Benzyltriethylammonium chloride 苄基三乙基氯化铵

规格: 99%
CAS: 56-37-1
产品编号: H77395
MDL: MFCD00011824
品牌: INFI
Chemical NameBenzyltriethylammonium chloride
CAS Number56-37-1
Alfabeta NameBENZYLTRIETHYLAMMONIUMCHLORIDE
MDL NumberMFCD00011824
Synonym Benzyltriethylammonium chloride {LY} Benzyltriethylammonium chloride {} {LY} Benzyltriethylammonium chloride {} {} {LY} Benzyltriethylammonium chloride {} {} {} {LY} Benzyltriethylammonium chloride {} {} {} {} {LY} Benzyltriethylammonium chloride {} {} {} {} {} {LY} Benzyltriethylammonium chloride {} {} {} {} {} {} {LY} Benzyltriethylammonium chloride {} {} {} {} {} {} {} {LY} Benzyltriethylammonium chloride {} {} {} {} {} {} {} {} {LY} Benzyltriethylammonium chloride {} {} {} {} {} {} {} {} {} {LY} Benzyltriethylammonium chloride {} {} {} {} {} {} {} {} {} {} {LY} Benzyltriethylammonium chloride {} {} {} {} {} {} {} {} {} {} {} {LY} Benzyltriethylammonium chloride {} {} {} {} {} {} {} {} {} {} {} {} {LY} Benzyltriethylammonium chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Benzyltriethylammonium chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Benzyltriethylammonium chloride {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID87563481
EC Number200-270-1
Beilstein Registry Number3574984
Chemical Name Translation苄基三乙基氯化铵
Reaxys-RN3574984
Wiswesser Line Notation2K2&2&1R &G
LabNetwork Molecule IDLN00175059
Canonical SMILESCC[N+](CC)(CC)CC1=CC=CC=C1.[Cl-]
GHS Symbol
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 18 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#01867

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2219 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Gastrointestinal - changes in structure or function of salivary glands
   Skin and Appendages - hair
REFERENCE :
   ATDAEI Acute Toxicity Data. Journal of the American College of Toxicology,
   Part B. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128)  V.1-
   1990-  Volume(issue)/page/year: 15(Suppl 1),S61,1996

Warnings IRRITANT
WGK Germany1
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H303 May be harmfully swallowed 吞食可能有害
    Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
    RTECSBO8275000
    Precautionary statements
    • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P305+P351+P338
    • P305+P351+P338+P337+P313
    • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
    • P332+P313
    • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
      Signal word Warning
      Safety Statements
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
      • S36 Wear suitable protective clothing 穿戴适当的防护服；
      • S37 Wear suitable gloves 戴适当手套；
      • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
        Risk Statements
        • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
          Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
          Hazard Codes Xi
        • 烷基化反应催化剂。有机合成相转移催化剂。通过相转移催化迈克尔加成反应(Mechael addition)合成多取代环丙烷。
        • {ALF} In combination with NaBr in acetonitrile, has been used for the mono-dealkylation of phosphonate diesters: Synthesis, 453 (1983).
        • {ALF} For use in the formation of polysubstituted cyclopropanes by carbene-type addition to double bonds, see Ethyl­ chloroacetate, A15554.
        • {ALF} Phase-transfer catalyst (see Appendix 2) which has found wide application in the generation of carbenes from haloforms and related precursors: Org. Synth. Coll., 7, 12 (1990); 8, 223 (1993). Dihalocarbenes have been used to convert primary amines (t-butylamine) to isonitriles: Org. Synth. Coll., 6, 232 (1988), and in the dehydration of amides, thioamides and oximes to nitriles: Tetrahedron Lett., 2121 (1973). Ureas give cyanamides.
        • {ALF} For use in the dialkylation of malonate esters to give cyclopropane derivatives, see: Synthesis, 54 (1985); Org. Synth. Coll., 7, 411 (1993).
        • {ALD} Beilstein: 12,IV,2164
          • 56-37-1 H77395 Benzyltriethylammonium chloride 苄基三乙基氯化铵

          化学属性

          Mol. FormulaC13H22ClN
          Mol. Weight227.77
          Melting Point239°C
          TSCAYes
          Solubility700 G/L (20 ºC)
          Density1.08
          Stability对湿度敏感
          Boiling Point366.11 °C at 760 mmHg

          *以上化合物性质及应用等信息仅供参考