(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II) (R,R)-(-)-N,N′-双(3,5-二-叔丁基亚水杨基)-1,2-环己二胺钴(II)

规格: 98%
CAS: 176763-62-5
产品编号: H89559
MDL: MFCD01631277
品牌: INFI
Chemical NameCobalt, [[2,​2'-​[(1R,​2R)​-​1,​2-​cyclohexanediylbis[(​nitrilo-​κN)​methylidyne]​]​bis[4,​6-​bis(1,​1-​dimethylethyl)​phenolato-​κO]​]​(2-​)​]​-​, (SP-​4-​2)​-
PubChem Substance ID24871023
Chemical Name Translation(R,R)-(-)-N,N'-双(3,5-二叔丁基亚水杨基)-1,2-环己基二胺钴
Synonym (R,R)-Jacobsen's catalyst cobalt(II) complex
MDL NumberMFCD01631277
CAS Number176763-62-5
GHS Symbol
WGK Germany3
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    Hazard statements
    • H332 Harmful if inhaled 吸入有害
    • H302 Harmful if swallowed 吞食有害
    • H312 Harmful in contact with skin 皮肤接触有害
      Hazard Codes Xn
      Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
      Signal word
      Safety Statements
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
      • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
        Risk Statements
        • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
        • {SA}
        • 1. Tokunaga, M. et al. Science 277 , 936, (1997) 摘要
        • {SA}
        • {SA} 2. Jacobsen, E.N. et al. Tetrahedron Lett. 38 , 773, (1997)
          • 176763-62-5 H89559 (R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II) (R,R)-(-)-N,N′-双(3,5-二-叔丁基亚水杨基)-1,2-环己二胺钴(II)

          化学属性

          Mol. FormulaC36H52CoN2O2
          Mol. Weight603.76
          Appearance red-brown pwdr.
          Melting Point406-412°C
          RedoxReduction

          *以上化合物性质及应用等信息仅供参考