Chemical Name | Chloro(1,5-Cyclooctadiene)Rhodium(I) Dimer |
Synonym |
氯(1,5-环辛二烯)铑二聚
Bis(1,5-cyclooctadiene)dirhodium(I) dichloride
5-环辛二烯)铑(Ⅰ)
1,5-环辛二烯氯铑(I)二聚体
(1,5-环辛二烯)氯铑(I)二聚体
环辛二烯络氯化铑
1,5-环辛二烯氯化铑(I)二聚体 氯(1,5-环辛二烯)铑(I)二聚体 氯化铑(I) 1,5-环辛二烯络合物二聚体
1,5-环辛二烯氯铑(I)二聚体 [Rh(COD)Cl]2 二聚氯代(1,5-环辛二烯)铑(I) 双(1,5-环辛二烯氯化铑) 环辛二烯络氯化铑
Bis(1,5-cyclooctadienerhodium chloride)
二聚氯代(1,5-环辛二烯)铑(Ⅰ)
双(1,5-环辛二烯氯化铑)
5-环辛二烯)氯铑(I)二聚体
氯(1
(1
[Rh(COD)Cl]2
5-环辛二烯)铑二聚,二聚氯代(1
二聚氯代(1,5-环辛二烯)铑(I) |
EC Number | 235-157-6 |
PubChem Substance ID | 87563994 |
Beilstein Registry Number | 2384789 |
Chemical Name Translation | (1,5-环辛二烯)氯铑(I)二聚体 |
Reaxys-RN | 14860700 |
MDL Number | MFCD00012415 |
CAS Number | 12092-47-6 |
WGK Germany | 3 |
GHS Symbol
Precautionary statements | |
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P302+P352+P332+P313+P362+P364
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P332+P313
- P305+P351+P338+P337+P313
- P302+P350
- P337+P313
|
Hazard statements | |
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
|
Signal word |
Warning |
Personal Protective Equipment |
dust mask type N95 (US), Eyeshields, Gloves |
Storage condition |
Air Sensitive & Hygroscopic
易吸潮,密闭干燥冷藏。 |
Safety Statements | |
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
|
Risk Statements | |
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
|
Hazard Codes |
Xi |
1,3-二烯和激活的烃反应的催化剂及制备手性复合物。耦合反应;不对称氢化反应; 硼氢化反应。
{ALF} Catalyzes the dehydrogenative coupling reaction of styrenes with Pinacolborane, L17558 to give the corresponding vinylboronates: Tetrahedron Lett., 40, 2585 (1999); Bull. Chem. Soc. Jpn., 75, 825 (2002). The complex has also been found to promote the atmospheric pressure carbonylation of benzylic halides to give good yields of phenylacetic acids: Tetrahedron Lett., 41, 7601 (2000).
{ALF} Homogeneous catalyst and catalyst precursor. For use in the preparation of a chiral BINAP alkene isomerization catalyst, see: Org. Synth. Coll., 8, 183 (1993).
{ALF} Miyaura has reported the Rh-catalyzed conjugate addition of arylboronic acids to ɑß-unsaturated carbonyl compounds in a single aqueous phase: Chem. Lett., 722 (2001):