研峰科技 Infinity Scientific

DIPHENYL DISULFIDE 二苯二硫醚

规格:

CAS: 882-33-7

产品编号: HXYJ0000002829

MDL: MFCD00003065

品牌: Bellen

Chemical Name	Phenyl Disulfide
CAS Number	882-33-7
Alfabeta Name	DIPHENYLDISULFIDE
MDL Number	MFCD00003065
Synonym	Diphenyl disulfide {LY} Diphenyl disulfide {} {LY} Diphenyl disulfide {} {} {LY} Diphenyl disulfide {} {} {} {LY} Diphenyl disulfide {} {} {} {} {LY} Diphenyl disulfide {} {} {} {} {} {LY} Diphenyl disulfide {} {} {} {} {} {} {LY} Diphenyl disulfide {} {} {} {} {} {} {} {LY} Diphenyl disulfide {} {} {} {} {} {} {} {} {LY} Diphenyl disulfide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenyl disulfide {} {} {} {} {} {} {} {} {} {} {LY} Diphenyl disulfide {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenyl disulfide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenyl disulfide {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenyl disulfide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenyl disulfide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenyl disulfide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenyl disulfide
EC Number	212-926-4
Beilstein Registry Number	6,323
PubChem Substance ID	87574417
Reaxys-RN	639794
Chemical Name Translation	二苯二硫醚
Wiswesser Line Notation	RSSR
LabNetwork Molecule ID	LN00223112
Canonical SMILES	C1(SSC2=CC=CC=C2)=CC=CC=C1

GHS Symbol

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD277-689

Warnings	IRRITANT, STENCH
Signal word
WGK Germany	3
Safety Statements
S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护； S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Risk Statements
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用 P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 P305+P351+P338 P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。 P332+P313 P501 Dispose of contents/container to..… 处理内容物/容器..... P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服 P273 Avoid release to the environment. 避免释放到环境中。 P302+P350 P337+P313 P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。 P302+P352+P332+P313+P362+P364 P305+P351+P338+P337+P313 P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
Hazard statements
H315 Causes skin irritation 会刺激皮肤 H400 Verytoxictoaquaticlife 对水生生物毒性非常大。 H319 Causes serious eye irritation 严重刺激眼睛 H335 May cause respiratory irritation 可能导致呼吸道刺激 H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Gloves
RTECS	SS6825000
Hazard Codes
UN Number	3077
Packing Group	III
Hazard Class	9
Storage condition	2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

The hydrolysis product of dyfonate( insecticide ) and participates in hydrothiolation of alkynes via amine-mediated single electron transfer mechanism.

{ALF} Alkyl halides under phase-transfer conditions give alkyl phenyl sulfides in good yields,: Synth. Commun., 12, 595 (1982), and alkenyl halides in the presence of CuI give alkenyl sulfides: Chem. Lett., 769 (1989).

{ALF} Sulfenylation agent for enolates of ketones, esters or carboxylic acid dianions: J. Am. Chem. Soc., 95, 6840 (1973); 98, 4887 (1976); Chem. Rev., 78, 363 (1978). Oxidation to the sulfoxide and thermal elimination can be used for the conversion of ketones to enones via thermal sulfoxide elimination, less frequently used than the selenoxide route (cf preceding entry), due to the higher temperatures required.

{ALF} Also sulfenylates organolithium reagents from, e.g. lithiated furans: J. Org. Chem., 46, 2473 (1981).

{uni_hamburg} Short: IV/20A

{ALF} For use as a catalyst in the photochemical cis-trans isomerization of olefins (used in the synthesis of the macrolide ricinelaidic acid lactone), see: Org. Synth. Coll., 7, 470 (1990).

{uni_hamburg} Short: III/5a

{uni_hamburg} Short: III/10a

{ALD} Beilstein:6,323

{uni_hamburg} Short: IV/1a

882-33-7 HXYJ0000002829 DIPHENYL DISULFIDE 二苯二硫醚

化学属性

Mol. Formula	C12H10S2
Mol. Weight	218.34
Melting Point	58-60°C
TSCA	Yes
Density	1.22
Boiling Point	310.0±11.0°C at 760 mmHg
Flash Point	310°C
Appearance	白色粉末。熔点62-63℃。

*以上化合物性质及应用等信息仅供参考