Chlorodiphenylphosphine 二苯基氯化膦

规格: 95%
CAS: 1079-66-9
产品编号: H68282
MDL: MFCD00000529
品牌: INFI
Chemical NameChlorodiphenylphosphine
Synonym AURORA KA-1322 CHLORODIPHENYLPHOSPHINE Chlordiphenylphosphin Chlorodiphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
EC Number214-093-2
Beilstein Registry Number16,763
PubChem Substance ID66180
Reaxys-RN512032
Chemical Name Translation二苯基氯化膦
LabNetwork Molecule IDLN00225723
InChIInChI=1S/C12H10ClP/c13-14(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H
MDL NumberMFCD00000529
CAS Number1079-66-9
Canonical SMILESClP(C1=CC=CC=C1)C2=CC=CC=C2
GHS Symbol
Signal word Danger Warning
WGK Germany2
Safety Statements
  • S8 Keep container dry 保持容器干燥；
  • S30 Never add water to this product 切勿将水加入该产品中；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S25 Avoid contact with eyes 避免眼睛接触；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S20 When using do not eat or drink 使用时，不得进食，饮水；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
    Risk Statements
    • R14 Reacts violently with water 遇水会猛烈反应
    • R22 Harmful if swallowed 吞咽有害
    • R34 Causes burns 会导致灼伤
    • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
    • R29 Contact with water liberates toxic gas. 遇水释放出有毒气体
      Precautionary statements
      • P234 Keep only in original container. 只保留在原来的容器中。
      • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
      • P264+P265
      • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
      • P273 Avoid release to the environment. 避免释放到环境中。
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
      • P301+P312
      • P301+P317
      • P301+P330+P331
      • P301+P330+P331+P310
      • P302+P361+P354
      • P303+P361+P353
      • P303+P361+P353+P310+P363
      • P304+
      • P304+P340
      • P304+P340+P310
      • P305+P351+P338
      • P305+P351+P338+P310
      • P305+P354+P338
      • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
      • P316
      • P317
      • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
      • P330 Rinse mouth. 漱口
      • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
      • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
      • P404 Store in a closed container. 贮存于密闭容器中。
      • P405 Store locked up. 上锁保管。
      • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
      • P501 Dispose of contents/container to..… 处理内容物/容器.....
        Packing GroupII
        UN Number UN3265 3265 UN 3265 8/PG 2
        Storage condition 2-8°C, stored under nitrogen Air & Moisture Sensitive Store at R.T. 长期储存可能变浑浊
        Hazard statements
        • H290 May be corrosive to metals 可能腐蚀金属。
        • H302 Harmful if swallowed 吞食有害
        • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
        • H318 Causes serious eye damage 严重伤害眼睛
        • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
          Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
          Hazard Codes C
          Hazard Class8
          Restrict -
        • 合成中锂化反应引入二苯基磷。
        • {uni_hamburg} Short: EINECS
        • {uni_hamburg} Short: III/20b
        • {ALD} Beilstein:16,763
        • {ALF} Reacts with Li metal in liquid ammonia to give the Li diphenylphosphide: Tetrahedron Lett., 21, 3535 (1980). Reaction with vinyl lithium intermediates from the reaction of alkyllithiums with sulfonylhydrazones (see p-Toluenesulfonyl­ hydrazide, A13529) gives vinylphosphines: Tetrahedron Lett., 22, 4619 (1981).
          • 1079-66-9 H68282 Chlorodiphenylphosphine 二苯基氯化膦

          化学属性

          Refractive index1.6340 to 1.6370
          TSCAYes
          Melting Point14-16°
          Vapor Density7.8 (vs air)
          Solubility起反应 VIOLENTLY
          Mol. FormulaC12H10ClP
          Mol. Weight220.63
          Density1.19
          Flash Point>110°C
          Appearance yellow liq.
          Stabilityair sensitive, moisture sensitive
          Boiling Point320°C at 760 mmHg
          Danger-Level-
          pH-:-
          Redox-

          *以上化合物性质及应用等信息仅供参考