Chemical Name | Cyanogen Bromide |
CAS Number | 506-68-3 |
Synonym |
(CN)Br
BROMOCYAN
BROMOCYANE
BROMOCYANIDE
BrCN
Bromcyan
Bromine Monocyanide
Bromine cyanide
Bromine cyanide (BrCN)
Bromine cyanide(BrCN)
Bromine monocyanide
Bromocyan
Bromocyanide
Bromocyanide(BrCN)
Bromocyanogen
Bromure de cyanogen
CYANOGEN BROMIDE
Campilit
Cyanbromid
Cyanic bromide
Cyanobromide
Cyanogen bromide ((CN)Br)
Cyanogen bromide(BrCN)
Cyanogen monobromide
NSC 89684
TL 822
bromuredecyanogen(french)
bromuredecyanogene
cyanogen bromide
氰化溴
溴化氰
溴化氰 溶液
溴化氰, 97+%
溴氰 |
PubChem Substance ID | 10476 |
EC Number | 208-051-2 |
Beilstein Registry Number | 1697296 |
MDL Number | MFCD00011597 |
Merck Number | 14,2693 |
Chemical Name Translation | 溴化氰 |
Wiswesser Line Notation | E CN |
LabNetwork Molecule ID | LN00192989 |
InChI | InChI=1S/CBrN/c2-1-3 |
GHS Symbol
WGK Germany | 3 |
Hazard statements | |
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H300+H310+H330
- H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
- H330 Fatal if inhaled 吸入致命
- H311 Toxic in contact with skin 皮肤接触中毒
- H300 Fatal if swallowed 吞食致命
- H351 Suspected of causing cancer 怀疑致癌
- H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
|
Personal Protective Equipment |
Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
Hazard Codes |
6.1
T+,N
T+,N,F |
RTECS | GT2100000 |
Precautionary statements | |
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P273 Avoid release to the environment. 避免释放到环境中。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P284 Wear respiratory protection.? 佩戴呼吸保护装置。
- P301+P310
- P302+P350
|
Signal word |
Danger |
Safety Statements | |
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
|
Risk Statements | |
- R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有剧毒
- R32 Contact with acids liberates very toxic gas 与酸接触释放出毒性很高的气体
- R34 Causes burns 会导致灼伤
- R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
- R50/53
- R51/53
|
UN Number |
1889
3390 |
Packing Group | I |
Hazard Class | 6.1 |
Storage condition |
2-8°C储存
储存温度2-8°C
0-6°C |
Warnings |
危化品目录(2015) |
TYPE OF TEST : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE : Inhalation
SPECIES OBSERVED : Rodent - mouse
DOSE/DURATION : 500 mg/m3/10M
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NDRC** National Defense Research Committee, Office of Scientific Research
and Development, Progress Report. Volume(issue)/page/year: No.9-4-1-9,1943
TYPE OF TEST : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE : Inhalation
SPECIES OBSERVED : Human
DOSE/DURATION : 92 ppm/10M
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161)
Formerly U.S. Clearinghouse for Scientific & Technical Information.
Volume(issue)/page/year: PB214-270
Restrict |
危险品 |
多肽(如甲硫氨酸)键的选择性裂解试剂。
{ALD} Merck: 14,2693
Beilstein: 3,IV,90
{ALF} Source of electrophilic cyanide. Reagent for the von Braun cleavage of tertiary amines: Org. React., 7, 198 (1953), for example demethylation of tertiary amines: J. Am .Chem. Soc., 89, 1942 (1967). For use in the cleavage of 2-trimethylsilylethyl sulfides in the prepaparation of nucleoside thiocyanates, see: J. Org. Chem., 67, 1898 (2002), and references therein. For a brief feature on its uses in synthesis, see: Synlett, 1638 (2005).
{uni_hamburg} Short: II/14a
{uni_hamburg} Short: II/19a