Chemical Name | Copper(II) trifluoromethanesulfonate |
Synonym |
Copper(II) trifluoromethanesulfonate
{LY} Copper(II) trifluoromethanesulfonate
{} {LY} Copper(II) trifluoromethanesulfonate
{} {} {LY} Copper(II) trifluoromethanesulfonate
{} {} {} {LY} Copper(II) trifluoromethanesulfonate
{} {} {} {} {LY} Copper(II) trifluoromethanesulfonate
{} {} {} {} {} {LY} Copper(II) trifluoromethanesulfonate
{} {} {} {} {} {} {LY} Copper(II) trifluoromethanesulfonate
{} {} {} {} {} {} {} {LY} Copper(II) trifluoromethanesulfonate
{} {} {} {} {} {} {} {} {LY} Copper(II) trifluoromethanesulfonate
{} {} {} {} {} {} {} {} {} {LY} Copper(II) trifluoromethanesulfonate
{} {} {} {} {} {} {} {} {} {} {LY} Copper(II) trifluoromethanesulfonate
{} {} {} {} {} {} {} {} {} {} {} {LY} Copper(II) trifluoromethanesulfonate
{} {} {} {} {} {} {} {} {} {} {} {} {LY} Copper(II) trifluoromethanesulfonate
{} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Copper(II) trifluoromethanesulfonate
{} {} {} {} {} {} {} {} {} {} {} {} {} {}
{} {} {} {} {} {} {} {} {} {} {} {} { |
EC Number | 252-300-8 |
Beilstein Registry Number | 4028198 |
PubChem Substance ID | 87577063 |
Reaxys-RN | 4028198 |
Chemical Name Translation | 三氟甲烷磺酸酮 |
LabNetwork Molecule ID | LN00224893 |
InChIKey | HRQFBGFAQQDQJD-UHFFFAOYSA-N |
CAS Number | 34946-82-2 |
MDL Number | MFCD00077492 |
InChI | InChI=1S/2CHF3O3S.Cu/c2*2-1(3,4)8(5,6)7;/h2*(H,5,6,7);/q;;+2/p-2 |
Canonical SMILES | O=S([O-])(C(F)(F)F)=O.[Cu+2] |
Safety Statements | |
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
|
Packing Group | II |
UN Number |
1759
3261 |
Risk Statements | |
|
Storage condition |
Store at room temperature
{LY} Store at room temperature
{} {LY} Store at room temperature
{} {} {LY} Store at room temperature
{} {} {} {LY} Store at room temperature
{} {} {} {} {LY} Store at room temperature
{} {} {} {} {} {LY} Store at room temperature
{} {} {} {} {} {} {LY} Store at room temperature
{} {} {} {} {} {} {} {LY} Store at room temperature
{} {} {} {} {} {} {} {} {LY} Store at room temperature
{} {} {} {} {} {} {} {} {} {LY} Store at room temperature
{} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature
{} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature
{} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature
{} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature
{} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature
{} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature
{} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
{} {} {} {} {} {} {} {} {} {} {} {} {} {} {} |
WGK Germany | 3 |
GHS Symbol
Precautionary statements | |
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331
- P301+P330+P331+P310
- P303+P361+P353+P310+P363
- P304+P340
- P304+P340+P310
- P305+P351+P338
- P305+P351+P338+P310
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
|
Hazard statements | |
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
|
Personal Protective Equipment |
Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges |
Signal word |
Danger |
Hazard Codes |
8
C |
Hazard Class | 8 |
有效催化把三甲基甲硅烷氰基添加到羰基化合物。
{ALF} Friedel-Crafts alkylation and acylation reactions of aromatics are also catalyzed: Tetrahedron, 57, 241 (2001).
{ALF} Widely used to generate carbenoid species from ɑ-diazo esters and ketones, via in situ reduction to the Cu(I) species: J. Am. Chem. Soc., 95, 3300 (1973). Preferred reagent for intramolecular cyclization of various diazo ketones: J. Org. Chem., 49, 11496 (1984). Also promotes the reaction between diazo esters and imines to give aziridines: J. Chem. Soc., Chem. Commun., 1 (1995).
{ALF} Catalyzes syn-selective aldol condensation of (Z)-silyl enol ethers with aldehydes: Chem. Lett., 959 (1997).
{ALF} Mild Lewis acid:
{ALF} Used catalytically, promotes dehydration of alcohols and diols to alkenes at ambient temperatures: Helv. Chim. Acta, 70, 607 (1987).
{ALF} For a brief feature on uses of the reagent in synthesis, see: Synlett, 1044 (2005).