Silver tetrafluoroborate 四氟硼酸银

规格: 99%
CAS: 14104-20-2
产品编号: H43293
MDL: MFCD00003408
品牌: INFI
Chemical NameSilver Tetrafluoroborate
CAS Number14104-20-2
Alfabeta NameSILVERTETRAFLUOROBORATE
MDL NumberMFCD00003408
Synonym 四氟硼酸银 Silver tetrafluoroborate Silbertetrafluoroborat Silver(1+) tetrafluoroborate(1-) Silver(I) fluoroborate Silber(I)tetrafluoroborat Silbertetrafluorborat
EC Number237-956-5
PubChem Substance ID87575928
Beilstein Registry Number11547930
Reaxys-RN11547930
Chemical Name Translation四氟硼酸银
InChIKeyCCAVYRRHZLAMDJ-UHFFFAOYSA-N
LabNetwork Molecule IDLN00119270
GHS Symbol
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 56 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#06756

Warnings 危化品目录(2015) MOISTURE SENSITIVE, CORROSIVE
RTECSED2875000
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
    Packing GroupII
    UN Number 1759
    Risk Statements
      Storage condition 易吸潮,密封避光保存 Light Sensitive & Hygroscopic 充氩保存
      WGK Germany3
      Precautionary statements
      • P303+P361+P353+P310+P363
      • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
      • P501 Dispose of contents/container to..… 处理内容物/容器.....
      • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P305+P351+P338
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
      • P301+P330+P331
      • P405 Store locked up. 上锁保管。
      • P304+P340
      • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
      • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P304+P340+P310
        Signal word
        Hazard statements
        • H302 Harmful if swallowed 吞食有害
        • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
          Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
          Hazard Codes C
          Hazard Class8
          Restrict 危险品
        • {ALF}
        • {ALF} For use in the preparation of stable, non-hygroscopic, crystalline acylammonium salts, see: J. Org. Chem., 57, 5136 (1992).
        • {ALF} Silver salt soluble in many organic solvents; useful, e.g. in promotion of the leaving ability of halogens. Promotes the conversion of ɑ-bromo aldehydes and ketones to their ɑ-fluoro equivalents: Tetrahedron Lett., 3357 (1979).
        • {ALF} Mediates the oxidative coupling of silylated cyclopropanols to 1,6-diones: J. Am. Chem. Soc., 105, 7192 (1983):
        • {uni_hamburg} Short: EINECS
        • {ALF} In the presence of AgBF4, aceta
        • {uni_hamburg} Short: III/7a
        • {ALF} In the presence of AgBF4, acetals of phenacyl halides undergo rearrangement to esters of arylacetic acids: J. Chem. Soc., Perkin 1, 2575 (1982); compare Silver nitrate, 11414.
          • 14104-20-2 H43293 Silver tetrafluoroborate 四氟硼酸银

          化学属性

          Mol. FormulaAgBF4
          Mol. Weight195
          Melting Point70-73
          TSCAT
          Density1.422
          Solubility可溶
          Stability对光线敏感，对湿度敏感

          *以上化合物性质及应用等信息仅供参考