n-Butylmagnesium chloride 正丁基氯化镁

规格: 1.4 M solution in Butyl diglyme, SpcSeal
CAS: 693-04-9
产品编号: H49932
MDL: MFCD00000475
品牌: INFI
Chemical Namen-Butylmagnesium Chloride
EC Number211-739-5
Beilstein Registry Number3587228
PubChem Substance ID101837
Synonym BUTYLMAGNESIUM CHLORIDE BUTYLMAGNESIUM CHLORIDE 2.0M SOLUTION & BUTYLMAGNESIUM CHLORIDE SOLUTION, ~2 M I N THF BUTYLMAGNESIUM CHLORIDE, 2.0M SOLUTION I N DIETHYL ETHER BUTYLMAGNESIUM CHLORIDE, 2.0M SOLUTION I N TETRAHYDROFURAN BUTYLMAGNESIUM CHLORIDE,1.45M SOLUTION IN BUTYL DIGLYME BuMgCl Butyl(chloro)magnesium Butylmagnesium Butylmagnesium Chloride (23% in Tetrahydrofuran, ca. 2mol/L) Magnesium, butylchloro- N-BUTYLMAGNESIUM CHLORIDE butylmagnesium chloride butylmagnesium chloride solution n-Butylmagnesium Chloride 2.0 M In Diethyl Ether n-Butylmagnesium Chloride 2.0 M In Tetrahydrofuran n-Butylmagnesium chloride, 1.5 n-Butylmagnesium chloride, 1.5-2.5M in THF, packaged under Argon in resealable ChemSeal bottles
Chemical Name Translation正丁基氯化镁
Reaxys-RN3683476
MDL NumberMFCD00000475
CAS Number693-04-9
InChIInChI=1S/C4H9.ClH.Mg/c1-3-4-2;;/h1,3-4H2,2H3;1H;/q-1;;+2/p-1
LabNetwork Molecule IDLN00241765
GHS Symbol
Signal word Danger
WGK Germany1
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
    Risk Statements
    • R11 Highly flammable 非常易燃
    • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应，释放出高度可燃气体
    • R15 Contact with water liberates extremely flammable gases 遇水会释放出极端易燃的气体
    • R19 May form explosive peroxides 可能生成易爆的过氧化物质
    • R22 Harmful if swallowed 吞咽有害
    • R34 Causes burns 会导致灼伤
    • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
      Precautionary statements
      • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
      • P222 Do not allow contact with air. 不要与空气接触。
      • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能，因为会剧烈反应可能产生闪火。
      • P231+P232
      • P233 Keep container tightly closed. ?保持容器密闭。
      • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
      • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
      • P242 Use only non-sparking tools. 只能使用无火花工具。
      • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
      • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
      • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
      • P301+P330+P331
      • P301+P330+P331+
      • P302+P334
      • P303+P361+P353
      • P304+P340
      • P305+P351+P338
      • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
      • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
      • P335+P334
      • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
      • P370+P378
      • P402+P404
      • P403+P233
      • P403+P235
      • P405 Store locked up. 上锁保管。
      • P422 Store contents under… 存储目录在…之下。
      • P501 Dispose of contents/container to..… 处理内容物/容器.....
        Hazard statements
        • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
        • H226 Flammable liquid and vapour 易燃液体和蒸气
        • H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
        • H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体，可自燃。
        • H302 Harmful if swallowed 吞食有害
        • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
        • H318 Causes serious eye damage 严重伤害眼睛
        • H335 May cause respiratory irritation 可能导致呼吸道刺激
        • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
        • H351 Suspected of causing cancer 怀疑致癌
          Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
          Packing GroupI
          UN Number 3399
          Storage condition Air & Moisture Sensitive 充氩保存 2-8°C
          Hazard Codes 4.3 F,C
          Hazard Class4.3/3
          Restrict 危险品
        • 格氏试剂
        • {ALD} Beilstein: 4,II,1038
          • 693-04-9 H49932 n-Butylmagnesium chloride 正丁基氯化镁

          化学属性

          TSCAYes
          Melting Point-17 ºC
          Boiling Point66 ºC
          Solubility起反应
          Flash Point1°F (THF)
          Appearance liq.
          Stabilityair sensitive, moisture sensitive
          Density0.962
          Mol. FormulaC4H9ClMg
          Mol. Weight116.87

          *以上化合物性质及应用等信息仅供参考