Tetrapropylammonium Perruthenate (TPAP) 过钌酸四丙胺盐(TPAP)

规格: 95+%
CAS: 114615-82-6
产品编号: H25613
MDL: MFCD00074914
品牌: INFI
Chemical NameTetrapropylammonium Perruthenate (TPAP)
Synonym TPAP 过钌酸四内胺,四丙基高钌酸铵,四正丙基过钌酸铵 四丙基高钌酸铵
MDL NumberMFCD00074914
PubChem Substance ID87577317
CAS Number114615-82-6
Reaxys-RN13168949
EC Number250-023-7
Beilstein Registry Number2384789
Chemical Name Translation四正丙基过钌酸铵
LabNetwork Molecule IDLN03265034
GHS Symbol
WGK Germany3
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P332+P313
  • P420 Store away from other materials. 远离其他材料。
  • P305+P351+P338+P337+P313
  • P302+P350
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P302+P352+P332+P313+P362+P364
    Hazard statements
    • H315 Causes skin irritation 会刺激皮肤
    • H335 May cause respiratory irritation 可能导致呼吸道刺激
    • H272 May intensify fire; oxidizer 可能加剧火势；氧化剂。
    • H319 Causes serious eye irritation 严重刺激眼睛
      Hazard Codes O,Xi
      Personal Protective Equipment Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
      Signal word
      UN Number UN1479
      Safety Statements
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
      • S37 Wear suitable gloves 戴适当手套；
      • S17 Keep away from combustible material 远离可燃物料；
      • S36 Wear suitable protective clothing 穿戴适当的防护服；
      • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
        Risk Statements
        • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
          Storage condition 有吸湿性 Hygroscopic
          Packing GroupII
          Hazard Class5.1
        • 可溶、非挥发性、空气稳定的温和催化剂，可与适当的共?氧化剂按化学计量或作为催化用途使用。
        • 氧化剂，用于将 N,N′-二羟基咪唑啉转化为氮氧自由基。将羟基取代的三-正丁基铵三氟硼酸盐氧化成醛和酮，而?不会伴随碳-硼键的断裂。
        • {SA} 3. Synthesis 7 , 639-666, (1994)
        • {ALF} Selective, catalytic oxidant introduced by Ley. Normally used in combination with N-methylmorpholine-N-oxide as the stoichiometric reoxidant and 4A molecular sieves to remove water. Preferred solvents are dichloromethane and acetonitrile. Primary and secondary alcohols are oxidized to aldehydes and ketones in high yield: J. Chem. Soc., Chem. Commun., 1625 (1987). For an example of alcohol to aldehyde oxidation in the partial synthesis of the acyl tetronic acid ionophore tetronasin, see: Tetrahedron Lett., 35, 319 (1994). Also useful for a number of other oxidations such as lactols to lactones and sulfides to sulfones. For oxidation of secondary amines to imines, and of hydroxylamines to nitrones, see: Tetrahedron Lett., 35, 6567, 6571 (1994).
        • {ALD} Merck: 14,10463
        • {ALF} For a comprehensive review of this reagent, see: Synthesis, 639 (1994). For a review of ruthenium oxo-complexes as organic oxidants, see: Chem. Soc. Rev., 21, 179 (1992).
        • {ALF} For a brief feature on uses in synthesis, see: Synlett, 824 (2007).
          • 114615-82-6 H25613 Tetrapropylammonium Perruthenate (TPAP) 过钌酸四丙胺盐(TPAP)

          化学属性

          Mol. FormulaC12H28NO4Ru
          Mol. Weight351
          Melting Point160
          TSCANo
          Density1.422
          Stability易吸潮

          *以上化合物性质及应用等信息仅供参考