Silver tetrafluoroborate 四氟硼酸银

规格: 99%
CAS: 14104-20-2
产品编号: H43293
MDL: MFCD00003408
品牌: INFI
Chemical NameSilver Tetrafluoroborate
CAS Number14104-20-2
MDL NumberMFCD00003408
Synonym 四氟硼酸银 Silver tetrafluoroborate Silbertetrafluoroborat Silver(1+) tetrafluoroborate(1-) Silver(I) fluoroborate Silber(I)tetrafluoroborat Silbertetrafluorborat
EC Number237-956-5
PubChem Substance ID87575928
Beilstein Registry Number11547930
Chemical Name Translation四氟硼酸银
LabNetwork Molecule IDLN00119270
GHS Symbol
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 56 mg/kg
   Details of toxic effects not reported other than lethal dose value
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#06756

Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
    Packing GroupII
    UN Number 1759
    Risk Statements
      Storage condition 易吸潮,密封避光保存 Light Sensitive & Hygroscopic 充氩保存
      WGK Germany3
      Precautionary statements
      • P303+P361+P353+P310+P363
      • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
      • P501 Dispose of contents/container to..… 处理内容物/容器.....
      • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P305+P351+P338
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
      • P301+P330+P331
      • P405 Store locked up. 上锁保管。
      • P304+P340
      • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
      • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P304+P340+P310
        Signal word
        Hazard statements
        • H302 Harmful if swallowed 吞食有害
        • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
          Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
          Hazard Codes C
          Hazard Class8
          Restrict 危险品
        • {ALF}
        • {ALF} For use in the preparation of stable, non-hygroscopic, crystalline acylammonium salts, see: J. Org. Chem., 57, 5136 (1992).
        • {ALF} Silver salt soluble in many organic solvents; useful, e.g. in promotion of the leaving ability of halogens. Promotes the conversion of ɑ-bromo aldehydes and ketones to their ɑ-fluoro equivalents: Tetrahedron Lett., 3357 (1979).
        • {ALF} Mediates the oxidative coupling of silylated cyclopropanols to 1,6-diones: J. Am. Chem. Soc., 105, 7192 (1983):
        • {uni_hamburg} Short: EINECS
        • {ALF} In the presence of AgBF4, aceta
        • {uni_hamburg} Short: III/7a
        • {ALF} In the presence of AgBF4, acetals of phenacyl halides undergo rearrangement to esters of arylacetic acids: J. Chem. Soc., Perkin 1, 2575 (1982); compare Silver nitrate, 11414.
        • 14104-20-2 H43293 Silver tetrafluoroborate


          Mol. FormulaAgBF4
          Mol. Weight195
          Melting Point70-73