Chemical Name | Tri(2-furyl)phosphine |
Synonym |
Tri-2-furanylphosphine
{LY} Tri-2-furanylphosphine
{} {LY} Tri-2-furanylphosphine
{} {} {LY} Tri-2-furanylphosphine
{} {} {} {LY} Tri-2-furanylphosphine
{} {} {} {} {LY} Tri-2-furanylphosphine
{} {} {} {} {} {LY} Tri-2-furanylphosphine
{} {} {} {} {} {} {LY} Tri-2-furanylphosphine
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{} {} {} {} {} {} {} {} {LY} Tri-2-furanylphosphine
{} {} {} {} {} {} {} {} {} {LY} Tri-2-furanylphosphine
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{} {} {} {} {} {} {} {} {} {} {LY} Tri-2-furanylphosphine
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{} {} {} {} {} {} {} {} {} {} {} {} {LY} Tri-2-furanylphosphine
{} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tri-2-furanylphosphine
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{} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tri-2-furanylphosphine
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{} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tri-2-fura |
EC Number | 000-000-0 |
Beilstein Registry Number | 1577564 |
PubChem Substance ID | 521585 |
Chemical Name Translation | 三(2-呋喃基)膦 |
Reaxys-RN | 1577564 |
LabNetwork Molecule ID | LN00188600 |
InChI | InChI=1S/C12H9O3P/c1-4-10(13-7-1)16(11-5-2-8-14-11)12-6-3-9-15-12/h1-9H |
MDL Number | MFCD00151857 |
CAS Number | 5518-52-5 |
Canonical SMILES | P(C1=CC=CO1)(C2=CC=CO2)C3=CC=CO3 |
Safety Statements | |
- S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
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Risk Statements | |
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
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Signal word |
Warning |
GHS Symbol
WGK Germany | 3 |
Precautionary statements | |
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P264+P265
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P350
- P302+P352
- P304+P340
- P305+P351+P338
- P305+P351+P338+P337+P313
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
- P319
- P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
- P332+P313
- P332+P317
- P337+P313
- P337+P317
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
- P362+P364
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
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Hazard statements | |
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
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Personal Protective Equipment |
dust mask type N95 (US), Eyeshields, Gloves |
Hazard Codes |
Xi |
Storage condition |
2-8°C, protect from light, stored under nitrogen
{LY} 2-8°C, protect from light, stored under nitrogen
Store at room temperature
{} {LY} 2-8°C, protect from light, stored under nitrogen
{} {} {LY} 2-8°C, protect from light, stored under nitrogen
{} {} {} {LY} 2-8°C, protect from light, stored under nitrogen
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{} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen
{} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen
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{} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen
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{} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen
{} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen
{} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, prote |
磷化氢配体,用于过渡金属介入的有机合成; 也用于Wittig 反应。
{ALF} In a study of Pd-catalyzed coupling reactions in supercritical CO 2, this ligand was among the best tried in both the Stille and Heck reactions, giving much superior results to e.g. triphenyl- or tri(o-tolyl)phosphine: Chem. Commun., 1397 (1998). See also Tris[3,5-bis(trifluoromethyl)­phenyl­]phosphine, L06941.
{ALF} Best ligand for Pd-catalyzed coupling of 5-iodouracil and unsaturated tributylstannanes: Synlett, 157 (1991).
{uni_hamburg} Short: III/35C4
{ALD} Beilstein:18(5)12,505
{ALF} Large rate enhancements (10 2 -10 3 ) over triphenylphosphine are observed in Pd-catalyzed coupling of olefinic stannanes and electrophiles: J. Am. Chem. Soc ., 113, 9585 (1991).
{TRC} Andersen N.G. et al.: Chem. Rev., 101, 997 (2001); Appel M. et al.: Eur. J. Org. Chem., 1143, (2002);