Tetramethylammonium triacetoxyborohydride三乙酰氧基硼氢化四甲铵

规格:
CAS: 109704-53-2
产品编号: Bellen10017978
MDL: MFCD00012196
品牌: Bellen
Chemical NameTetramethylammonium triacetoxyborohydride
MDL NumberMFCD00012196
PubChem Substance ID87577312
Beilstein Registry Number8238791
CAS Number109704-53-2
Synonym 四甲基三乙酰氧硼氢化铵
EC Number000-000-0
Reaxys-RN8238791
Chemical Name Translation四甲基三乙酰氧硼氢化铵
GHS Symbol
Precautionary statements
  • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能，因为会剧烈反应可能产生闪火。
  • P231+P232
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P370+P378
  • P422 Store contents under… 存储目录在…之下。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
    Hazard statements
    • H315 Causes skin irritation 会刺激皮肤
    • H335 May cause respiratory irritation 可能导致呼吸道刺激
    • H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
    • H319 Causes serious eye irritation 严重刺激眼睛
      WGK Germany3
      Personal Protective Equipment Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
      Signal word Danger
      Safety Statements
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
      • S36 Wear suitable protective clothing 穿戴适当的防护服；
      • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
        Hazard Codes 4.3
        Risk Statements
        • R15 Contact with water liberates extremely flammable gases 遇水会释放出极端易燃的气体
        • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
          Packing GroupII
          UN Number 2813
          Storage condition Moisture Sensitive 0-10 0-10°C
          Hazard Class4.3
        • {ALF} Reduces ß-hydroxy ketones in 1:1 MeCN_-_AcOH to give 1,3-diols with high anti-stereoselectivity: J. Am. Chem. Soc., 110, 3560 (1988). Under similar conditions, ß-hydroxy oximino ethers are reduced stereoselectively to the hydroxylamine ethers: J. Am. Chem. Soc., 114, 8750 (1992). ɑ-Hydroxy oximino ethers are also reduced to syn-1,2-hydroxyamine derivatives: Tetrahedron Lett., 34, 3271 (1993).
          • 109704-53-2 Bellen10017978 Tetramethylammonium triacetoxyborohydride三乙酰氧基硼氢化四甲铵

          化学属性

          Mol. FormulaC10H22BNO6
          Mol. Weight263.10
          Melting Point93-98
          TSCANo

          *以上化合物性质及应用等信息仅供参考