Chemical Name | Silver Tetrafluoroborate |
CAS Number | 14104-20-2 |
Alfabeta Name | SILVERTETRAFLUOROBORATE |
MDL Number | MFCD00003408 |
Synonym |
四氟硼酸银
Silver tetrafluoroborate
Silbertetrafluoroborat
Silver(1+) tetrafluoroborate(1-)
Silver(I) fluoroborate
Silber(I)tetrafluoroborat
Silbertetrafluorborat |
EC Number | 237-956-5 |
PubChem Substance ID | 87575928 |
Beilstein Registry Number | 11547930 |
Reaxys-RN | 11547930 |
Chemical Name Translation | 四氟硼酸银 |
InChIKey | CCAVYRRHZLAMDJ-UHFFFAOYSA-N |
LabNetwork Molecule ID | LN00119270 |
Warnings |
危化品目录(2015)
MOISTURE SENSITIVE, CORROSIVE |
RTECS | ED2875000 |
Safety Statements | |
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
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Packing Group | II |
UN Number |
1759 |
Risk Statements | |
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Storage condition |
易吸潮,密封避光保存
Light Sensitive & Hygroscopic
充氩保存 |
WGK Germany | 3 |
GHS Symbol
Precautionary statements | |
- P303+P361+P353+P310+P363
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331
- P405 Store locked up. 上锁保管。
- P304+P340
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P304+P340+P310
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Signal word |
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Hazard statements | |
- H302 Harmful if swallowed 吞食有害
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
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Personal Protective Equipment |
Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges |
Hazard Codes |
C |
Hazard Class | 8 |
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE : Intravenous
SPECIES OBSERVED : Rodent - mouse
DOSE/DURATION : 56 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010)
Volume(issue)/page/year: NX#06756
Restrict |
危险品 |
{ALF}
{ALF} For use in the preparation of stable, non-hygroscopic, crystalline acylammonium salts, see: J. Org. Chem., 57, 5136 (1992).
{ALF} Silver salt soluble in many organic solvents; useful, e.g. in promotion of the leaving ability of halogens. Promotes the conversion of ɑ-bromo aldehydes and ketones to their ɑ-fluoro equivalents: Tetrahedron Lett., 3357 (1979).
{ALF} Mediates the oxidative coupling of silylated cyclopropanols to 1,6-diones: J. Am. Chem. Soc., 105, 7192 (1983):
{uni_hamburg} Short: EINECS
{ALF} In the presence of AgBF4, aceta
{uni_hamburg} Short: III/7a
{ALF} In the presence of AgBF4, acetals of phenacyl halides undergo rearrangement to esters of arylacetic acids: J. Chem. Soc., Perkin 1, 2575 (1982); compare Silver nitrate, 11414.