3-Methyl-1-butanol 3-甲基-1-丁醇

规格: 99%, SpcDry, with molecular sieves, Water≤50 ppm (by K.F.), SpcSeal
CAS: 123-51-3
产品编号: H60579
MDL: MFCD00002934
品牌: INFI
Chemical Name3-Methyl-1-Butanol
Synonym 1-Hydroxy-3-methylbutane 1-Hydroxy-3-methylbutane; Isoamyl alcohol; Isopentyl alcohol 2-Methyl-4-butanol 3-METHYL BUTANOL 3-Methyl-1-butanol 3-Methylbutan-1-ol 3-Metil-butanolo 3-甲基-1-丁醇 3-甲基-1-丁醇, ACS, 98.5+% 3-甲基丁醇 FEMA 2057 ISOAMYL ALCOHOL ISOPENTANOL Isoamyl alcohol Isoamyl alcohol, Isobutylcarbinol Isoamyl alcohol, primary METHYL-BUTANOL NATURAL ISO AMYL ALCOHOL 异丁原醇 异丁基甲醇
CAS Number123-51-3
PubChem Substance ID31260
EC Number204-633-5
Beilstein Registry Number1718835
MDL NumberMFCD00002934
Reaxys-RN1718835
Merck Number5195
Chemical Name Translation异戊醇
Wiswesser Line NotationQ2Y1&1
LabNetwork Molecule IDLN00163016
InChIInChI=1S/C5H12O/c1-5(2)3-4-6/h5-6H,3-4H2,1-2H3
GHS Symbol
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 27 gm/kg/75W-I
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Liver - tumors
   Blood - leukemia
REFERENCE :
   ARGEAR Archiv fuer Geschwulstforschung.  (VEB Verlag Volk und Gesundheit
   Neue Gruenstr. 18, Berlin DDR-1020, Ger. Dem. Rep.)  V.1-    1949-
   Volume(issue)/page/year: 45,19,1975

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3800 mg/kg/85W-I
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Liver - tumors
   Blood - leukemia
REFERENCE :
   ARGEAR Archiv fuer Geschwulstforschung.  (VEB Verlag Volk und Gesundheit
   Neue Gruenstr. 18, Berlin DDR-1020, Ger. Dem. Rep.)  V.1-    1949-
   Volume(issue)/page/year: 45,19,1975

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Human
DOSE/DURATION           : 150 ppm
TOXIC EFFECTS :
   Sense Organs and Special Senses (Olfaction) - effect, not otherwise
   specified
   Sense Organs and Special Senses (Eye) - conjunctive irritation
   Lungs, Thorax, or Respiration - other changes
REFERENCE :
   JIHTAB Journal of Industrial Hygiene and Toxicology.  (Cambridge, MA)
   V.18-31, 1936-49.  For publisher information, see AEHLAU.
   Volume(issue)/page/year: 25,282,1943

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1300 mg/kg
TOXIC EFFECTS :
   Liver - fatty liver degeneration
   Kidney, Ureter, Bladder - other changes
   Blood - other changes
REFERENCE :
   SAMJAF South African Medical Journal.  (Medical Assoc. of South Africa,
   Secy., P.O. Box 643, Cape Town, S. Africa)  V.6-    1932-
   Volume(issue)/page/year: 43,795,1969

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 813 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AEPPAE Naunyn-Schmiedeberg's Archiv fuer Experimentelle Pathologie und
   Pharmakologie.  (Berlin, Ger.) V.110-253, 1925-66.  For publisher
   information, see NSAPCC.  Volume(issue)/

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 7480 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FCTXAV Food and Cosmetics Toxicology.  (London, UK)  V.1-19, 1963-81.  For
   publisher information, see FCTOD

WGK Germany1
Hazard Codes 3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H318 Causes serious eye damage 严重伤害眼睛
    Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
    RTECSEL5425000
    Precautionary statements
    • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
    • P233 Keep container tightly closed. ?保持容器密闭。
    • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
    • P241+P242+P243
    • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
    • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
    • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P303+P361+P353
    • P304+P340+P312
    • P305+P351+P338
    • P305+P351+P338+P310
    • P305+P351+P338+P337+P313
    • P307+P311
    • P308+P311
    • P337+P313
    • P370+P378
    • P403+P233
    • P403+P235
    • P405 Store locked up. 上锁保管。
    • P501 Dispose of contents/container to..… 处理内容物/容器.....
      Signal word Danger Warning
      UN Number 1105 1201/1105 UN1105
      Risk Statements
      • R10 Flammable 易燃
      • R20 Harmful by inhalation 吸入有害
      • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
      • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
      • R37 Irritating to respiratory system 刺激呼吸道
      • R66 Repeated exposure may cause skin dryness or cracking 反复接触可能导致皮肤干燥或皴裂
        Safety Statements
        • S46 If swallowed, seek medical advice immediately and show this container or label 食入时，立即求医并出示容器/标签；
          Packing GroupIII
          Storage condition 密封阴凉处保存。 Flammables area
          Hazard Class3
          Warnings 危化品目录(2015)
          Restrict 危险品
        • 脂肪、树脂、生物碱的溶剂, 测定牛乳中的脂肪, 测定铁、硅、钍及杂醇油等。也用于铁、钴、铜盐和二苯碳酰二肼的络合萃取。氯化锂与其他碱金属氯化物的分离。
        • {ALD} Merck: 14,5195
        • {ALD} Merck: 14,5195
        • Beilstein:1,392
          • 123-51-3 H60579 3-Methyl-1-butanol 3-甲基-1-丁醇

          化学属性

          Mol. FormulaC5H12O
          Mol. Weight88.15
          Refractive index1.4020 to 1.4070
          Boiling Point130
          Density0.809
          Melting Point-117
          Flash Point46°C(lit.)
          TSCAYes
          Autoignition Point644 °F
          Vapor Density3 (vs air)
          Vapor Pressure2 mmHg ( 20 °C)
          Solubility25 G/L (20 ºC)

          *以上化合物性质及应用等信息仅供参考