Copper(I) iodide 碘化亚铜

规格: 98%
CAS: 7681-65-4
产品编号: H73192
MDL: MFCD00010978
品牌: INFI
Chemical NameCopper(I) Iodide
Synonym Cuprous iodide {LY} Cuprous iodide {} {LY} Cuprous iodide {} {} {LY} Cuprous iodide {} {} {} {LY} Cuprous iodide {} {} {} {} {LY} Cuprous iodide {} {} {} {} {} {LY} Cuprous iodide {} {} {} {} {} {} {LY} Cuprous iodide {} {} {} {} {} {} {} {LY} Cuprous iodide {} {} {} {} {} {} {} {} {LY} Cuprous iodide {} {} {} {} {} {} {} {} {} {LY} Cuprous iodide {} {} {} {} {} {} {} {} {} {} {LY} Cuprous iodide {} {} {} {} {} {} {} {} {} {} {} {LY} Cuprous iodide {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cuprous iodide {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cuprous iodide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cuprous iodide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cuprous iodide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cuprous iodide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {
PubChem Substance ID6432705
EC Number231-674-6
Beilstein Registry Number2384789
Merck Number14,2662
Chemical Name Translation碘化亚铜(I)
LabNetwork Molecule IDLN00192893
InChIInChI=1S/Cu.HI/h;1H/q+1;/p-1
MDL NumberMFCD00010978
CAS Number7681-65-4
Canonical SMILES[Cu]I
GHS Symbol
WGK Germany3
Hazard Codes
Hazard statements
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H318 Causes serious eye damage 严重伤害眼睛
    Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
    Precautionary statements
    • P273 Avoid release to the environment. 避免释放到环境中。
    • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P305+P351+P338
    • P501 Dispose of contents/container to..… 处理内容物/容器.....
      Signal word Danger
      Safety Statements
        Risk Statements
          Storage condition 2-8°C, stored under nitrogen, away from moisture {LY} RT, stored under nitrogen, away from moisture {} {LY} RT, stored under nitrogen, away from moisture {} {} {LY} RT, stored under nitrogen, away from moisture {} {} {} {LY} RT, stored under nitrogen, away from moisture {} {} {} {} {LY} RT, stored under nitrogen, away from moisture {} {} {} {} {} {LY} RT, stored under nitrogen, away from moisture {} {} {} {} {} {} {LY} RT, stored under nitrogen, away from moisture {} {} {} {} {} {} {} {LY} RT, stored under nitrogen, away from moisture {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen, away from moisture {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen, away from moisture {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen, away from moisture {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen, away from moisture {} {} {} {} {} {} {} {} {} {} {}
          UN Number UN3077
          Packing GroupIII
        • 有机反应催化剂，与碘化汞同用，作为测定机械轴承温度升高的指示剂。
        • {uni_hamburg} Short: II/24A
        • {ALFA} Has been used in an improved Ullmann synthesis of diaryl ethers with ultrasound activation: J. Chem. Soc., Perkin 1, 407 (1992), and also as a catalyst for the arylation of active methylene compounds: Synthesis, 67 (1983); J. Org. Chem., 58, 7606 (1993).
        • {ALFA} The formation of Cu(I) acetylides from terminal acetylenes, and their coupling with aryl or vinyl iodides, known as the Castro-Stephens reaction: J. Org. Chem., 28, 3313 (1963), is more often now carried out in situ with a Pd catalyst (the Sonogashira coupling), e.g. with trans-Dichlorobis(triphenyl­phosphine)­palladium(II)­, 10491: Tetrahedron Lett., 4467 (1975); J. Org. Chem., 63, 8551 (1998), or Tetrakis(triphenyl­phosphine)­palladium(0)­, 10548: Tetrahedron Lett., 30, 6997 (1989); Org. Synth. Coll., 9, 117 (1998); Synlett, 1387 (1998).
        • {ALFA} Precursor of organocopper reagents. Forms a 1:1-complex with triethyl phosphite, useful in the preparation of unsymmetrical biaryls by a room-temperature Ullmann-type coupling reaction: J. Am. Chem. Soc., 98, 8282 (1976); Tetrahedron Lett., 2767 (1978). For list of examples, see: Org. Synth. Coll., 8, 586 (1993).
        • {ALD} Merck: 14,2662
          • 7681-65-4 H73192 Copper(I) iodide 碘化亚铜

          化学属性

          Boiling Point1290°C at 760 mmHg
          Density5.62 g/mL at 25 °C(lit.)
          Melting Point605°C
          Refractive index2.346
          TSCAYes
          SolubilitySoluble in water (0.08 mg/ml at 20 °C). Insoluble in alcohol, and dilute acids.
          Vapor Pressure10 mmHg ( 656 °C)
          Stability对光敏感
          Flash Point1290°C
          Mol. FormulaCuI
          Appearance off-white pwdr.
          Mol. Weight190.45

          *以上化合物性质及应用等信息仅供参考