Chemical Name | Tris(dibenzylideneacetone)dipalladium(0)-chloroform Adduct |
Alfabeta Name | TRISDIBENZYLIDENEACETONEDIPALLADIUMCHLOROFORMADDUCT ()- |
Synonym |
Pd2(dba)3·CHCl3
{LY} Pd2(dba)3·CHCl3
{} {LY} Pd2(dba)3·CHCl3
{} {} {LY} Pd2(dba)3·CHCl3
{} {} {} {LY} Pd2(dba)3·CHCl3
{} {} {} {} {LY} Pd2(dba)3·CHCl3
{} {} {} {} {} {LY} Pd2(dba)3·CHCl3
{} {} {} {} {} {} {LY} Pd2(dba)3·CHCl3
{} {} {} {} {} {} {} {LY} Pd2(dba)3·CHCl3
{} {} {} {} {} {} {} {} {LY} Pd2(dba)3·CHCl3
{} {} {} {} {} {} {} {} {} {LY} Pd2(dba)3·CHCl3
{} {} {} {} {} {} {} {} {} {} {LY} Pd2(dba)3·CHCl3
{} {} {} {} {} {} {} {} {} {} {}
{} {} {} {} {} {} {} {} {} {} {} {LY} Pd2(dba)3·CHCl3
{} {} {} {} {} {} {} {} {} {} {} {} {LY} Pd2(dba)3·CHCl3
{} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Pd2(dba)3·CHCl3
{} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Pd2(dba)3·CHCl3
{} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Pd2(dba)3·CHCl3
{} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Pd2(dba)3·CHCl3
{} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
{} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Pd2(dba)3·CHCl3
{} {} {} {} {} {} {} {} {} {} {} {} |
PubChem Substance ID | 11029508 |
EC Number | 250-023-7 |
Beilstein Registry Number | 2384789 |
Chemical Name Translation | 三(二亚苄基丙酮)二钯-氯仿加合物 |
LabNetwork Molecule ID | LN00177555 |
InChI | InChI=1S/3C17H14O.CHCl3.2Pd/c3*18-17(13-11-15-7-3-1-4-8-15)14-12-16-9-5-2-6-10-16;2-1(3)4;;/h3*1-14H;1H;;/b3*13-11+,14-12+;;; |
MDL Number | MFCD00075479 |
CAS Number | 52522-40-4 |
Canonical SMILES | [Pd][Pd].ClC(Cl)Cl.O=C(/C=C/C1=CC=CC=C1)/C=C/C2=CC=CC=C2.[3] |
Warnings |
IRRITANT |
Safety Statements | |
- S22 Do not breathe dust 不要吸入粉尘;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
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Risk Statements | |
- R22 Harmful if swallowed 吞咽有害
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R38 Irritating to skin 刺激皮肤
- R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
- R48/20/22
|
Storage condition |
2-8°C, protect from light, stored under nitrogen
{LY} 2-8°C, protect from light, stored under nitrogen
Air & Moisture Sensitive
{} {LY} 2-8°C, protect from light, stored under nitrogen
{} {} {LY} 2-8°C, protect from light, stored under nitrogen
{} {} {} {LY} 2-8°C, protect from light, stored under nitrogen
{} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen
{} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen
{} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen
{} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen
{} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen
{} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen
{} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen
{} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen
{} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, prote |
WGK Germany | 3 |
GHS Symbol
Precautionary statements | |
- P281 Use personal protective equipment as required. 使用所需的个人防护装备。
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Signal word |
Warning |
Hazard statements | |
- H315 Causes skin irritation 会刺激皮肤
- H302 Harmful if swallowed 吞食有害
- H351 Suspected of causing cancer 怀疑致癌
|
Personal Protective Equipment |
dust mask type N95 (US), Eyeshields, Gloves |
Hazard Codes |
Xn |
环化催化剂。
{ALF} Phosphine-free Pd(0) catalyst. Catalyzes the addition of arylboronic acids to aldehydes, affording secondary alcohols. No reaction was observed in the absence of chloroform: Org. Lett., 7, 4153 (2005).