Chemical Name | 1-Butyl-3-Methylimidazolium Hexafluorophosphate |
CAS Number | 174501-64-5 |
Alfabeta Name | BUTYLMETHYLIMIDAZOLIUMHEXAFLUOROPHOSPHATE 13--- |
MDL Number | MFCD03093295 |
Synonym |
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EC Number | 000-000-0 |
Merck Number | 1581 |
Beilstein Registry Number | 8026031 |
PubChem Substance ID | 87565152 |
Reaxys-RN | 8026031 |
Chemical Name Translation | 1-丁基-3-甲基咪唑六氟磷酸盐 |
LabNetwork Molecule ID | LN00119727 |
Warnings |
IRRITANT |
Risk Statements | |
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
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Safety Statements | |
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Signal word |
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GHS Symbol
WGK Germany | 3 |
Precautionary statements | |
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P305+P351+P338+P337+P313
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Hazard statements | |
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
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Personal Protective Equipment |
Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
Hazard Codes |
6.1
Xi |
Packing Group | III |
UN Number |
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Storage condition |
充氩保存 |
离子液体,用在许多环保型的反应中。
{ALF} Heck reactions with aryl halides can be carried out with controlled microwave heating: J. Org. Chem., 67, 6243 (2002).
{ALD} Merck: 14,1581
{ALF} Ionic liquid.
{ALF} For use in dihydroxylation of alkenes with Osmium(VIII)­ oxide, 12103, facilitating the reuse of the Os catalyst, see: Org. Lett., 4, 2197 (2002).
{ALF} Recyclable medium for oxidation of alcohols, catalyzed by TEMPO, A12733, and CuCl, to give aldehydes and ketones chemoselectively under mild conditions: Org. Lett., 4, 1507 (2002).
{ALF} A copper-free Sonogashira coupling of terminal alkynes with aryl iodides, catalyzed by trans-Dichlorobis(triphenyl­phosphine)­palladium(II)­, 10491, has been adapted to a microflow system for efficient catalyst recycling: Org. Lett., 4, 1691 (2002).