Risk Statements
    • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
    • R24 Toxic in contact with skin 与皮肤接触有毒
    • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
    • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
    • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
    • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
    • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
      Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Hygroscopic {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light
      Hazard statements
      • H302 Harmful if swallowed 吞食有害
      • H310 Fatal in contact with skin 皮肤接触致命
      • H311 Toxic in contact with skin 皮肤接触中毒
      • H315 Causes skin irritation 会刺激皮肤
      • H318 Causes serious eye damage 严重伤害眼睛
      • H319 Causes serious eye irritation 严重刺激眼睛
      • H335 May cause respiratory irritation 可能导致呼吸道刺激
      • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
        Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
        Precautionary statements
        • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
        • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
        • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
        • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
        • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
        • P273 Avoid release to the environment. 避免释放到环境中。
        • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
        • P301+P312
        • P301+P312+P330
        • P302+P350
        • P302+P352
        • P302+P352+P310+P361+P364
        • P304+P340
        • P305+P351+P338
        • P305+P351+P338+P337+P313
        • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
        • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
        • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
        • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
        • P330 Rinse mouth. 漱口
        • P332+P313
        • P337+P313
        • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
        • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
        • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
        • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
        • P403+P233
        • P405 Store locked up. 上锁保管。
        • P501 Dispose of contents/container to..… 处理内容物/容器.....
          Signal word Danger
          Hazard Codes Xn T;Xn 6.1
          Hazard Class6.1
        • A useful synthetic reagent used in proteomics research.
        • {ALF} Has been used as an ionic liquid solvent in the regioselective O-alkylation of C/O ambident nucleophiles: Tetrahedron Lett., 33, 4435 (1992); see Tetra-n-butyl­ammonium bromide, A10249.
        • {ALF} Quaternary phosphonium salt, useful as a phase-transfer catalyst at high temperatures, at which nitrogen analogues tend to undergo elimination (see Appendix 2), e.g. as catalyst for the dealkoxycarbonylation of malonates and ß-keto esters by heating in stearic acid: Synthesis, 320 (1985).
          • 3115-68-2 Bellen10017775 Tetrabutylphosphonium bromide四丁基溴化膦

          化学属性

          Mol. FormulaC16H36BrP
          Mol. Weight339.34
          Melting Point99-104°C
          TSCAYes
          Flash Point290°C
          SolubilityCA 70 G/100 ML
          Stability对热敏感，易吸潮
          Appearance 白色至类白色晶体，熔点99-104℃

          *以上化合物性质及应用等信息仅供参考