Chemical Name | Dimethyl acetylmethylphosphonate |
CAS Number | 4202-14-6 |
EC Number | 224-110-5 |
Beilstein Registry Number | 1766218 |
MDL Number | MFCD00008769 |
Synonym |
Dimethyl acetonylphosphonate
{LY} Dimethyl acetonylphosphonate
{} {LY} Dimethyl acetonylphosphonate
{} {} {LY} Dimethyl acetonylphosphonate
{} {} {} {LY} Dimethyl acetonylphosphonate
{} {} {} {} {LY} Dimethyl acetonylphosphonate
{} {} {} {} {} {LY} Dimethyl acetonylphosphonate
{} {} {} {} {} {} {LY} Dimethyl acetonylphosphonate
{} {} {} {} {} {} {} {LY} Dimethyl acetonylphosphonate
{} {} {} {} {} {} {} {} {LY} Dimethyl acetonylphosphonate
{} {} {} {} {} {} {} {} {} {LY} Dimethyl acetonylphosphonate
{} {} {} {} {} {} {} {} {} {} {LY} Dimethyl acetonylphosphonate
{} {} {} {} {} {} {} {} {} {} {} {LY} Dimethyl acetonylphosphonate
{} {} {} {} {} {} {} {} {} {} {} {} {LY} Dimethyl acetonylphosphonate
{} {} {} {} {} {} {} {} {} {} {} {} {}
{} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dimethyl acetonylphosphonate
{} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dimethyl acetonylphosphonate
{} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
{} {} {} {} {} {} {} {} {} {} {} {} { |
PubChem Substance ID | 77872 |
Chemical Name Translation | 2-氧代丙基膦酸二甲酯 |
Reaxys-RN | 1766218 |
InChIKey | UOWIYNWMROWVDG-UHFFFAOYSA-N |
LabNetwork Molecule ID | LN00009226 |
InChI | InChI=1S/C5H11O4P/c1-5(6)4-10(7,8-2)9-3/h4H2,1-3H3 |
Canonical SMILES | CC(CP(OC)(OC)=O)=O |
Signal word |
Warning |
GHS Symbol
WGK Germany | 3 |
Safety Statements | |
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Risk Statements | |
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
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Precautionary statements | |
- P201 Obtain special instructions before use. 使用前获取专门指示。
- P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P281 Use personal protective equipment as required. 使用所需的个人防护装备。
- P301+P312
- P302+P352
- P304+P312
- P304+P340
- P305+P351+P338
- P308+P313
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
- P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
- P330 Rinse mouth. 漱口
- P332+P313
- P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
- P403+P233
- P403+P235
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
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Personal Protective Equipment |
Eyeshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US)
Eyeshields, Gloves, half-mask respirator (EU), half-mask respirator (US), multi-purpose combination respirator cartridge (US) |
Storage condition |
2-8°C, stored under nitrogen
{LY} 2-8°C, stored under nitrogen
{} {LY} 2-8°C, stored under nitrogen
{} {} {LY} 2-8°C, stored under nitrogen
{} {} {} {LY} 2-8°C, stored under nitrogen
{} {} {} {} {LY} 2-8°C, stored under nitrogen
{} {} {} {} {} {LY} 2-8°C, stored under nitrogen
{} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen
{} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen
{} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen
{} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen
{} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen
{} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen
{} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen
{} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen
{} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen
{} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen
{} {} {} {} {} {} {} {} {} {} {} {} {} {} { |
Hazard statements | |
- H227 Combustible liquid 可燃液体
- H302 Harmful if swallowed 吞食有害
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H332 Harmful if inhaled 吸入有害
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H341 Suspected of causing genetic defects 怀疑导致遗传性缺陷
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Hazard Codes |
Xi |
{ALD} Beilstein: 4,IV,3604
{ALF} Successive treatment with NaH and n-BuLi gives the dianion which can be alkylated or acylated on the terminal position: see. e.g.: Synth. Commun., 22, 219 (1992); J. Chem. Soc., Perkin 1, 2259 (1998).
{ALF} For use of ß-ketophosphonates in an annulation sequence for building a cyclohexadienone ring onto a cyclic ketone, see: Synthesis, 855 (1982):
{ALF} Horner-Wadsworth-Emmons precursor of ɑß-unsaturated ketones.