| Chemical Name | Diethylaluminum Chloride |
|---|
| CAS Number | 96-10-6 |
|---|
| EC Number | 202-477-2 |
|---|
| Beilstein Registry Number | 4123259 |
|---|
| MDL Number | MFCD00000459 |
|---|
| Synonym |
Aluminiumdiethylmonochlorid
Aluminum, chlorodiethyl-
Chlorodiethylaluminum
Chlorodiethylaluminum (also called Diethylaluminum Chloride)
DEAC
DIETHYLALUMINIUM CHLORIDE
DIETHYLALUMINUM CHLORIDE, 25 WT. % (1.8M ) SOLUTION IN TOLUENE
Diethylaluminium chloride
Diethylaluminum
Diethylaluminum chloride
Diethylaluminum monochloride
Diethylchloroaluminum
Diethylchoroaluminum
aluminiumdiethylchloride
aluminum, chlorodiethyl-
chlorodiethyl-al
chlorodiethyl-aluminu
dichlorotetraethyldi-aluminu
diethylaluminummonochloride
diethylchloroaluminum
{} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {uni_hamburg}
二乙基氯化铝
二乙基氯化铝, 25% W/W IN 庚烷, 95+%
氯代二乙鋁
氯化二乙基铝;二乙基氯化铝 |
| PubChem Substance ID | 7277 |
|---|
| Chemical Name Translation | 氯化二乙基铝 |
|---|
| Merck Number | 326 |
|---|
| LabNetwork Molecule ID | LN00164172 |
|---|
| InChI | InChI=1S/2C2H5.Al.ClH/c2*1-2;;/h2*1H2,2H3;;1H/q;;+1;/p-1 |
|---|
| Signal word |
Danger |
GHS Symbol
| WGK Germany | 3 |
|---|
| Safety Statements | |
|---|
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
- S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签；
|
| Risk Statements | |
|---|
- R11 Highly flammable 非常易燃
- R14 Reacts violently with water 遇水会猛烈反应
- R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应，释放出高度可燃气体
- R17 Spontaneously flammable in air 在空气中能够自燃
- R34 Causes burns 会导致灼伤
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R48/20
- R50/53
- R51/53
- R62 Possible risk of impaired fertility 有削弱生殖能力的危险
- R63 Possible risk of harm to the unborn child 可能危害未出生婴儿
- R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
- R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
|
| Precautionary statements | |
|---|
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P222 Do not allow contact with air. 不要与空气接触。
- P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能，因为会剧烈反应可能产生闪火。
- P231+P232
- P370+P378
- P422 Store contents under… 存储目录在…之下。
|
| Hazard statements | |
|---|
- H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
- H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
- H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
- H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
- H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
- H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体，可自燃。
- H361 Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害
|
| Personal Protective Equipment |
Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
| RTECS | BD0558000 |
|---|
| Packing Group | I |
|---|
| UN Number |
3394 |
| Storage condition |
密封保存
Air & Moisture Sensitive
充氩保存
0-6°C |
| Hazard Codes |
4.2
F,C,N |
| Hazard Class | 4.3 |
|---|
TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE : Inhalation
SPECIES OBSERVED : Rodent - rat
DOSE/DURATION : 11 gm/m3
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1215,1986
| Warnings |
危险化学品 |
| Restrict |
危险品 |
⑴.遇空气易自燃，遇水易爆炸。
⑵.用作聚烯烃、丁基橡胶和乙丙橡胶的聚合催化剂。
⑶.合成有机金属化合物和避孕药的中间体。
丙烯聚合反应的助催化剂，低压聚乙烯催化剂；乙丙橡胶、聚异丁烯、芳烃加氢等反应催化剂；火箭，导弹燃料以及镀铝原料。
{uni_hamburg} Short: EINECS
Title: EINECS (European Inventory of Existing Commercial Chemical Substances)
Source: Official Journal of the European Communities
Volume: C 146 A (15.06.1990)
Page: 1
Year: 1990
Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein
Publish_Date: 1990/06/15
{uni_hamburg} Short: III/35C4
Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Hydrogen-1, Part 4: Inorganic and Organometallic Compounds
Author: Gupta, R.R.; Platzer, N.
Editor: Gupta, R.R.; Lechner, M.D.
Source: Landolt-Börnstein, New Series
Volume: III/35C4
Year: 2001
Keyword: Hydrogen 1; Nuclear Magnetic Resonance
ISBN: 3-540-41059-7
ISBN: 978-3-540-41059-1
Internet Resource: DOI:10.1007/b76570
RefComment: VII, 299 pages. With CD-ROM. Hardcover
Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CD-ROM's.
{uni_hamburg} Short: IV/20A
Title: Vapor Pressure and Antoine Coefficients for Hydrocarbons and Sulfur-, Selenium-, Tellurium-, and Halogen-Containing Organic Compounds
Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R.
Editor: Hall, K.R.
Source: Landolt-Börnstein, New Series
Volume: IV/20A
Year: 1999
Keyword: organic compounds; vapor pressure
ISBN: 3-540-64735-X
ISBN: 978-3-540-64735-5
Internet Resource: DOI:10.1007/b71086
RefComment: VIII, 373 pages.
