Ethylaluminum dichloride 二氯乙基铝

规格: 1.5 M(25%) solution in hexanes, SpcSeal
CAS: 563-43-9
产品编号: H23830
MDL: MFCD00000457
品牌: INFI
Chemical NameEthylaluminum dichloride
Synonym Aluminum, dichloroethyl- Aluminum,dichloroethyl- Dichlorethylaluminium Dichloro(ethyl)aluminium Dichloroethylaluminum ETHYLALUMINIUM DICHLORIDE ETHYLALUMINIUM-DICHLORID-LOESUNG ~ 1 M I ETHYLALUMINUM DICHLORIDE 25 WT. % (1.8& ETHYLALUMINUM DICHLORIDE, 25 WT. % (1.8M ) SOLUTION IN TOLUENE EtAlCl2 Ethyl aluminum dichloride Ethylaluminium dichloride Ethylaluminium dichloride(225 g cylinder) Ethylaluminium dichloride, 0.9M solution in heptane Ethylaluminiumdichlorid Ethyldichloraluminium Ethyldichloroaluminum dichloroethyl-aluminu dichloroethylaluminum {} {Chemicalbo {} {uni_hamburg} 乙基二氯化铝，二氯化乙基铝 二氯乙基铝 二氯化乙基鋁 二氯化乙基铝 二氯化乙基铝,1M 正己烷溶液
CAS Number563-43-9
EC Number209-248-6
Beilstein Registry Number4123357
MDL NumberMFCD00000457
PubChem Substance ID11237
Chemical Name Translation二氯乙基铝
Merck Number326
LabNetwork Molecule IDLN00162827
InChIInChI=1S/C2H5.Al.2ClH/c1-2;;;/h1H2,2H3;;2*1H/q;+2;;/p-2
GHS Symbol
Signal word Danger
WGK Germany2
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签；
    Risk Statements
    • R11 Highly flammable 非常易燃
    • R48/20
    • R17 Spontaneously flammable in air 在空气中能够自燃
    • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应，释放出高度可燃气体
    • R34 Causes burns 会导致灼伤
    • R63 Possible risk of harm to the unborn child 可能危害未出生婴儿
    • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
    • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
    • R62 Possible risk of impaired fertility 有削弱生殖能力的危险
    • R51/53
    • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
    • R15 Contact with water liberates extremely flammable gases 遇水会释放出极端易燃的气体
    • R14 Reacts violently with water 遇水会猛烈反应
      Precautionary statements
      • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
      • P222 Do not allow contact with air. 不要与空气接触。
      • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能，因为会剧烈反应可能产生闪火。
      • P231+P232
      • P233 Keep container tightly closed. ?保持容器密闭。
      • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
      • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
      • P242 Use only non-sparking tools. 只能使用无火花工具。
      • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
      • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
      • P273 Avoid release to the environment. 避免释放到环境中。
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
      • P301+P330+P331
      • P302+P334
      • P303+P361+P353
      • P304+P340
      • P305+P351+P338
      • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
      • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
      • P335+P334
      • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
      • P370+P378
      • P402+P404
      • P403+P235
      • P405 Store locked up. 上锁保管。
      • P422 Store contents under… 存储目录在…之下。
      • P501 Dispose of contents/container to..… 处理内容物/容器.....
        Hazard statements
        • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
        • H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
        • H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体，可自燃。
        • H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
        • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
        • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
        • H318 Causes serious eye damage 严重伤害眼睛
        • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
        • H361d Suspected of damaging the unborn child 怀疑对未出生婴儿造成伤害
        • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
          RTECSBD0705000
          Packing GroupI
          UN Number UN 3399 4.3/PG 1 UN3394 3399
          Storage condition Air & Moisture Sensitive 0-6°C
          Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
          Hazard Codes F,C F;T 4.2 F,T,N,C
          Hazard Class4.3
          Warnings 危化品目录(2015) 危险化学品
        • 烯烃聚合的助催化剂。
        • {uni_hamburg} Short: III/20a
        • {uni_hamburg} Short: III/31a
        • {ALD} Merck:326
        • {ALD} Merck:326
        • Beilstein:4(3)1973
          • 563-43-9 H23830 Ethylaluminum dichloride 二氯乙基铝

          化学属性

          Mol. FormulaCH3CH2AlCl2
          Mol. Weight127
          Density0.927 g/mL at 25 °C
          Flash Point-22°(-9°F)
          TSCAYes
          Boiling Point115°C
          Vapor Pressure5 mmHg ( 60 °C)
          Melting Point32°C
          Solubility可混溶于甲苯、汽油。
          Stability对空气和湿度敏感

          *以上化合物性质及应用等信息仅供参考