(Methoxymethyl)diphenylphosphine oxide ( 甲氧基甲基)二苯基磷氧

规格: 98%
CAS: 4455-77-0
产品编号: H65929
MDL: MFCD00015451
品牌: INFI
Chemical Name[(methoxymethyl)(phenyl)phosphoroso]benzene
MDL NumberMFCD00015451
CAS Number4455-77-0
Synonym (Methoxymethyl)diphenylphosphine oxide {LY} (Methoxymethyl)diphenylphosphine oxide {} {LY} (Methoxymethyl)diphenylphosphine oxide {} {} {LY} (Methoxymethyl)diphenylphosphine oxide {} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide {} {} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide {} {} {} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide {} {} {} {} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide {} {} {} {} {} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide {} {} {} {} {} {} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide {} {} {} {} {} {} {} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide {} {} {} {} {} {} {} {} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide {} {} {} {} {} {} {} {} {} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide {} {} {} {} {} {} {} {} {} {} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (Methoxymethyl)diphenylphosphine oxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (Me
PubChem Substance ID78203
Beilstein Registry Number649558
EC Number224-704-4
Chemical Name Translation(甲氧基甲基)二苯基磷氧
Reaxys-RN649558
InChIKeyOEPKDBQOTLDTNC-UHFFFAOYSA-N
LabNetwork Molecule IDLN00222937
InChIInChI=1S/C14H15O2P/c1-16-12-17(15,13-8-4-2-5-9-13)14-10-6-3-7-11-14/h2-11H,12H2,1H3
Canonical SMILESCOCP(C1=CC=CC=C1)(C2=CC=CC=C2)=O
GHS Symbol
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   KHFZAN Khimiko-Farmatsevticheskii Zhurnal.  Chemical Pharmaceutical Journal.
    For English translation, see PCJOAU.  (V/O Mezhdunarodnaya Kniga, 113095
   Moscow, USSR)  V.1-    1967-  Volume(issue)/page/year: 24(4),22,1990

Hazard statements
  • H302 Harmful if swallowed 吞食有害
    WGK Germany3
    RTECSSZ0199360
    Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
    Signal word
    Safety Statements
      Risk Statements
      • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
      • R22 Harmful if swallowed 吞咽有害
        Hazard Codes Xn
        Precautionary statements
        • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
        • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
        • P301+P312
        • P301+P312+P330
        • P301+P317
        • P330 Rinse mouth. 漱口
        • P501 Dispose of contents/container to..… 处理内容物/容器.....
          Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitr
        • {ALF} Horner olefination with aldehydes and ketones gives vinyl ethers (and hence higher aldehydes). The method is reported to be superior to the Wittig alternative. The two diastereoisomeric adducts can also be isolated and each converted to a single stereoisomer of the enol ether: J. Chem. Soc., Perkin 1, 3099 (1979):
          • 4455-77-0 H65929 (Methoxymethyl)diphenylphosphine oxide ( 甲氧基甲基)二苯基磷氧

          化学属性

          Mol. FormulaC14H15O2P
          Mol. Weight246.24
          Melting Point113-120 °C
          TSCANo
          Boiling Point334.7±25.0 °C at 760 mmHg

          *以上化合物性质及应用等信息仅供参考