Borane-tetrahydrofuran complex 硼烷四氢呋喃

规格: 1.0 M solution in THF, SpcSeal
CAS: 14044-65-6
产品编号: H67695
MDL: MFCD00012429
品牌: INFI
Chemical NameBorane tetrahydrofuran complex solution
Beilstein Registry Number3668402
MDL NumberMFCD00012429
PubChem Substance ID24850560
Synonym BORANE TETRAHYDROFURAN COMPLEX SOLUTION, ~1 M IN THF TETRAHYDROFURAN BORANE Borane tetrahydrofuran complex solution 四氫喃硼烷 四氢喃硼烷 硼烷-四氢呋喃 BORANE BORANE-TETRAHYDROFURAN COMPLEX, CA. 1.8M SOLUTION IN TETRAHYDROFURAN, TECH. BTHF Borane-tetrahydrofuran complex, 1M solution tetrahydrofuran BORANE-TETRAHYDROFURAN COMPLEX, 1.5M SOL N IN TETRAHYDROFURAN AND ETHER, TECH. BORANE-TETRAHYDROFURAN COMPLEX 1.0M SO& BORANE TETRAHYDROFURAN COMPLEX BORANE-TETRAHYDROFURAN BORON HYDRIDE-TETRAHYDROFURAN COMPLEX Tetrahydrofuran borane
EC Number237-881-8
CAS Number14044-65-6
Reaxys-RN3668402
Chemical Name Translation硼烷四氢呋喃络合物
LabNetwork Molecule IDLN01358165
GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H302 Harmful if swallowed 吞食有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体，可自燃。
  • H318 Causes serious eye damage 严重伤害眼睛
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H351 Suspected of causing cancer 怀疑致癌
  • H319 Causes serious eye irritation 严重刺激眼睛
    Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
    Precautionary statements
    • P303+P361+P353
    • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
    • P501 Dispose of contents/container to..… 处理内容物/容器.....
    • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能，因为会剧烈反应可能产生闪火。
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P370+P378
    • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
    • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P422 Store contents under… 存储目录在…之下。
    • P231+P232
    • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
    • P301+P330+P331+P310
    • P403+P233
    • P305+P351+P338+P310
      Signal word
      Safety Statements
        Packing GroupI
        UN Number
        Risk Statements
        • R11 Highly flammable 非常易燃
        • R22 Harmful if swallowed 吞咽有害
        • R19 May form explosive peroxides 可能生成易爆的过氧化物质
        • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
        • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应，释放出高度可燃气体
        • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
        • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
        • R66 Repeated exposure may cause skin dryness or cracking 反复接触可能导致皮肤干燥或皴裂
        • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
          Storage condition 0-10 2-8°C Air & Moisture Sensitive 储存温度2-8℃ 0-10°C
          Hazard Codes
          Hazard Class4.3/3
          Restrict 危险品
        • 用于将聚酰胺纤维表面的酰胺基还原为仲胺。
        • {ALD} Beilstein:17(3/4)24
        • {ALF} Examples of hydroboration reactions:
        • {ALF} For other reactions of borane, see Borane-dimethyl­ sulfide complex, L07705.
        • {ALF} For use in the reduction of carboxylic acids to alcohols, see: Org. Synth. Coll., 7, 221 (1990).
        • {ALF} Hydroboration, followed by reaction of the trialkylborane with a diazoketone to give a homologated ketone: Org. Synth. Coll., 6, 919 (1988). In situ generation of "disiamyl" borane from 2-methyl-2-butene, and use of this reagent in selective hydroboration reactions: Org. Synth. Coll., 7, 258 (1990). Preparation of di-3-pinanylborane from (-)-ɑ-pinene, and its use in asymmetric hydroborations, see: Org. Synth. Coll., 7, 339 (1990).
          • 14044-65-6 H67695 Borane-tetrahydrofuran complex 硼烷四氢呋喃

          化学属性

          Flash Point-22°C(lit.)
          TSCAYes
          Boiling Point66
          Solubility起反应
          Stability对空气敏感，对湿度敏感
          Density0.898
          Mol. FormulaC4H11BO
          Mol. Weight85.94
          Danger-Level-
          pH-:-
          Redox-

          *以上化合物性质及应用等信息仅供参考