Aluminum tert-butoxide 叔丁醇铝

规格: 99%
CAS: 556-91-2
产品编号: H50588
MDL: MFCD00008801
品牌: INFI
Chemical NameAluminum tert-Butoxide
Synonym Aluminum tert-Butoxide {LY} Aluminum tert-Butoxide {} {LY} Aluminum tert-Butoxide {} {} {LY} Aluminum tert-Butoxide {} {} {} {} {} {} {LY} Aluminum tert-Butoxide {} {} {} {} {LY} Aluminum tert-Butoxide {} {} {} {} {} {LY} Aluminum tert-Butoxide {} {} {} {} {} {} {LY} Aluminum tert-Butoxide {} {} {} {} {} {} {} {LY} Aluminum tert-Butoxide {} {} {} {} {} {} {} {} {LY} Aluminum tert-Butoxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Aluminum tert-Butoxide {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} Aluminum tert-Butoxide {} {} {} {} {} {} {} {} {} {} {} {LY} Aluminum tert-Butoxide {} {} {} {} {} {} {} {} {} {} {} {} {LY} Aluminum tert-Butoxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Aluminum tert-Butoxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Aluminum tert-Butoxide {} {} {} {} {} {} {} {}
Beilstein Registry Number4148229
PubChem Substance ID68399
CAS Number556-91-2
EC Number209-146-1
MDL NumberMFCD00008801
Reaxys-RN4148229
Merck Number333
Chemical Name Translation叔丁醇铝
LabNetwork Molecule IDLN01739958
InChIInChI=1S/3C4H9O.Al/c3*1-4(2,3)5;/h3*1-3H3;/q3*-1;+3
Canonical SMILESCC(C)(C)O[Al](OC(C)(C)C)OC(C)(C)C
GHS Symbol
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P302+P361+P354
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P310
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P316
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
    Signal word Danger
    Hazard statements
    • H228 Flammable solid 易燃固体
    • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
      Hazard Codes F,C
      WGK Germany3
      Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
      Storage condition 2-8°C, sealed storage, away from moisture {LY} 2-8°C, sealed storage, away from moisture Moisture Sensitive {} {LY} 2-8°C, sealed storage, away from moisture {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {}
      UN Number UN 2925 4.1/PG 2
      Safety Statements
      • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
      • S8 Keep container dry 保持容器干燥；
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
      • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
      • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
        Risk Statements
        • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
          Packing GroupII
          Hazard Class4.1/8
        • {SA}
        • Merck 14 ,333
        • {SA}
        • Beil. 1 ,IV,1612
        • {SA}
        • Fieser 1 ,23 / Fieser 2 ,21
        • {SA}
        • Aldrich MSDS 1 , 54:A / Corp MSDS 1 (1), 116:B / FT-IR 1 (2), 1281:A / FT-IR 2 (3), 4494:D / RegBook 1 (2), 3059:E / Structure Index 1 , 484:D:9
        • {ALF} Catalyst for the Oppenauer oxidation of secondary alcohols to ketones by hydride transfer, normally to acetone as solvent: Org. Synth. Coll., 3, 207 (1955). See also Aluminum isopropoxide, 14007. For improved conditions, see Zirconium(IV)­ tert-butoxide, 42583.
          • 556-91-2 H50588 Aluminum tert-butoxide 叔丁醇铝

          化学属性

          Mol. FormulaC12H27AlO3
          Mol. Weight246.32
          Density1.0251
          Melting Point241 °C
          SolubilityVery soluble in organic solvents
          TSCAYes
          Boiling Point156 °C at 2 mmHg
          Flash Point>65°C

          *以上化合物性质及应用等信息仅供参考