Rhodium 铑

规格: 10% on Carbon (wetted with ca. 55% Water)
CAS: 7440-16-6
产品编号: H80890
MDL: MFCD00011201
品牌: INFI
Chemical NameRhodium
PubChem Substance ID87575632
Reaxys-RN4122948
EC Number231-125-0
Merck Number14,8186
Synonym Rhodium on carbon (55% water) {LY} Rhodium on carbon (55% water) {} {LY} Rhodium on carbon (55% water) {} {} {LY} Rhodium on carbon (55% water) {} {} {} {LY} Rhodium on carbon (55% water) {} {} {} {} {LY} Rhodium on carbon (55% water) {} {} {} {} {} {} {} {} {} {} {LY} Rhodium on carbon (55% water) {} {} {} {} {} {} {LY} Rhodium on carbon (55% water) {} {} {} {} {} {} {} {LY} Rhodium on carbon (55% water) {} {} {} {} {} {} {} {} {LY} Rhodium on carbon (55% water) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Rhodium on carbon (55% water) {} {} {} {} {} {} {} {} {} {} {LY} Rhodium on carbon (55% water) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Rhodium on carbon (55% water) {} {} {} {} {} {} {} {} {} {} {} {} {LY} Rhodium on carbon (55% water) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Rhodium on carbon (55% water) {} {} {} {} {} {} {} {} {
Chemical Name Translation铑
InChIKeyMHOVAHRLVXNVSD-UHFFFAOYSA-N
Wiswesser Line NotationRH
LabNetwork Molecule IDLN00196194
MDL NumberMFCD00011201
CAS Number7440-16-6
InChIInChI=1S/Rh
Canonical SMILES[Rh/C]
GHS Symbol
WGK Germanynwg
Hazard Codes F;Xi C,Xi,F Xi F,Xi O,C
RTECSVI9069000
UN Number 1378 3089 UN 3089 4.1/PG 2 UN1325 UN1789 UN3089
Signal word Danger Warning {} {} {} {} {} {} {TCI}
Hazard statements
  • H228 Flammable solid 易燃固体
  • H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
  • H272 May intensify fire; oxidizer 可能加剧火势；氧化剂。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H413 Maycauselonglastingharmfuleffectstoaquaticlife 可能对水生生物造成长期持续有害影响。
    Precautionary statements
    • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
    • P222 Do not allow contact with air. 不要与空气接触。
    • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
    • P285 In case of inadequate ventilation wear respiratory protection. 在通风不足的情况下，戴呼吸防护。
    • P304+P340+P342+P311
    • P304+P341
    • P305+P351+P338
    • P335+P334
    • P370+P378
    • P422 Store contents under… 存储目录在…之下。
    • P501 Dispose of contents/container to..… 处理内容物/容器.....
      Risk Statements
      • R11 Highly flammable 非常易燃
      • R37 Irritating to respiratory system 刺激呼吸道
      • R20 Harmful by inhalation 吸入有害
      • R53 May cause long-term adverse effects in the aquatic environment 对水生环境有长期的有害作用
      • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
      • R36 Irritating to eyes 刺激眼睛
      • R8 Contact with combustible material may cause fire 遇到易燃物会导致起火
      • R35 Causes severe burns 会导致严重灼伤
      • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
      • R34 Causes burns 会导致灼伤
      • R23 Toxic by inhalation 吸入有毒
        Safety Statements
        • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
        • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
        • S37 Wear suitable gloves 戴适当手套；
        • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
        • S22 Do not breathe dust 不要吸入粉尘；
        • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
        • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
        • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
        • S36 Wear suitable protective clothing 穿戴适当的防护服；
        • S17 Keep away from combustible material 远离可燃物料；
        • S38 In case of insufficient ventilation wear suitable respiratory equipment 通风不良时，佩带适当的呼吸器；
        • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
        • S33 Take precautionary measures against static discharges 对静电采取预防措施；
          Personal Protective Equipment Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges dust mask type N95 (US), Eyeshields, Gloves dust mask type N95 (US), Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
          Packing GroupII
          Hazard Class4.2
          Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
        • 主要应用范围：加氢、脱氢、氧化、扩环、环化、偶联、甲酰化、羰基化等
        • 应用领域：化工、医药和医药中间体、染料、农药、高分子材料等。
        • {ALF} For a monograph on catalytic hydrogenation, see: P. N. Rylander, Hydrogenation Methods, Academic Press, N.Y. (1985).
        • {ALF} For the reduction of nitrobenzene to phenylhydroxylamine using hydrazine hydrate as the hydrogen source, see: Org. Synth. Coll., 8, 16 (1993).
        • {ALD} Merck: 14,8186
        • {ALF} Rhodium catalysts are especially useful for the hydrogenation of aromatic rings under mild conditions. For details for the hydrogenation of 4-aminobenzoic acid to its hexahydro derivative under modest pressure, see: Org. Synth. Coll., 5, 670 (1973).
        • {ALF} Rhodium catalysts have also been used for the reduction of oximes to amines.
        • {ALF} Useful catalyst for hydrogenation of tetrasubstituted alkenes conjugated to a carbonyl group: Synlett, 117 (1997).
          • 7440-16-6 H80890 Rhodium 铑

          化学属性

          Density12.41 g/cm3(lit.)
          TSCAYes
          Boiling Point3727 °C at 760 mmHg
          Melting Point1966 °C
          Solubility不溶
          Stability对空气敏感
          Mol. FormulaRh
          Appearance ~2 nm; brown-black viscous substance grey-brown liq. black pwdr. (d50=18 μm) black liq. pwdr. 1/8'' x 1/8'' pellets
          Mol. Weight102.91

          *以上化合物性质及应用等信息仅供参考