Triphenylborane 三苯基硼烷

规格: 0.25 M solution in THF, SpcSeal
CAS: 960-71-4
产品编号: H71816
MDL: MFCD00003007
品牌: INFI
Chemical NameTriphenylborane
CAS Number960-71-4
PubChem Substance ID70400
MDL NumberMFCD00003007
Synonym triphenyl-boran 三苯基硼烷 triphenylborane solution 三苯基硼烷 溶液 TRIPHENYLBORON, POWDER, WATER <2% triphenyl-borane Borane, triphenyl- 三苯基硼 Triphenyboron Bortriphenyl Borine, triphenyl- Triphenylborine Triphenylboron, min. 95% TRIPHENYLBORINE 三苯硼[烷] BORON TRIPHENYL Methylquecksilber(II)-chlorid 13% Cl TRIPHENYLBORON borine,triphenyl Triphenylboron Triphenylborane Triphenylbor C18H15B Triphenylboron,min.95% TRIPHENYLBORANE
EC Number213-504-2
Beilstein Registry Number1961313
Chemical Name Translation三苯基硼烷
InChIKeyMXSVLWZRHLXFKH-UHFFFAOYSA-N
LabNetwork Molecule IDLN01363619
InChIInChI=1S/C18H15B/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H
GHS Symbol
WGK Germany3
Hazard Codes Xn;F F F,Xn
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H228 Flammable solid 易燃固体
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H351 Suspected of causing cancer 怀疑致癌
    Precautionary statements
    • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
    • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
    • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
    • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
    • P301+P312+P330
    • P305+P351+P338
    • P370+P378
    • P403+P235
      Signal word Danger Warning
      RTECSED2367500
      Safety Statements
      • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
      • S22 Do not breathe dust 不要吸入粉尘；
      • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
      • S39 Wear eye/face protection 戴眼睛/面孔保护装置；
      • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
      • S36 Wear suitable protective clothing 穿戴适当的防护服；
      • S33 Take precautionary measures against static discharges 对静电采取预防措施；
      • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
        UN Number UN1325 UN 1993 3/PG 2 1993
        Risk Statements
        • R11 Highly flammable 非常易燃
        • R19 May form explosive peroxides 可能生成易爆的过氧化物质
        • R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
        • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
        • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
        • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
        • R22 Harmful if swallowed 吞咽有害
          Storage condition Air Sensitive
          Personal Protective Equipment Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
          Packing GroupIII
          Hazard Class4.1
        • {SA} Beil. 16 ,IV,1623
        • {SA} Corp MSDS 1 (2), 3516:A / FT-IR 1 (2), 1134:C / FT-IR 2 (3), 4458:D / IR-Spectra (2), 1327:D / IR-Spectra (3), 1552:F / NMR-Reference 2 (2), 1013:B / RegBook 1 (2), 3027:I / Structure Index 1 , 479:E:1
        • {uni_hamburg} Short: EINECS
        • Title: EINECS (European Inventory of Existing Commercial Chemical Substances)
        • Source: Official Journal of the European Communities
        • Volume: C 146 A (15.06.1990)
        • Page: 1
        • Year: 1990
        • Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein
        • Publish_Date: 1990/06/15
        • {uni_hamburg} Short: III/35A
        • Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Boron-11 and Phosphorus-31
        • Author: Gupta, R.R.; Jain, M.; Pardasani, P.; Pardasani, R.T.; Pelter, A.
        • Editor: Gupta, R.R.; Lechner, M.D.
        • Source: Landolt-Börnstein, New Series
        • Volume: III/35A
        • Year: 1997
        • ISBN: 3-540-60366-2
        • ISBN: 978-3-540-60366-5
        • Internet Resource: DOI:10.1007/b53033
        • RefComment: VIII, 242 pages. With CD-ROM. Hardcover
        • Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CO-ROM&#39;s.
          • 960-71-4 H71816 Triphenylborane 三苯基硼烷

          化学属性

          Mol. FormulaB(C6H5)3
          Mol. Weight242
          Boiling Point203 °C/15 mmHg(lit.)
          Density0.898 g/mL at 25 °C
          Melting Point145 °C(lit.)
          TSCAYes
          Flash Point1 °F
          Appearance powder

          *以上化合物性质及应用等信息仅供参考