Chemical Name | Diethylzinc |
Synonym |
DEZ DEZn Et2Zn Zincdiethyl
DEZn
DIETHYLZINC
DIETHYLZINC SOLUTION, IN TOLUENE (1.1 M)
DIETHYLZINC SOLUTION, ~1 M SOLUTION IN H EXANE
DIETHYLZINC, 15 WT. % (1.1M) SOLUTION IN TOLUENE
DIETHYLZINC, 52.0 WT.% ZN (MINIMUM)
DIETHYLZINC, CYLINDER WITH 100 G
DIETHYLZINC, FOR CAMBRIDGE NANOTECH INC
Diethylene Zinc
Diethylzinc,elec.gr.(99.999%-Zn)PURATREM
Diethylzink
ZINCDIETHYL
Zinc ethide
Zincdiethyl
Zinkdiethyl
Zinkdiäthyl
diethyl zinc
diethylzinc
diethylzine
乙基锌
二乙基锌 溶液
二乙基锌, 名义上为15% W/W 己烷溶液 |
PubChem Substance ID | 11185 |
EC Number | 209-161-3 |
Beilstein Registry Number | 3587207 |
Reaxys-RN | 3587207 |
Merck Number | 3131 |
Chemical Name Translation | 二乙基锌 |
LabNetwork Molecule ID | LN00222421 |
InChI | InChI=1S/2C2H5.Zn/c2*1-2;/h2*1H2,2H3;/q2*-1;+2 |
MDL Number | MFCD00009021 |
CAS Number | 557-20-0 |
GHS Symbol
WGK Germany | 3 |
Hazard statements | |
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
- H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体,可自燃。
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
- H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
- H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
- H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
- H361 Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害
- H361d Suspected of damaging the unborn child 怀疑对未出生婴儿造成伤害
|
Personal Protective Equipment |
Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
Hazard Codes |
4.3
F,C,N
F,Xn,N,C
F;C;N |
Precautionary statements | |
- P201 Obtain special instructions before use. 使用前获取专门指示。
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P222 Do not allow contact with air. 不要与空气接触。
- P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能,因为会剧烈反应可能产生闪火。
- P231+P232
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- P305+P351+P338+P310
- P308+P313
- P335+P334
- P370+P378
- P403+P233
- P422 Store contents under… 存储目录在…之下。
|
Signal word |
Danger |
UN Number |
3399 |
Safety Statements | |
- S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
- S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐:立即求医并出示该容器或标签;
- S8 Keep container dry 保持容器干燥;
|
Risk Statements | |
- R11 Highly flammable 非常易燃
- R14 Reacts violently with water 遇水会猛烈反应
- R17 Spontaneously flammable in air 在空气中能够自燃
- R34 Causes burns 会导致灼伤
- R48/20
- R51/53
- R62 Possible risk of impaired fertility 有削弱生殖能力的危险
|
Storage condition |
Air & Moisture Sensitive
0-6°C |
Packing Group | I |
RTECS | ZH2077777 |
Hazard Class | 4.3/3 |
Warnings |
危化品目录(2015) |
Restrict |
危险品 |
⑴. 常温常压下为无色透明有恶臭的液体,遇水剧烈水解,易溶于己烷、庚烷等脂肪族饱和烃和甲苯、二甲苯等芳香族烃中。空气中能自燃,燃烧时产生氧化锌白烟。与水激烈反应,并分解发生可燃性乙烷气而着火。应在惰性气氛中保存。
⑵. 与具有活泼氢的醇类、酸类激烈反应。遇水分解,生成氢氧化锌和乙烷。与三级卤代烃[例如(CH3)3CCl]反应可制取四级烃[如(CH3)3C·C2H5)。
⑶. 可用于半导体生产的金属有机化学气相沉积(MOCVD)工艺和外延生长及聚合反应的催化剂。.在制造发光二极管时用作AsCa、GaP、G
和Rh (I) 催化剂一起用于从α,β-非饱和酮制备α-三氟甲基酮。
{uni_hamburg} Short: II/25C
{ALD} Merck:14,3131
Beilstein:4(4)4423
{uni_hamburg} Short: III/38A
{ALD} Merck:14,3131