Chemical Name | (R)-(-)-2-Phenylglycinol |
CAS Number | 56613-80-0 |
Alfabeta Name | PHENYLGLYCINOL R2(())---- |
MDL Number | MFCD00008062 |
Synonym |
(R)-(-)-2-Amino-2-phenylethanol
(R)-(-)-2-氨基-2-苯基乙醇;(R)-(-)-2-苯基-2-氨基乙醇
(R)-2-Amino-2-phenylethanol, D-(−)-α-Phenylglycinol
(R)-2-氨基-2-苯乙醇 D-(-)-α-苯甘氨醇
(R)-2-氨基-2-苯乙醇 D-(-)-α-苯甘氨醇
D-(-)-α-苯甘氨醇
R-苯甘氨醇,右旋苯甘氨醇,2-苯甘氨酸 |
Beilstein Registry Number | 2935848 |
PubChem Substance ID | 87575300 |
EC Number | 260-287-5 |
Reaxys-RN | 2935848 |
Chemical Name Translation | D-苯甘氨醇 |
LabNetwork Molecule ID | LN00009350 |
InChIKey | IJXJGQCXFSSHNL-UHFFFAOYSA-N |
Warnings |
IRRITANT |
WGK Germany | 3 |
Personal Protective Equipment |
Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter |
Signal word |
Warning |
Hazard statements | |
- H315 Causes skin irritation 会刺激皮肤
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Precautionary statements | |
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P350
- P302+P352+P332+P313+P362+P364
- P305+P351+P338
- P305+P351+P338+P337+P313
- P332+P313
- P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
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Safety Statements | |
- S22 Do not breathe dust 不要吸入粉尘;
- S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S37 Wear suitable gloves 戴适当手套;
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Risk Statements | |
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
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Storage condition |
0-10°C
Air Sensitive |
GHS Symbol
作为合成的结构单元使用的手性 β-氨基醇。
本氨基醇可用于由三氟丙酮酸乙酯制备手性亚胺或噁唑烷。然后,可将这些中间体用于合成 α-三氟甲基脯氨酸的两种对映体。
{SA} Tetrahedron Lett. 45 , 5287, (2004)
{ALFA} Condensation with glutaraldehyde gives a useful intermediate in asymmetric synthesis of alkaloids: Org. Synth. Coll., 9, 176 (1998):
{ALD} Beilstein:13(4)1835
{ALF} Condensation with glutaraldehyde gives a useful intermediate in asymmetric synthesis of alkaloids: Org. Synth. Coll., 9, 176 (1998):
{TRC} Kristensen, T. E. et al.: Eur. J. Org. Chem., 30, 5185 (2009); Liu, W. et al.: You. Xua., 26, 518 (2006);
{ALF} Starting material for the enantioselective synthesis of 2,6-disubstituted piperazines: Synthesis, 833 (1996), and for chiral ɑ-amino phosphonates: Org. Synth., 75, 19 (1997).
{ALFA} Starting material for the enantioselective synthesis of 2,6-disubstituted piperazines: Synthesis, 833 (1996), and for chiral ɑ-amino phosphonates: Org. Synth., 75, 19 (1997).