Chemical Name | Bis(1,5-cyclooctadiene)diiridium(I) dichloride |
Synonym |
1,
1,5-辛二烯氯化铱二聚体
BIS(1,5-CYCLOOCTADIEN)DIIRIDIUM(I)-DICHL ORIDE
BIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) DIC&
Bis(1,5-cyclooctadiene)diiridium(I) dichloride
CHLORO(1,5-CYCLOOCTADIENE)IRIDATE (I) DIMER
CHLORO(1,5-CYCLOOCTADIENE)IRIDIUM(I) DIMER (57%IR)
Chlor-(1,5-cyclooctadien)-iridium(I) Dimer
Chloro(1,5-cyclooctadiene)iridium(I) dimer
Chloro(1,5-cyclooctadiene)iridium(I), dimer,99.9%
Chloro(1,5-cyclooctadiene)iridium(I)dimere
Chloro-1,5-cyclooctadieneiridium(I)dimer,99%
DI-MU-CHLORO-BIS[(1,2,5,6-ETA)-1,5-CYCLOOCTADIENE]DIIRIDIUM
IRIDIUM I CYCLOOCTADIENE CHLORIDE
[Ir(cod)Cl]2
di-mu-chlorobis[(1,2,5,6-eta)cycloocta-1,5-diene]diiridium
双(1,5-环辛二烯)diiridium(一)二氯化
氯代-1,5-环戊二烯铱二聚体 |
EC Number | 235-170-7 |
PubChem Substance ID | 87560730 |
Beilstein Registry Number | 14372408 |
Chemical Name Translation | 双(1,5-环辛二烯)氯化铱(I)二聚体 |
Reaxys-RN | 14372408 |
InChIKey | ILRJMVBVICHYPJ-UHFFFAOYSA-L |
LabNetwork Molecule ID | LN00197889 |
MDL Number | MFCD00012414 |
CAS Number | 12112-67-3 |
GHS Symbol
WGK Germany | 3 |
Precautionary statements | |
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- P305+P351+P338+P337+P313
- P332+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
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Hazard statements | |
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
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Signal word |
Warning |
Personal Protective Equipment |
dust mask type N95 (US), Eyeshields, Gloves |
Safety Statements | |
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
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Risk Statements | |
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
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Hazard Codes |
Xi |
Storage condition |
0-10°C
2-8°C |
{ALF} In the presence of a phosphite, catalyzes displacements by carbon nucleophiles at the more substituted position in allylic systems: Angew Chem. Int. Ed., 36, 263 (1997); J. Am. Chem. Soc., 120, 8647 (1998).
{ALF}
{ALF} With catalytic amounts of dppp (1,3-Bis(diphenyl­phosphino)­propane, A12931) and Cs2CO3, a transfer hydrogenation system with 2-propanol as the H source can reduce both olefinic double bonds and carbonyl groups; for ɑß-unsaturated ketones, selective reduction to saturated ketones can be achieved: J. Org. Chem., 66, 4710 (2001).
{ALF} Effective catalyst for the reaction of alcohols with vinyl acetate to give vinyl ethers: J. Am. Chem. Soc., 124, 1590 (2002).
{ALF} Catalyst for Miyaura and Hartwig's direct boronylation of arenes with Bis(pinacolato)­diboron, L16088: J. Am. Chem. Soc., 124, 390 (2002):
{uni_hamburg} Short: III/10b
{uni_hamburg} Short: EINECS
{ALF} Catalyst precursor for asymmetric hydrogenation: Angew. Chem. Int. Ed., 37, 2897 (1998).