Chloro(1,5-cyclooctadiene)iridium(I) dimer 1,5-环辛二烯氯化铱二聚体

规格:
CAS: 12112-67-3
产品编号: HXYJ0000000167
MDL: MFCD00012414
品牌: Bellen
Chemical NameBis(1,5-cyclooctadiene)diiridium(I) dichloride
Synonym 1, 1,5-辛二烯氯化铱二聚体 BIS(1,5-CYCLOOCTADIEN)DIIRIDIUM(I)-DICHL ORIDE BIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) DIC& Bis(1,5-cyclooctadiene)diiridium(I) dichloride CHLORO(1,5-CYCLOOCTADIENE)IRIDATE (I) DIMER CHLORO(1,5-CYCLOOCTADIENE)IRIDIUM(I) DIMER (57%IR) Chlor-(1,5-cyclooctadien)-iridium(I) Dimer Chloro(1,5-cyclooctadiene)iridium(I) dimer Chloro(1,5-cyclooctadiene)iridium(I), dimer,99.9% Chloro(1,5-cyclooctadiene)iridium(I)dimere Chloro-1,5-cyclooctadieneiridium(I)dimer,99% DI-MU-CHLORO-BIS[(1,2,5,6-ETA)-1,5-CYCLOOCTADIENE]DIIRIDIUM IRIDIUM I CYCLOOCTADIENE CHLORIDE [Ir(cod)Cl]2 di-mu-chlorobis[(1,2,5,6-eta)cycloocta-1,5-diene]diiridium 双(1,5-环辛二烯)diiridium(一)二氯化 氯代-1,5-环戊二烯铱二聚体
EC Number235-170-7
PubChem Substance ID87560730
Beilstein Registry Number14372408
Chemical Name Translation双(1,5-环辛二烯)氯化铱(I)二聚体
Reaxys-RN14372408
InChIKeyILRJMVBVICHYPJ-UHFFFAOYSA-L
LabNetwork Molecule IDLN00197889
MDL NumberMFCD00012414
CAS Number12112-67-3
GHS Symbol
WGK Germany3
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
    Hazard statements
    • H315 Causes skin irritation 会刺激皮肤
    • H319 Causes serious eye irritation 严重刺激眼睛
    • H335 May cause respiratory irritation 可能导致呼吸道刺激
      Signal word Warning
      Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
      Safety Statements
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
        Risk Statements
        • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
          Hazard Codes Xi
          Storage condition 0-10°C 2-8°C
        • {ALF} In the presence of a phosphite, catalyzes displacements by carbon nucleophiles at the more substituted position in allylic systems: Angew Chem. Int. Ed., 36, 263 (1997); J. Am. Chem. Soc., 120, 8647 (1998).
        • {ALF}
        • {ALF} With catalytic amounts of dppp (1,3-Bis(diphenyl­phosphino)­propane, A12931) and Cs2CO3, a transfer hydrogenation system with 2-propanol as the H source can reduce both olefinic double bonds and carbonyl groups; for ɑß-unsaturated ketones, selective reduction to saturated ketones can be achieved: J. Org. Chem., 66, 4710 (2001).
        • {ALF} Effective catalyst for the reaction of alcohols with vinyl acetate to give vinyl ethers: J. Am. Chem. Soc., 124, 1590 (2002).
        • {ALF} Catalyst for Miyaura and Hartwig's direct boronylation of arenes with Bis(pinacolato)­diboron, L16088: J. Am. Chem. Soc., 124, 390 (2002):
        • {uni_hamburg} Short: III/10b
        • {uni_hamburg} Short: EINECS
        • {ALF} Catalyst precursor for asymmetric hydrogenation: Angew. Chem. Int. Ed., 37, 2897 (1998).
        • 12112-67-3 HXYJ0000000167 Chloro(1,5-cyclooctadiene)iridium(I) dimer	1,5-环辛二烯氯化铱二聚体

          化学属性

          SolubilitySoluble in chloroform, toluene. Slightly soluble in acetone, alcohol.
          TSCANo
          Density1.422
          Mol. Formula[IrCl(C8H12)]2
          Mol. Weight672
          Appearance red to orange pwdr.
          Melting Point205
          RedoxReduction

          *以上化合物性质及应用等信息仅供参考