Chemical Name | Trimethylphenylammonium Tribromide |
Synonym |
Mono(N,N,N-trimethylbenzenaminium) tribromide
{LY} Mono(N,N,N-trimethylbenzenaminium) tribromide
X-TractElute
hydroxide of phenyltrimethylammonium
iodide of phenyltrimethylammonium
phenyltrimethylammonium
phenyltrimethylammonium acetate
phenyltrimethylammonium benzenesulfonate
phenyltrimethylammonium bromide
phenyltrimethylammonium chloride
phenyltrimethylammonium tosylate
phenyltrimethylammonium tribromide
phenyltrimethylammonium, tri(methyl-3(2)H)-labeled cpd
trimethyl-d9-anilinium hydroxide
trimethylanilinium
trimethylanilinium iodide
trimethylphenylammonium hydroxide
trimethylphenylammonium iodide
{} {LY} Mono(N,N,N-trimethylbenzenaminium) tribromide
{} {} {LY} Mono(N,N,N-trimethylbenzenaminium) tribromide
{} {} {} {LY} Mono(N,N,N-trimethylbenzenaminium) tribromide
{} {} {} {} {LY} Mono(N,N,N-trim |
CAS Number | 4207-56-1 |
EC Number | 224-127-8 |
Beilstein Registry Number | 3919459 |
MDL Number | MFCD00011789 |
PubChem Substance ID | 77880 |
Reaxys-RN | 3919459 |
Chemical Name Translation | 苯基三甲基三溴化铵 |
InChIKey | PRXNKYBFWAWBNZ-UHFFFAOYSA-N |
LabNetwork Molecule ID | LN00191249 |
InChI | InChI=1S/C9H14N.Br3/c1-10(2,3)9-7-5-4-6-8-9;1-3-2/h4-8H,1-3H3;/q+1;-1 |
Canonical SMILES | C[N+](C)(C1=CC=CC=C1)C.Br[Br-]Br |
Signal word |
Danger |
GHS Symbol
WGK Germany | 3 |
Safety Statements | |
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
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Risk Statements | |
- R34 Causes burns 会导致灼伤
- R37 Irritating to respiratory system 刺激呼吸道
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Precautionary statements | |
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331
- P301+P330+P331+P310
- P302+P361+P354
- P303+P361+P353
- P303+P361+P353+P310+P363
- P304+P340
- P304+P340+P310
- P305+P351+P338
- P305+P351+P338+P310
- P305+P354+P338
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P316
- P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
- P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
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Hazard statements | |
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
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Personal Protective Equipment |
Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges |
Packing Group | II |
UN Number |
1759
3261
UN 3261 8/PG 2 |
Storage condition |
Store at room temperature
{LY} Store at room temperature
{} {LY} Store at room temperature
{} {} {LY} Store at room temperature
{} {} {} {LY} Store at room temperature
{} {} {} {} {LY} Store at room temperature
{} {} {} {} {} {LY} Store at room temperature
{} {} {} {} {} {} {LY} Store at room temperature
{} {} {} {} {} {} {} {LY} Store at room temperature
{} {} {} {} {} {} {} {} {LY} Store at room temperature
{} {} {} {} {} {} {} {} {} {LY} Store at room temperature
{} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature
{} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature
{} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature
{} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature
{} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature
{} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature
{} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
{} {} {} {} {} {} {} {} {} {} {} {} {} {} {} |
Hazard Codes |
8
C |
Hazard Class | 8 |
溴化试剂,用于在1,2-位把溴增加到α,β-不饱和化合物的双键上。
{ALF} Reagent for the selective ɑ-bromination of acetals with good stability and solubility in organic solvents such as THF: Tetrahedron Lett., 24 (1959); Bull. Soc. Chim. Fr., 1822 (1961); 90 (1962). For example of use in a one-pot ɑ-bromoacetalization of carbonyl com
{ALF} For example of selective ɑ-monobromination of ketones, see: Org. Synth. Coll., 6, 175 (1988). Silyl enol ethers are also ɑ-brominated with this reagent to give ɑ-bromo enones: Synlett, 651 (1994).
{uni_hamburg} Short: EINECS
{ALF} Tosylhydrazones have been oxidized to N-alkenyl-N'-tosyldiazenes: J. Org. Chem., 39, 826 (1974).
{ALF} Reagent for the selective ɑ-bromination of acetals with good stability and solubility in organic solvents such as THF: Tetrahedron Lett., 24 (1959); Bull. Soc. Chim. Fr., 1822 (1961); 90 (1962). For example of use in a one-pot ɑ-bromoacetalization of carbonyl compounds in high yields, see: Synthesis, 309 (1982).
{uni_hamburg} Short: II/27B
{ALD} Beilstein:12,159
{ALF} Catalyses the aziridination of alkenes by Chloramine-T trihydrate, A12044: J. Am. Chem. Soc., 120, 6844 (1998).