Chemical Name | Hexabutylditin |
Synonym |
1,1,1,2,2,2-Hexabutyl-distannane
BIS[TRIBUTYLTIN(IV)]
Bis(tri-n-butyltin)
Bis(tributyltin)
Bis-(tributylzinn)
Distannane, hexabutyl-
Distannane,hexabutyl-
HEXABUTYLDISTANNANE
HEXABUTYLDITIN 97+%
Hexa-n-butyldistannane
Hexa-n-butylditin, min. 95%
Hexa-n-butylditin,min.95%
Hexabutyldistannane, Hexabutylditin
Hexabutyldistannane; Hexabutylditin
Hexabutylditin
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CAS Number | 813-19-4 |
PubChem Substance ID | 6327815 |
EC Number | 212-383-3 |
Beilstein Registry Number | 3605476 |
MDL Number | - |
Chemical Name Translation | 六正丁基二锡 |
InChIKey | REDSKZBUUUQMSK-UHFFFAOYSA-N |
LabNetwork Molecule ID | LN00009522 |
InChI | InChI=1S/6C4H9.2Sn/c6*1-3-4-2;;/h6*1,3-4H2,2H3;; |
Canonical SMILES | - |
GHS Symbol
WGK Germany | 3 |
Hazard statements | |
- H315 Causes skin irritation 会刺激皮肤
- H301 Toxic if swallowed 吞食有毒
- H312 Harmful in contact with skin 皮肤接触有害
- H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
- H319 Causes serious eye irritation 严重刺激眼睛
- H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
|
Personal Protective Equipment |
Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
Hazard Codes |
6.1
T,N |
Precautionary statements | |
- P273 Avoid release to the environment. 避免释放到环境中。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P310
- P305+P351+P338
- P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医,如果你觉得不舒服
- P501 Dispose of contents/container to..… 处理内容物/容器.....
|
Signal word |
Danger |
UN Number |
2788
UN 2788 6.1/PG 1
UN2788 |
Risk Statements | |
- R21 Harmful in contact with skin 与皮肤接触有害
- R25 Toxic if swallowed 吞咽有毒
- R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
- R48/23/25
- R50/53
|
Safety Statements | |
- S35 This material and its container must be disposed of in a safe way 该物料及其容器必须以安全方式处置;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
|
Storage condition |
+4°C, Hygroscopic
4
4°C, Hygroscopic
Air & Moisture Sensitive
Freezer (-20°C)
对空气和湿度敏感,密封保存。 |
Packing Group | III |
Hazard Class | 6.1 |
用于甲锡烷化芳基卤的试剂.
{ALF} Brings about the deoxygenation of amine oxides: Synthesis, 55 (1987), and the photo-desulfurisation of 1,3-dithiole-2-thiones to tetrathiafulvalenes: J. Am. Chem. Soc., 98, 7440 (1976).
{ALF} Source of on thermolysis or photolysis of tributylstannyl radicals, avoiding the problems sometimes attributable to the hydrogen donor capability of Tri-n-butyl­tin hydride, A13298.ɑ-Iodo-ketones or esters with a suitably-placed double bond undergo radical cyclizations on UV irradiation in the presence of a catalytic amount of the distannane: Tetrahedron Lett., 28, 2477 (1987); J. Org. Chem., 54, 1826, 3140 (1989). Compare analogous reductive cyclizations using the tin hydride. Improved conditions have been developed for generation of the tributylstannyl radical by mild UV irradiation in the presence of a triplet sensitizer (e.g. 4'-Methoxyacetophenone, A11162), allowing selective C-C bond forming reactions to be performed under free-radical conditions: Synlett, 287 (1993).
{uni_hamburg} Short: III/35C4
{SA} Tetrahedron Lett. 29 , 6893, (1988)
{ALF} Source of on thermolysis or photolysis of tributylstannyl radicals, avoiding the problems sometimes attributable to the hydrogen donor capability of Tri-n-butyl­tin hydride, A13298.ɑ-Iodo ketones or esters with a suitably-placed double bond undergo radical cyclizations on UV irradiation in the presence of a catalytic amount of the distannane: Tetrahedron Lett., 28, 2477 (1987); J. Org. Chem., 54, 1826, 3140 (1989). Compare analogous reductive cyclizations using the tin hydride. Improved conditions have been developed for generation of the tributylstannyl radical by mild UV irradiation in the presence of a triplet sensitizer (e.g. 4'-Methoxyacetophenone, A11162), allowing selective C-C bond forming reactions to be performed under free-radical conditions: Synlett, 287 (1993).
{ALF} Brings about the deoxygenation of amine oxides: Synthesis, 55 (1987), and the photo-desulfurization of 1,3-dithiole-2-thiones to