Dichloro(p-cymene)ruthenium(II) dimer 二氯双(4-甲基异丙基苯基)钌(II)

规格: 98%
CAS: 52462-29-0
产品编号: H48910
MDL: MFCD00064793
品牌: INFI
Chemical NameDichloro(p-cymene)ruthenium(II) dimer
MDL NumberMFCD00064793
Synonym Dichloro(p-cymene)ruthenium(II) dimer {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {} {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {} {} {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {} {} {} {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {} {} {} {} {} {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {} {} {} {} {} {} {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {} {} {} {} {} {} {} {} {} {
EC Number435-530-5
CAS Number52462-29-0
PubChem Substance ID87569153
Beilstein Registry Number2384789
Chemical Name Translation二氯(4-甲基异丙苯)钌(II)二聚体
LabNetwork Molecule IDLN00155202
Canonical SMILESCc1ccc(C(C)C)cc1.Cc2ccc(C(C)C)cc2.Cl[Ru]3Cl[Ru](Cl)Cl3
GHS Symbol
Safety Statements
  • S24 Avoid contact with skin 避免皮肤接触；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
    Risk Statements
    • R22 Harmful if swallowed 吞咽有害
    • R36 Irritating to eyes 刺激眼睛
    • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
    • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
    • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
    • R52/53
      WGK Germany2
      Precautionary statements
      • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
      • P273 Avoid release to the environment. 避免释放到环境中。
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
      • P302+P352+P332+P313+P362+P364
      • P305+P351+P338
      • P305+P351+P338+P337+P313
      • P332+P313
      • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
      • P501 Dispose of contents/container to..… 处理内容物/容器.....
        Signal word Warning
        Hazard statements
        • H315 Causes skin irritation 会刺激皮肤
        • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
        • H302 Harmful if swallowed 吞食有害
        • H319 Causes serious eye irritation 严重刺激眼睛
          Hazard Codes Xn
          Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitr
        • Hydrosilylation Catalysts
        • Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis
        • Cyclometalated ruthenium complexes with arylimines and nitrogen-containing heterocycles via C-H bond activation
        • {ALF} Catalyst for highly stereoselective hydrosilylation of terminal alkynes: Org. Lett., 2, 1887 (2000). Also promotes the aerobic oxidation of benzylic and allylic alcohols to the corresponding aldehydes: Tetrahedron Lett., 41, 7507 (2000).
        • {ALF} In the presence of pyrrolidine, catalyzes the 1,4-addition of terminal alkynes to enones to give δ-ynones: Org. Lett., 3, 2089 (2001).
        • {ALF} Effective catalyst for dehydration of aldoximes to nitriles: Org. Lett., 3, 4271 (2001).
        • {ALF} Verstaile catayst for C-C bond formation by C-H bond activation, for example in the coupling of vinylsilanes with aromatic C-H bonds to give arylethyl silanes: Angew. Chem. Int. Ed., 45, 8232 (2006).
          • 52462-29-0 H48910 Dichloro(p-cymene)ruthenium(II) dimer 二氯双(4-甲基异丙基苯基)钌(II)

          化学属性

          Mol. FormulaC20H28Cl4Ru2
          Mol. Weight612.39
          TSCANo
          Melting Point247.0-250.0°C
          Density1.422
          Stability对光敏感

          *以上化合物性质及应用等信息仅供参考