Boron trichloride 三氯化硼二氯甲烷溶液

规格: 1.0 M solution in methylene chloride, SpcSeal
CAS: 10294-34-5
产品编号: H31003
MDL: MFCD00011313
品牌: INFI
Chemical NameBoron Trichloride
CAS Number10294-34-5
PubChem Substance ID24861566
EC Number233-658-4
MDL NumberMFCD00011313
Reaxys-RN3903057
Merck Number1348
Synonym BCl3 {uni_hamburg} Borane,trichloro- BCl3 Boron chloride Borane, trichloro- Boron chloride (BCl3) Trichloroborane Trichloroboron BORON TRICHLORIDE, 10 WT. % SOLUTION IN 2-CHLOROETHANOL 氯化硼 BORON TRICHLORIDE, 1.0M SOLUTION IN HEXA NES BORON TRICHLORIDE, 1.0M SOLUTION IN P-XY LENE chloruredebore chloruredebore(french) boron (III) chloride 三氯硼烷 boron trichloride BORON TRICHLORIDE, 1.0M SOLUTION IN DICH LOROMETHANE BORON TRICHLORIDE, 1.0M SOLUTION IN HEPT ANE BORON TRICHLORIDE, 1.0 M SOLUTION IN TO& trichloro-Boron 三氯化硼 trichloro-boran boronchloride(bcl3) Trichlorboran Trona
Beilstein Registry Number2384789
Chemical Name Translation三氯化硼
Wiswesser Line NotationGBGG
LabNetwork Molecule IDLN00163774
GHS Symbol
TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 20 ppm/7H
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - other changes
   Skin and Appendages - dermatitis, other (after systemic exposure)
   Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
   14KTAK "Boron, Metallo-Boron Compounds and Boranes," Adams, R.M., ed., New
   York, John Wiley & Sons, Inc., 1964  Volume(issue)/page/year: -,693,1964

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2541 ppm/1H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   42,417,1977

WGK Germany3
Hazard Codes 3 8 F,T+ F,T+,N
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H331 Toxic if inhaled 吸入中毒
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H300 Fatal if swallowed 吞食致命
  • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H361d Suspected of damaging the unborn child 怀疑对未出生婴儿造成伤害
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H351 Suspected of causing cancer 怀疑致癌
  • H301 Toxic if swallowed 吞食有毒
  • H312 Harmful in contact with skin 皮肤接触有害
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H361 Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害
  • H300+H330
  • H280 Contains gas under pressure; may explode if heated 内含高压气体，遇热可能爆炸。
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
    Personal Protective Equipment Faceshields, Gloves, Goggles, half-mask respirator (US), multi-purpose combination respirator cartridge (US) Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
    RTECSED1925000
    Precautionary statements
    • P201 Obtain special instructions before use. 使用前获取专门指示。
    • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
    • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
    • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
    • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
    • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
    • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
    • P273 Avoid release to the environment. 避免释放到环境中。
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
    • P301+P310
    • P301+P310+P331
    • P301+P330+P331+P310
    • P303+P361+P353
    • P304+P340
    • P305+P351+P338
    • P305+P351+P338+P310
    • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
    • P370+P378
    • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
    • P403+P233
    • P501 Dispose of contents/container to..… 处理内容物/容器.....
      Signal word Danger
      Storage condition Moisture Sensitive 0-10 0-10°C 储存温度 2-8℃; 充氩保存 2-8°C
      UN Number 2922 2924 UN2927
      Safety Statements
      • S1 Keep locked up 上锁；
      • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
      • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
      • S25 Avoid contact with eyes 避免眼睛接触；
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
      • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
      • S33 Take precautionary measures against static discharges 对静电采取预防措施；
      • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
      • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
      • S38 In case of insufficient ventilation wear suitable respiratory equipment 通风不良时，佩带适当的呼吸器；
      • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
      • S57 Use appropriate containment to avoid environmental contamination 使用适当容器避免环境污染；
      • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
      • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
      • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签；
      • S7/9 Keep container tightly closed and in a well-ventilated place 保持容器严格密闭，置于通风良好的场所；
      • S8 Keep container dry 保持容器干燥；
      • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
        Risk Statements
        • R10 Flammable 易燃
        • R11 Highly flammable 非常易燃
        • R14 Reacts violently with water 遇水会猛烈反应
        • R21 Harmful in contact with skin 与皮肤接触有害
        • R24 Toxic in contact with skin 与皮肤接触有毒
        • R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有剧毒
        • R26/28 Very toxic by inhalation and if swallowed 吸入及吞食都有剧毒
        • R34 Causes burns 会导致灼伤
        • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
        • R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性：吸入，皮肤接触和吞食都会产生十分严重的不可逆危险
        • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
        • R48/20
        • R50/53
        • R51/53
        • R62 Possible risk of impaired fertility 有削弱生殖能力的危险
        • R63 Possible risk of harm to the unborn child 可能危害未出生婴儿
        • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
        • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
          Packing GroupII
          Hazard Class3/8
          Warnings 危化品目录(2015)
          Restrict 危险品
        • ⑴.常温常压下为无色发烟液体或气体，有强烈臭味，易潮解。对眼睛、皮肤、粘膜和上呼吸道有强烈的腐蚀作用。吸入后可因喉、支气管的痉挛、水肿，化学性肺炎、肺水肿而致死。中毒表现有烧灼感、咳嗽、喘息、喉炎、气短、头痛、恶心和呕吐。
        • ⑵. 化学反应活性很高，遇水分解生成氯化氢和硼酸，并放出大量热量。在湿空气中因水解而生成烟雾。与铜及其合金有可能生成具有爆炸性的氯乙炔。遇潮气时对大多数金属有强腐蚀性，也能腐蚀玻璃等。三氯化硼反应能力较强，能形成多种配位化合物，具有较高的热力学稳定性，但在放电作用下，会分解形成低价的
        • 用于制备脂肪酸甲酯以及用于三酸甘油酯的酯交换反应。
        • {SA}
        • 1. Kawaguchi, M. et al. Chem. Mater. 8 , 1197, (1996)
        • {SA}
        • 2. McGinnis, M.B. et al. J. Org. Chem. 61 , 3496, (1996)
        • {SA}
        • Merck 14 ,1348
        • {SA}
        • Fieser 1 ,67 / Fieser 2 ,34 / Fieser 3 ,31 / Fieser 4 ,42 / Fieser 5 ,50 / Fieser 6 ,65 / Fieser 9 ,62 / Fieser 12 ,65 / Fieser 13 ,43 / Fieser 14 ,54 / Fieser 15 ,44
        • {uni_hamburg} Short: II/25A
        • Title: Structure Data Of Free Polyatomic Molecules: Inorganic Molecules
        • Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N.
        • Editor: Kuchitsu, K.
        • Source: Landolt-Börnstein, New Series
        • Volume: II/25A
        • Year: 1998
        • Keyword: Free Polyatomic Molecules; Inorganic Molecules; Molecules
        • ISBN: 3-540-61713-2
        • ISBN: 978-3-540-61713-6
        • Internet Resource: DOI:10.1007/b59072
        • RefComment: VII, 359 pages. Hardcover
        • Abstract: Volume II/25 is a supplemented and revised edition of the preceding volumes II/7, II/15, II/21 and II/23 containing up to date information on inorganic and organic polyatomic molecules. All experimental methods for the determination of quantitative structural data of free molecules have been considered: microwave, infrared, Raman, electronic and photoelectron spectroscopy as well as electron diffraction. The data obtained by these methods have been critically evaluated and compiled. They are presented separately for each molecule, together with a schematic figure of the structure and the original literature.
        • {uni_hamburg} Short: III/20a
        • Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cl
        • Author: Chihara, H.; Nakamura, N.
        • Editor: Hellwege, K.-H.; Hellwege, A.M.
        • Source: Landolt-Börnstein, New Series
        • Volume: III/20a
        • Year: 1988
        • Keyword: NQR
        • ISBN: 3-540-18161-X
        • ISBN: 978-3-540-18161-3
        • Internet Resource: DOI:10.1007/b31153
        • RefComment: IX,677 pages. Hardcover
        • Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and s
          • 10294-34-5 H31003 Boron trichloride 三氯化硼二氯甲烷溶液

          化学属性

          Boiling Point12.5 °C(lit.)
          Melting Point-107 °C(lit.)
          TSCAYes
          Vapor Density4.05 (vs air)
          Vapor Pressure29.72 psi ( 55 °C)
          Flash Point2°C(lit.)
          Solubility分解
          Stability对热、湿度及空气敏感
          Density0.718
          Mol. FormulaBCl3
          Mol. Weight117.17
          pH:A

          *以上化合物性质及应用等信息仅供参考