1,3-Dibromopropane 1,3-二溴丙烷

规格: 98%
CAS: 109-64-8
产品编号: H52066
MDL: MFCD00000255
品牌: INFI
Chemical Name1,3-Dibromopropane
CAS Number109-64-8
Synonym 1,3-Dibromopropane 1,3-Bis(bromo)propane 1 Trimethylene dibromide ?,?-Dibromopropane 1,3-DIBROMOPROPANE, REAGENTPLUS, 99% 1 3-DIBROMOPROPANE REAGENTPLUS(TM) 9& ALPHA,GAMMA-DIBROMOPROPANE 三亚甲基二溴 ω,ω'-Dibromopropane Trimethylenbromid 1,3-Dibrompropan {Chemicalb omega,omega’-dibromopropane TRIMETHYLENE DIBROMIDE 1,3-dibromo-propan ?,?'-Dibromopropane 三亚甲基二溴,溴化三次甲基 NSC 62663 ω,ω’-Dibromopropane Trimethylene bromide 溴化三次甲基 ,-Dibromopropane Dibromo-1,3 propane α,γ-Dibromopropane 溴化三亚甲基 Propane,1,3-dibromo- Trimethylene Dibromide 1,3-二溴丙烷
EC Number203-690-3
Beilstein Registry Number635662
MDL NumberMFCD00000255
Merck Number9713
PubChem Substance ID8001
Reaxys-RN635662
Chemical Name Translation1,3-二溴丙烷
Wiswesser Line NotationE3E
LabNetwork Molecule IDLN00195158
InChIInChI=1S/C3H6Br2/c4-2-1-3-5/h1-3H2
GHS Symbol
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Rectal
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 1 gm/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
   Behavioral - irritability
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 34,223,1928

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 473 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPCEAO Journal fuer Praktische Chemie.  (Johann Ambrosius Barth Verlag,
   Postfach 109, Leipzig DDR-7010, Ger. Dem. Rep.)  V.1-    1834-
   Volume(issue)/page/year: 320,133,1978

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 10 umol/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 2,59,1980

Signal word
WGK Germany2
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
    Risk Statements
      Precautionary statements
      • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
      • P501 Dispose of contents/container to..… 处理内容物/容器.....
      • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P305+P351+P338
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
      • P332+P313
      • P301+P312+P330
      • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
      • P302+P350
      • P337+P313
      • P302+P352+P332+P313+P362+P364
      • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
      • P201 Obtain special instructions before use. 使用前获取专门指示。
      • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
      • P273 Avoid release to the environment. 避免释放到环境中。
      • P305+P351+P338+P337+P313
      • P308+P311
      • P211 Do not spray on an open flame or other ignition source.? 不要喷洒在明火或其他点火源。
      • P370+P378
      • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
      • P405 Store locked up. 上锁保管。
      • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
      • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
        RTECSTX8575000
        Packing GroupIII
        UN Number 1993
        Hazard Codes Xn,N,Xi
        Hazard statements
        • H315 Causes skin irritation 会刺激皮肤
        • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
        • H302 Harmful if swallowed 吞食有害
        • H226 Flammable liquid and vapour 易燃液体和蒸气
        • H319 Causes serious eye irritation 严重刺激眼睛
          Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
          Storage condition 充氩密封阴凉避光保存。 2-8°C
          Hazard Class9
        • 有机合成(合成环丙烷)。
        • {uni_hamburg} Short: II/25C
        • {ALD} Merck:14,9713
        • {TRC} Koudelakova, T., et al.: Biochem. J., 435,?345 (2011),
        • {ALD} Merck:14,9713
        • Beilstein:1,110
        • {uni_hamburg} Short: III/38B
          • 109-64-8 H52066 1,3-Dibromopropane 1,3-二溴丙烷

          化学属性

          Mol. FormulaC3H6Br2
          Mol. Weight202
          Density1.989
          Refractive index1.5200 to 1.5240
          Flash Point54°(130°F)
          TSCAYes
          Boiling Point167
          Melting Point-34
          Solubility1.7 G/L (30 ºC)
          Vapor Density7 (vs air)
          Stability对光敏感
          Appearance 无色或淡黄色液体。凝固点-34.2℃，沸点165℃（167.3℃），59-63℃（2.66kPa），55.6℃（1.33kPa），相对密度1.9822（20/4℃），折光率1.5232，闪点54℃。溶于乙醚、丙酮和氯仿，不溶于水。长时间遇热则分解，并部分转变为1,2-二溴丙烷。与水煮沸产生丙二醇。无臭，味甜，易吸潮。

          *以上化合物性质及应用等信息仅供参考